Evaluation of coal as adsorbent for phosphate removal

This paper reports the adsorption of phosphate ions on coal, charcoal, and coal ash. The influences of factors such as contact time, and initial adsorbate concentration have been studied. Adsorption of phosphate ions on virgin coal was significant compared to charcoal, coal and coal ash evacuated at 200°C. The significant adsorption capability of coal is due to the porosity as well as due to organic carbon and inorganic elements present in coal. The evacuation of coal proved to be ineffective in enhancing its capability for phosphate ions retention. The adsorption behaviors of all the three adsorbent used was conformed using Freundlich’s adsorption model. The results suggest that coal could be used as an efficient adsorbent for removing phosphate ions from wastewater.     

An integrated approach for aquifer vulnerability mapping using GIS and rough sets: study from an alluvial aquifer in North India

A modified DRASTIC model in a geographic information system (GIS) environment coupled with an information-analytic technique called ‘rough sets’ is used to understand the aquifer vulnerability characteristics of a segment of the lower Kali watershed in western Uttar Pradesh, India. Since the region is a flat plain, topography (T) is removed as a potential control. Other parameters are the same as in DRASTIC, hence the new model is termed as DRASIC. The rough set technique is employed to provide insight into the relative vulnerabilities of different administrative units (blocks) within the study area. Using rough sets, three important factors are computed: strength, certainty and coverage. Strength indicates how the vulnerability characteristics vary in the entire area, certainty gives the relative fractions of low, medium and high vulnerability regions within a particular block, and coverage computes the percentage of a particular vulnerability state in each block. The purpose of the work is to demonstrate the utility of this integrated approach in classifying different administrative blocks in the study area according to their aquifer vulnerability characteristics. This approach is particularly useful for block-level planning and decision making for sustainable management of groundwater resources.     

Effect Of A Heat Island On The Meteorology Of A Complex Urban Airshed

A three-dimensional mesoscale model was used to study the effect of an urban heat island in a relatively complex situation. A heat emission inventory was carried out for an urban airshed thatincludes sources such as motor vehicles, waste heat from industries and electricity consumption. To demonstrate the relative significance of anthropogenic heat flux and variant surface characteristics, three model simulations were conducted. In the first simulation, anthropogenic heat flux was ignored and non-variant surface properties were considered for the entire modelling domain. In the second simulation, variant surface characteristics were considered. While in the third simulation, gridded anthropogenic heat flux and variant surface characteristic were utilised. From these experiments, it was inferred that an additional source of heat in urban areas can substantially affect the wind and temperature regime under light wind conditions. During the day, the anthropogenic heat flux has minimum effect on the urban temperature, however it magnifies the intensity of the convergence near the urban areas.     

Large scale mass movements triggered by the Kashmir earthquake 2005, Pakistan

The SPOT image analysis in Muzaffarabad Azad Kashmir,northwest Himalayas,Pakistan reveals that the Kashmir earthquake 2005 triggered a number of coseismic mass movements along the hanging wall block of the Muzaffarabad Fault.The Neelidandi and Langarpura rock falls have been identified as two major reactivated mass movements with an estimated volume of 3.1 × 106m3and 5.76 × 106m3,respectively.The Neelidandi and Langarpura mass movements were initiated during earthquake in the direction of northwest-southeast extension and northeastsouthwest directed thrusting,respectively.The Neelidandi rock fall occurred in sheared cherty dolomites and limestones of the Cambrian Muzaffarabad Formation,whereas the Langarpura rock fall occurred in alternating clays,shales,claystones,siltstones and sandstones of the Miocene Murree Formation.These rock units along the fault are highly fractured and jointed.The geotechnical maps and geological longitudinal profiles show the relationship between the geometrical characteristics and mechanism of these mass movements.Their characteristics were analyzed according to the role of topographic,seismic,geological and tectonic factors.The steep topography,sheared rocks,lithology,coseismic uplift and strong ground shaking of the hanging wall block along Muzaffarabad Fault facilitated the gravity collapse of these mass movements.     

Optimization and simulation of reservoir operation with sediment evacuation: a case study of the Tarbela Dam,Pakistan

Many reservoirs around the world are being operated based on rule curves developed without considering the evacuation of deposited sediment. Current reservoir simulation and optimization models fall short of incorporating the concept of sustainability because the reservoir storage losses due to sedimentation are not considered. This study develops a new model called Reservoir Optimization‐Simulation with Sediment Evacuation (ROSSE) model. The model utilizes genetic algorithm based optimization capabilities and embeds the sediment evacuation module into the simulation module. The sediment evacuation module is implemented using the Tsinghua university flushing equation. The ROSSE model is applied to optimize the rule curves of Tarbela Reservoir, the largest reservoir in Pakistan with chronic sedimentation problems. In the present study, rule curves are optimized for maximization of net economic benefits from water released. The water released can be used for irrigation, power production, sediment evacuation, and for flood control purposes. Relative weights are used to combine the benefits from these conflicting water uses. Nine sets of rule curves are compared, namely existing rule curves and proposed rule curves for eight scenarios developed for various policy options. These optimized rule curves show an increase of net individual economic benefits ranging from 9 to 248% over the existing rule curves. The shortage of irrigation supply during the simulation period is reduced by 38% and reservoir sustainability is enhanced by 28% through increased sediment evacuation. The study concludes that by modifying the operating policy and rule curves, it is possible to enhance the reservoir's sustainability and maximize the net economic benefits. The developed methodology and the model can be used for optimization of rule curves of other reservoirs with sedimentation problems. Copyright © 2008 John Wiley & Sons, Ltd.     

