Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.     

Energy partitioning over a semi‐arid shrubland in northern China

During the last decade, the widely distributed shrublands in northern China have shown significant signs of recovery from desertification, the result of widespread conservation practices. However, to support the current efforts in conservation, more knowledge is needed on surface energy partitioning and its biophysical controls. Using eddy‐covariance measurements made over a semi‐arid shrubland in northwest China in 2012, we examined how surface energy‐balance components vary on diurnal and seasonal scales, and how biophysical factors control bulk surface parameters and energy exchange. Sensible heat flux (H) exceeded latent heat flux (λE) during most of the year, resulting in an annual Bowen ratio (β, i.e. H/λE) of 2.0. λE exceeded H only in mid‐summer when frequent rainfall co‐occurred with the seasonal peak in leaf area index (LAI). Evapotranspiration reached a daily maximum of 3.3 mm day^?1, and summed to 283 mm yr^?1. The evaporative fraction (EF, i.e. λE/R_n), Priestley–Taylor coefficient (α), surface conductance (g_s) and decoupling coefficient (Ω) were all positively correlated with soil water content (SWC) and LAI. The direct enhancement of λE by high vapour pressure deficit (VPD) was buffered by a concurrent suppression of g_s. The g_s played a direct role in controlling EF and α by mediating the effects of LAI, SWC and VPD. Our results highlight the importance of adaptive plant responses to water scarcity in regulating ecosystem energy partitioning, and suggest an important role for revegetation in the reversal of desertification in semi‐arid areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Petrographische und Kalium-Argon-Untersuchungen an basischen tertiären Vulkaniten zwischen Westerwald und Vogelsberg

Between the upper tertiary volcanic areas of Westerwald and Vogelsberg (central Western Germany) occur more than 40 isolated tertiary volcanic dikes, eroded necks, plugs and domes. Twelve of these volcanic rocks have been investigated petrographically and chemically and classified by means of their modal and chemical composition. Additional modal analyses have been performed on seven other volcanics. On seventeen volcanic occurences K-Ar-whole rock age determinations have been made. The K-Ar age determinations yield- with the exception of an olivine-nephelinite — values between 27 and 15 Ma. Regarding the known intervals of volcanic activities of the Westerwald- and Voge1sberg-areas, most of the examined volcanics can be related genetically with one of the adjacent volcanic areas. There seems to be no geographical overlapping of volcanics showing Westerwaldages and Vogelsberg-ages. A possible influence of excess-Ar-bearing phases (e. g. mantle xenoliths) and an Ar-loss of constituent matter of the groundmass have been estimated by additional age determinations of enriched samples. These influences — partially compensating each other — may shift the K-Ar whole rock age to a maximum of 5 % and thus do not exceed the dimension of the standard deviations. A distinct NNE-SSW-striking fault in the region between Marburg and Gießen is situated parallel with the eastern border of the “Rheinisches Schiefergebirge”. Volcanics showing Westerwald-age and Vogelsberg-age respectively reach this fault, but obviously do not overlap it. Relations between rock-type an rock age, as it has been observed for the volcanics of the northern Hessian Depression (Kreuzer et al. 1973;Wedepohl 1982) cannot be proved certainly. On the other hand, similar to the basaltic rocks of the northern Hessian Depression, the youngest volcanic product is an olivine-nephelinite (9 Ma).     

