Defining the geochemical baseline: a case of Hong Kong soils

A geochemical baseline provides the means to distinguish between the pedogenic origin and the anthropogenic origin of the trace element in the environmental compartments. We collected 271 soil samples representative of different parent rocks and soil types from the whole territory of Hong Kong and analyzed the composition of clay mineralogy and the contents of 15 chemical elements (Fe, Cd, As, etc.) for these samples. The baseline was predicted with the method of the normalization procedure combined with the relative cumulative frequency curve. The result indicated that Fe was the best reference element for the normalization procedure among the five potential reference elements (Fe, Al, Sc, Ti, and Mn), followed by Sc and Ti. A poor correlation was found between Sc, Ti, and Cu. The predicted baseline was much lower than the A-value of the Dutch List used usually in screening the polluted soil of Hong Kong, implying that the extent of heavy metal pollution might have been underestimated with respect to local lands. We also applied the cluster analysis to distinguish the geochemical associations of the trace elements due to its importance to the baseline. Approximately three major associations including the Fe–Mn-oxides related, Al oxides or Al-bearing-clay-mineralogy related and sulfide- related associations were observed from the dendrogram.     

斜底面上的表面波理论

考察了任意倾斜底面上的Kelvin波问题，并用线性化的控制方程分别研究了相应于垂直刚壁的和无限倾斜底面上的表面波频散关系。文中还对任意斜坡上的浅水表面波做了尺度分析，并把决定其频散关系的特征值问题简化为该斜坡上气压扰动的常微分方程，且用数值方法进行了求解。     

Modeling the Population Effects of Hypoxia on Atlantic Croaker (<Emphasis Type="Italic">Micropogonias undulatus</Emphasis>) in the Northwestern Gulf of Mexico: Part 1—Model Description and Idealized Hypoxia

We developed a spatially explicit, individual-based model to analyze how hypoxia effects on reproduction, growth, and mortality of Atlantic croaker in the northwestern Gulf of Mexico lead to population-level responses. The model follows the hourly growth, mortality, reproduction, and movement of individuals on a 300 × 800 spatial grid of 1-km² cells for 140 years. Chlorophyll-a concentration, water temperature, and dissolved oxygen (DO) were specified daily for each grid cell and repeated for each year of the simulation. A bioenergetics model was used to represent growth, mortality was assumed stage- and age-dependent, and the movement behavior of juveniles and adults was modeled based on temperature and avoidance of low DO. Hypoxia effects were imposed using exposure effect submodels that converted time-varying exposures to low DO to reduced hourly growth, increased hourly mortality, and reduced annual fecundity. Results showed that 100 years of either mild or intermediate hypoxia produced small reductions in population abundance, while repeated severe hypoxia caused a 19% reduction in long-term population abundance. Relatively few individuals were exposed to low DO each hour, but many individuals experienced some exposure. The response was dominated by a 5% average reduction in annual fecundity of individuals. Under conditions of random sequences of mild, intermediate, and severe hypoxia years occurring in proportion to their historical frequency, the model predicted a 10% decrease in the long-term population abundance of croaker. A companion paper substitutes hourly DO values from a three-dimensional water quality model for the idealized hypoxia and results in a more realistic population reduction of about 25%.     

Hydrogeochemical exploration for Mississippi valley-type deposits, Arkansas, U.S.A.

Three areas located in northern Arkansas, U.S.A., representing differing host rock and mineralization, were selected to investigate the usefulness of hydrogeochemical exploration for Mississippi Valley-type Pb-Zn mineralization. Despite the geologic differences among the areas, there were no great differences in groundwater chemistry and threshold values. Anomalous Pb concentrations, and also anomalous Zn concentrations to a lesser extent, are useful in detecting the Pb-Zn mineralized areas; however, specific deposits could not be located. Because of the low threshold values (about 20 μg/1) for Pb and Zn, spring water must be utilized in order to avoid plumbing contamination.     

Evaluation of a Photosynthesis-Based Canopy Resistance Formulation in the Noah Land-Surface Model

Accurately representing complex land-surface processes balancing complexity and realism remains one challenge that the weather modelling community is facing nowadays. In this study, a photosynthesis-based Gas-exchange Evapotranspiration Model (GEM) is integrated into the Noah land-surface model replacing the traditional Jarvis scheme for estimating the canopy resistance and transpiration. Using 18-month simulations from the High Resolution Land Data Assimilation System (HRLDAS), the impact of the photosynthesis-based approach on the simulated canopy resistance, surface heat fluxes, soil moisture, and soil temperature over different vegetation types is evaluated using data from the Atmospheric Radiation Measurement (ARM) site, Oklahoma Mesonet, 2002 International H₂O Project (IHOP_2002), and three Ameriflux sites. Incorporation of GEM into Noah improves the surface energy fluxes as well as the associated diurnal cycle of soil moisture and soil temperature during both wet and dry periods. An analysis of midday, average canopy resistance shows similar day-to-day trends in the model fields as seen in observed patterns. Bias and standard deviation analyses for soil temperature and surface fluxes show that GEM responds somewhat better than the Jarvis scheme, mainly because the Jarvis approach relies on a parametrised minimum canopy resistance and meteorological variables such as air temperature and incident radiation. The analyses suggest that adding a photosynthesis-based transpiration scheme such as GEM improves the ability of the land-data assimilation system to simulate evaporation and transpiration under a range of soil and vegetation conditions.     