Ion-acoustic solitons in pair-ion plasma with non-thermal electrons

Properties of fully nonlinear ion-acoustic solitary waves in an unmagnetized and collisionless pair-ion (PI) plasma containing superthermal electrons obeying Cairns distribution have been analyzed. A linear biquadratic dispersion relation has been derived, which yields the fast (supersonic) and slow (subsonic) modes in a pair-ion-electron plasma with nonthermal electrons. For nonlinear analysis, Korteweg-de Vries equation is obtained using the reductive perturbation technique. It is found that in case of slow mode, both electrostatic hump and dip type structures are formed depending on the temperature difference between positively and negatively charged ions, whereas, only dip type solitary structures have been observed for fast mode. The present work may be employed to explore and to understand the formation of solitary structures in the space (especially, the Earth’s ionosphere where two distinct pair ion species (H ^±) are present) and laboratory produced pair-ion plasmas with nonthermal electrons.     

Magnetic tracing of sediment dynamics of mudbanks off southwest coast of India

In this study, we utilized environmental magnetic in combination with sedimentological and hydrodynamic data to investigate the formative processes of mudbanks along southwest coast of India. We document the linkages between enrichment of silt-sized magnetic particles and formation processes of mudbanks along Alappuzha coast. A trend of increasing magnetite concentration and coarsening in magnetic grain size is observed at mudbank stations M2 and M3, while the mud-deficient station (M1) showed an opposite trend. A strong relationship between magnetic and physical grain size for all samples implies that the magnetic particle size and clastic grain size are largely adjunct. Analysis of rock magnetic and grain size data of surficial and suspended sediments from non-mudbank (M1) and two mudbank stations (M2, M3) reflect the differential sediment partitioning and transport regimes which controlled the formation of mudbanks along Alappuzha coast. Two plausible mechanisms responsible for the formation of mudbanks are identified: grain size-selective entrainment is the dominant process during pre-monsoon; weaker hydrodynamics (waves and bottom currents) favors accumulation of silt-sized (fine and coarse) magnetic and non-magnetic fractions resulting in the formation of magnetically low-enriched sediment bed of mixed grain sizes. At the onset of monsoon, wave-induced energetic bottom currents enhance the suspension of entire sediment bedload at stations M2, M3 to form fluid mud. Concurrently, mineral-density-based selective fractionation allows the settling of coarse silt-sized magnetic particles, while the fine magnetic silt-size particles accumulate forming thick fluid mud as a suspension load resulting in the formation of mudbanks. An observed increase in magnetic susceptibility and coarsening in magnetic grain size of surficial sediments at mudbank stations (M2, M3) during monsoon period supports the interpretation. Our findings are summarized in a conceptual model which can be very well applied to investigate sediment dynamics associated with mudbank formation in coastal and shelf sedimentary systems.     

Electrostatic electron acoustic solitons in electron-positron-ion plasma with superthermal electrons and positrons

Properties of fully nonlinear electron-acoustic solitary waves in an unmagnetized and collisionless electron-positron-ion plasma containing cold dynamical electrons, superthermal electrons and positrons obeying Cairns’ distribution have been analyzed in the stationary background of massive positive ions. A linear dispersion relation has been derived, from which it is found that even in the absence of superthermal electrons, the superthermal positron component can provide the restoring force to the cold inertial electrons to excite electron-acoustic waves. Moreover, superthermal electron and positron populations seem to enhance the electron acoustic wave phase speed. For nonlinear analysis, Korteweg-de Vries equation is obtained using the reductive perturbation technique. It is found that in the presence of positron both hump and dip type solitons appear to excite. The present work may be employed to explore and to understand the formation of electron acoustic soliton structures in the space and laboratory plasmas with nonthermal electrons and positrons.     

Growth and decay of sonic discontinuities in non-equilibrium magnetogasdynamics

The phenomenon associated with sonic discontinuities in non-equilibrium magnetogasdynamics has been studied by the use of singular surface theory. The fundamental differential equations for growth and decay of sonic discontinuities have been formulated for general class of relaxing gas applying compatibility conditions for surface of discontinuity in continuum mechanics. This class of equations have been solved completely and for particular case of plane. We have also obtained the critical time at which sonic wave terminates in shock wave.     

SMART-1 mission description and development status

SMART-1 is the first of the Small Missions for Advanced Research in Technology of the ESA Horizons 2000 scientific programme. The SMART-1 mission is dedicated to testing of new technologies for future cornerstone missions, using Solar-Electric Primary Propulsion (SEPP) in Deep Space. The chosen mission planetary target is the Moon. The target orbit will be polar with the pericentre close to the South-Pole. The pericentre altitude lies between 300 and 2000 km, while the apocentre will extend to about 10,000 km. During the cruise phase, before reaching the Moon, the spacecraft thrusting profile allows extended periods for cruise science. The SMART-1 spacecraft will be launched in the spring of 2003 as an auxiliary passenger on an Ariane 5 and placed into a Geostationary Transfer Orbit (GTO). The expected launch mass is about 370 kg, including 19 kg of payload. The selected type of SEPP is a Hall-effect thruster called PPS-1350. The thruster is used to spiral out of the GTO and for all orbit maneuvers including lunar capture and descent. The trajectory has been optimised by inserting coast arcs and the presence of the Moon's gravitational field is exploited in multiple weak gravity assists.The Development Phase started in October 1999 and is expected to be concluded by a Flight Acceptance Review in January 2003. The short development time for this high technology spacecraft requires a concerted effort by industry, science institutes and ESA centres. This paper describes the mission and the project development status both from a technical and programmatic standpoint.