Paleomonsoon precipitation deduced from a sediment core from the equatorial Indian Ocean

Rapid shifts in past climate recorded in polar ice sheets have elicited various explanations relating to either thermohaline circulation changes by ice-rafting or natural greenhouse gas concentrations modulated by climatic conditions in the tropics. To compare the tropical paleoclimate record with the polar record, one must choose sediment cores from highly productive ocean regions. Necessarily, such regions reflect the wind records in the tropics, because high productivity is associated with upwelling driven by winds. Comparing tropical precipitation records with high-latitude records is, however, a more difficult task because sediments recording paleoprecipitation usually have low sedimentation rates, and offer coarser resolution relative to polar ice cores. Here, we present δ ¹⁸O data of three planktonic species of Foraminifera (a proxy for precipitation) from such a sediment core, spanning the past 35 ka for the equatorial Indian Ocean, which falls under the southwest monsoon (SWM) realm. Results show that minimum SWM precipitation occurred at the Last Glacial Maximum, with a subsequent increase at Termination IA. During the Holocene, SWM precipitation intensified uniformly up to the core top (∼2.2 ka b.p.), as revealed by generally decreasing δ ¹⁸O values. Variations in precipitation are consistent with climate changes recorded in polar ice sheets. Although the different resolutions of the two records preclude a rigorous comparison, abrupt cooling/warming events appear to be accompanied by sudden reduction/enhancement in (SWM) rainfall. Thus, mechanisms with time scales much shorter than a millennium, such as natural greenhouse warming (e.g., CH₄ concentration), controlled by emissions from the tropics, could have played a major role in high-latitude climate change.     

Organo- and lithofacies of glacial-interglacial deposits in the Norwegian-Greenland Sea: Responses to paleoceanographic and paleoclimatic changes

Based on a multiparameter approach a combined litho- and organofacies concept was developed for glacial and interglacial sediment sections along an E-W transect through the central part of the Norwegian-Greenland Sea (NGS).

Modern and past surface water regimes are clearly displayed by specific litho- and organofacies patterns. Interglacial conditions reveal specific Atlantic water associated lithofacies (A and B3) in the eastern and central sector of the Norwegian-Greenland Sea (NGS). Corresponding interglacial organofacies in general are not well correlated to lithofacies due to strong diagenetic degradation of labile, e.g. autochthonous organic matter (OM). While in near-surface sediments a marine-dominated organofacies (I-1) is preserved under Atlantic water masses, this correlation is not evident for lower Holocene and Isotope Stage 5 deposits. However, during Isotopic Event 5.5.1 increased proportions of marine OM are recorded in a high accumulating core on the Vøring Plateau. Glaciomarine background lithofacies (B and C) indicate minor input of ice rafted debris (IRD) and seasonal variable sea-ice cover. Corresponding organofacies (II-1, non-oxidized and II-2, oxidized) are dominated by allochthonous OM. Most spectacular are glacial diamictons (Lithofacies E and F) evidencing short-term sediment pulses due to a sudden disintegration of far advanced tide water ice margins on the outer shelves. These diamictons bear specific organofacies (III-1 and III-2) with a clear predominance of terrigenous and reworked OM.

Some of the diamictons seem to occur contemporaneous with the so called “Heinrich-layers” H1 and H2, suggesting a common trigger-mechanism for the almost simultaneous disintegration of huge continental ice masses along the shelves of North America and the eastern margin of the NGS.

Application of a combined organo- and lithofacies concept provides essential information on spatial and temporal variations of water mass characteristics, the oceanic effects of ice sheet dynamics and circulation models.     

Standard facies models to incorporate all heterogeneity levels in a reservoir model

The construction of reservoir models is frustrated by the fact that core and well cover only a fraction of the reservoir volume and it is therefore difficult to determine features like facies shape, -size, and -distribution, inter- and intra-facies boundaries and lateral trends from them. These features are, however, critical to fluid flow and they should necessarily be incorporated in the reservoir model and we therefore propose to systematically describe geometry and distribution of facies. To this end we make use of “standard facies models” that a priori contain all elements and boundaries of facies for a number of typical depositional environments.     

The effect of low level supplementary heating on diving duration

The exothermic reaction which proceeds when small sachets containing particulate mixtures of iron and magnesium are flooded with sea water, has been used for thermal support of free divers. Initial application of such generators to heating of the hands (Burton and Chan, 1981), and later extension to heating of the torso, have been described previously (Chan and Burton, 1981, 1982). Of considerable interest during field trials of the torso heating system was a strong subjective impression among those taking part, that significant increases of dive duration and decreases of perceived discomfort could be obtained with relatively low levels of power generation, for example less than 50% of that required for thermal balance. In this paper, a simple mathematical model of human stored heat loss is used to rationalize this observation. Also it successfully predicts voluntary exposure times of unheated divers who become cold. When used to estimate body heat debt, the model enables documented dives by this laboratory and by others, including recent exposures in Antarctica using low level supplementary heating, to be analysed.     

Distributions of dissolved and particulate biogenic thiols in the subartic Pacific Ocean

Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.     

Analysis of seawater for dissolved cadmium, copper and lead: An intercomparison of voltammetric and atomic absorption methods

An intercomparison study of voltammetric and atomic absorption spectrometric methods for determining cadmium, lead and copper in seawater samples was conducted. The voltammetric approach utilizes differential pulse anodic stripping voltammetry using a rotating, glassy carbon, mercury film electrode under conditions developed to minimize contamination sources and to enhance sensitivity for seawater matrices. The atomic absorption approach involves a concentration step using either an organic solvent extraction of metal dithiocarbamate chelates or a Chelex-100 column with detection by graphite furnace atomic absorption spectrometry. Similar and consistent results were obtained using both methods for the three trace metals studied on a wide range of natural seawater samples. Both methods are comparable in sensitivity for cadmium and copper, however the voltammetric method is better suited for the analysis of lead in seawater because of its enhanced sensitivity and low blank. An advantage of the voltammetric approach is its amenability towards real-time shipboard analysis.     

Bioerosion by chemosynthetic biological communities on Holocene submarine slide scars

Geomorphic, stratigraphic, and faunal observations of submarine slide scars that occur along the flanks of Monterey Canyon in 2.0–2.5 km water depths were made to identify the processes that continue to alter the surface of a submarine landslide scar after the initial slope failure. Deep-sea chemosynthetic biological communities and small caves are common on the sediment-free surfaces of the slide scars, especially along the headwall. The chemosynthetic organisms observed on slide scars in Monterey Canyon undergo a faunal succession based in part on their ability to maintain their access to the redox boundaries in the sediment on which they depend on as an energy source. By burrowing into the seafloor, these organisms are able to follow the retreating redox boundaries as geochemical re-equilibration occurs on the sole of the slide. As these organisms dig into the seafloor on the footwall, they often generate small caves and weaken the remaining seafloor. While chemosynthetic biological communities are typically used as indicators of fluid flow, these communities may be supported by methane and hydrogen sulfide that are diffusing out of the fresh seafloor exposed at the sole of the slide by the slope failure event. If so, these chemosynthetic biological communities may simply mark sites of recent seafloor exhumation, and are not reliable fluid seepage indicators.