Prediction of ground vibration due to quarry blasting based on gene expression programming: a new model for peak particle velocity prediction

Blasting is a widely used technique for rock fragmentation in opencast mines and tunneling projects. Ground vibration is one of the most environmental effects produced by blasting operation. Therefore, the proper prediction of blast-induced ground vibrations is essential to identify safety area of blasting. This paper presents a predictive model based on gene expression programming (GEP) for estimating ground vibration produced by blasting operations conducted in a granite quarry, Malaysia. To achieve this aim, a total number of 102 blasting operations were investigated and relevant blasting parameters were measured. Furthermore, the most influential parameters on ground vibration, i.e., burden-to-spacing ratio, hole depth, stemming, powder factor, maximum charge per delay, and the distance from the blast face were considered and utilized to construct the GEP model. In order to show the capability of GEP model in estimating ground vibration, nonlinear multiple regression (NLMR) technique was also performed using the same datasets. The results demonstrated that the proposed model is able to predict blast-induced ground vibration more accurately than other developed technique. Coefficient of determination values of 0.914 and 0.874 for training and testing datasets of GEP model, respectively show superiority of this model in predicting ground vibration, while these values were obtained as 0.829 and 0.790 for NLMR model.     

Structural chemistry of synthetic cordierite: Evidence for solid solutions and disordered compositional domains in Bi-flux-grown Mg-cordierites

The structure, crystal chemistry, and microstructure of disordered and ordered Mg-cordierites synthesized in a bismuth oxide flux system have been studied by a combination of x-ray and neutron powder diffraction and quantitative x-ray microanalysis using analytical electron microscopy. Microchemical data obtained on Bi-flux cordierites using energy-dispersive x-ray analysis is interpreted through comparison with data collected on stoichiometric Mg₂Al₄Si₅O₁₈ glass and α- and β-cordierite samples synthesized by subsolidus crystallization of the glass. Bi-flux cordierites crystallize in both the hexagonal and orthorhombic polymorphs and contain 5 to 10 at% occupancy of bismuth on the C1 and C2 channel sites. The microstructure of Bi-flux α-cordierite is characterized by the existence of local domains of disordered cordierite solid solutions with variable composition and significant vacancy concentrations on the octahedral site. The β-cordierites have a more homogeneous microstructure but are still Al-deficient, Si-rich solid solutions.     

Fracture grouting and geonails for soft soil tunnelling

To stabilise the tunnel faces and slopes in soft clay for the Airport Link construction in Australia, fracture grouting and glass fibre-reinforced plastic (GFRP) soil nails are proposed for the soil improvement as well as ease of handling. The compensation caused by the fracture grouting and the gain in strength due to consolidation as well as the geonail have stabilised the soft clay during construction. Only a small amount of ground settlement during soft clay box-jacking operation is generated so that the railway traffic above the embankment can be maintained without interference. The design method of the fracture grouting ground improvement study for this difficult project is discussed in this paper. Extensive laboratory and field tests were employed to verify the design assumptions and to fine-tune the ground improvement studies. The success of this project in poor ground conditions results from combined efforts of extensive field tests, an improved ground improvement design method and a realistic numerical analysis to assess the unstable/highly stressed zones for the placement of soil reinforcement.     

Late Pleistocene to Holocene sedimentation and hydrocarbon seeps on the continental shelf of a steep,tectonically active margin,southern California,USA

Small, steep, uplifting coastal watersheds are prolific sediment producers that contribute significantly to the global marine sediment budget. This study illustrates how sedimentation evolves in one such system where the continental shelf is largely sediment-starved, with most terrestrial sediment bypassing the shelf in favor of deposition in deeper basins. The Santa Barbara–Ventura coast of southern California, USA, is considered a classic area for the study of active tectonics and of Tertiary and Quaternary climatic evolution, interpretations of which depend upon an understanding of sedimentation patterns. High-resolution seismic-reflection data over >570 km² of this shelf show that sediment production is concentrated in a few drainage basins, with the Ventura and Santa Clara River deltas containing most of the upper Pleistocene to Holocene sediment on the shelf. Away from those deltas, the major factor controlling shelf sedimentation is the interaction of wave energy with coastline geometry. Depocenters containing sediment 5–20 m thick exist opposite broad coastal embayments, whereas relict material (bedrock below a regional unconformity) is exposed at the sea floor in areas of the shelf opposite coastal headlands. Locally, natural hydrocarbon seeps interact with sediment deposition either to produce elevated tar-and-sediment mounds or as gas plumes that hinder sediment settling. As much as 80% of fluvial sediment delivered by the Ventura and Santa Clara Rivers is transported off the shelf (some into the Santa Barbara Basin and some into the Santa Monica Basin via Hueneme Canyon), leaving a shelf with relatively little recent sediment accumulation. Understanding factors that control large-scale sediment dispersal along a rapidly uplifting coast that produces substantial quantities of sediment has implications for interpreting the ancient stratigraphic record of active and transform continental margins, and for inferring the distribution of hydrocarbon resources in relict shelf deposits.