Lithic fragments,glasses and chondrules from Luna 16 fines

Bulk compositions of igneous and microbreccia lithic fragments, glasses, and chondrules from Luna 16 fines as well as compositions of minerals in basaltic lithic fragments were determined with the electron microprobe. Igneous lithic fragments and glasses are divided into two groups, the anorthositic-noritic-troctolitic (hereafter referred to as ANT) and basaltic groups. Chondrules are always of ANT composition and microbreccia lithic fragments are divided into groups 1 and 2. The conclusions reached may be summarized as follows: (1) Luna 16 fines are more similar in composition to Apollo 11 than to Apollo 12 and 14 materials (e.g. Apollo 11 igneous lithic fragments and glasses fall into similar ANT and basaltic groups; abundant norites in Luna 16 and Apollo 11 are not KREEP as in Apollo 12 and 14; Luna 16 basaltic lithic fragments may represent high-K and low-K suites as is the case for Apollo 11; rare colorless to greenish, FeO-rich and TiO₂-poor glasses were found in both Apollo 11 and Luna 16; Luna 16 spinels are similar to Apollo 11 spinels but unlike those from Apollo 12). (2) No difference was noted in the composition of lithic fragments, glasses and chondrules from Luna 16 core tube layers A and D. (3) Microbreccia lithic fragments of group 1 originated locally by mixing of high proportions of basaltic with small proportions of ANT materials. (4) Glasses are the compositional analogs to the lithic fragments and not to the microbreccias; most glasses were produced directly from igneous rocks. (5) Glasses show partial loss of Na and K due to vaporization in the vitrification process. (6) Luna 16 chondrules have ANT but not basaltic composition. It is suggested that either liquid droplets of ANT composition are more apt to nucleate from the supercooled state; or basaltic droplets have largely been formed in small and ANT droplets in large impact events (in the latter case, probability for homogeneous and inhomogeneous nucleation is larger. (7) No evidence for ferric iron and water-bearing minerals was found. (8) Occurrence of a great variety of igneous rocks in Luna 16 samples (anorthosite, noritic anorthosite, anorthositic norite, olivine norite, troctolite, and basalt) confirm our earlier conclusion that large-scale melting or partial melting to considerable depth and extensive igneous differentiation must have occurred on the moon.     

Untersuchungen über die Trübungsverhältnisse,die Durchsichtigkeit und die Wasserfarbe in schweizerischen Gewässern

Zusammenfassung Im ersten, der Festlegung der theoretischen Grundlagen der Trübung gewidmeten Kapitel wird die Sinkgeschwindigkeit kleiner Teilchen auf Grund der Gesetze der ?Schwebetheorie? vonWesenberg-Lund, W. Ostwald sowie der Stokesschen Formel diskutiert. Ein weiteres Kapitel orientiert anhand bisheriger Kenntnisse über die Erscheinungen der Lichtdurchl?ssigkeit (bzw.-absorption) und des Lichtklimas in verschiedenen Tiefen unserer Seen. Die Trübung der in einer Reihe von Flu?systemen und Seen erhobenen W?sser wurde mittels der absoluten Messung im Pulfrich-Stufenphotometer festgestellt. Sodann wurden die analysierten Proben nach steigenden Trübungswerten geordnet und unterteilt in ?Klarseen?, ?mitteltrübe? und ?trübe? Seen. Schliesslich wurde zusammen mitH. Züllig der Grad der Trübung, der Transparenz und die Seefarbe zueinander in Beziehung gebracht, wobei unterschieden wird zwischen Seen, die a) durch vorwiegend anorganische Stoffe, b) durch vorwiegendOscillatoria-armes Plankton, c) durch vorwiegendOscillatoria rubescens getrübt sind. Die in mehreren Tabellen und Abbildungen wiedergegebenen Werte der Wassertrübung spiegeln die unterschiedlichen Verh?ltnisse wider, die sich im Laufe einer ausgedehnteren Flu?strecke oder in einem See ergeben aus der Mischung des verschieden stark mit Schwebestoffen belasteten Wassers von Haupt- und Nebenfluss, sodann aus der fortschreitenden oder von Strecke zu Strecke wechselnden Sedimentation, und natürlich auch von der lokalen oder regionalen Wetterlage (Niederschl?ge und Schneeschmelze). In ausgedehnten und zum Teil über Monate hinweg durchgeführten Sedimentationsversuchen im Laboratorium wurde schliesslich der Kl?rvorgang von W?ssern verschiedener Herkunft in Funktion der Zeit untersucht. Dabei ergaben sich unterschiedliche Kurven, die ein Bild zu vermitteln verm?gen über den mittleren Durchmesser der die Trübung verursachenden sedimentierbaren, anorganischen Partikeln.     

MELIMEX,an experimental heavy metal pollution study: Effects of increased heavy metal load on uptake of glucose by natural planctonic communities

Glucose uptake in lake water samples has been determined with short-time¹⁴C-experiments at different additions of the single heavy metals Cu⁺⁺, Zn⁺⁺, Cd⁺⁺, Pb⁺⁺, Hg⁺⁺ and at different additions of a combination of all metals. The degree of a metal induced inhibition of glucose uptake varied from lake to lake and from season to season, whereby the addition of legally tolerated concentrations of 10 μg Cu/l and 200 μg Zn/l inhibited glucose uptake in most samples significantly, as well as the simultaneous addition of all metals. The legally tolerated limit of 1 μg Hg/l inhibited glucose uptake in Lake Lucerne samples almost completely, showed however no effect in samples of Lake Baldegg. The equimolar toxicity sequence of heavy metals for heterotrophic microorganisms has been determined as: Hg>Cu>Cd>(Zn. Pb). Glucose uptake of plankton sampled from metal polluted limno-corrals was less inhibited than that of the control plankton, when heavy metals were added to the samples singly or in combination. It is assumed that this effect is due to the natural selection of more resistant plankton species.     

On the relation between residual currents and the wind field in the German Bight

Summary The long-period part (T>25 h) of currents measured at close spacing in the German Bight in June 1968 is investigated. The north component of the bottom current is shown to be highly correlated with the east component of the wind in this area, the wind-generated changes of the mass-field giving rise to a quasi-geostrophic current near the bottom.This current responds without perceptible delay to the variations of wind fields with periods considerably longer than those of the seiches of the North Sea. The accelerations linked to such long periods are so small as to be negligable and the residual currents can be regarded as quasi-stationary.

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Über die Beziehung zwischen Reststrom und Windfeld in der Deutschen Bucht

Zusammenfassung Es werden engabständige Strommessungen in der Deutschen Bucht aus dem Juni 1968 in ihrem langperiodischen Teil (T>25 h) untersucht. Dabei ergibt sich, daß die Nordkomponente des Bodenstromes (v) stark korreliert mit der Ostkomponente des Windes (U) in diesem Gebiet. Die winderzeugten Veränderungen des Massenfeldes verursachen eine quasi-geostrophische Strömung am Boden.Diese Strömung reagiert ohne erkennbare Verzögerung auf solche Veränderungen des Windfeldes, die erheblich größere Perioden haben als die Eigenschwingungen der Nordsee. Die damit verbundenen Beschleunigungen sind sehr klein und so zu vernachlässigen; daher kann man die Restströmung auch als quasi-stationär ansehen.

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Sur la relation entre les courants résiduels et le champ du vent en baie Allemande

Résumé La partie à longue période (T>25 h) de courants measurés en des points rapprochés en baie Allemande en juin 1968 est étudiée. La composante Nord du courant de fond se révèle largement corrélée avec la composante Est du vent dans cette zone. Les modifications du champ de masse dues au vent donnent naissance à un courant quasi-géostrophique près du fond.Ce courant répond sans délai perceptible aux variations du champ du vent avec des périodes considérablement plus longues que celles des seiches de la mer du Nord. Les accélérations liées à de telles longues périodes sont si petites qu'elles peuvent être négligées et les courants peuvent être considérés comme quasi-stationnaires.

     

Natural shock behavior of almandite in metamorphic rocks from the ries crater,Germany

An extensive study of a big number of gneiss specimens with various shock features from the suevite allowed unravelling of the shock behavior of almandite garnets.Almandites in shocked metamorphic rocks show with increasing dynamic pressures strong irregular fracturing. differently oriented sets of planar fractures or elements, brown turbidity and nucleation of minute crystals of an unknown phase in solid garnets. At higher peak pressures garnet was found to break down to (1) orthopyroxene + spinel + glass, and to (2) spinel + glass due to fast shock-melting.Extensive quantitative electron microprobe studies of almandite garnets and their breakdown products were carried out. The breakdown products within the original grain boundaries of the garnets consist of an alumina-rich orthopyroxene (with up to 10 wt. % Al₂O₃), hercynite to pleonaste spinels and a silica and calcium-rich glass matrix. The chemical zonation of magnesium and manganese of the former garnets is inherited in the composition of the newly formed orthopyroxenes.Petrographic evidence and chemical composition suggest a fast breakdown of the almandite garnets after passing of shock waves at rapidly falling pressures and very high post-shock temperatures within the ejected gneissic rock material.