A crustal seismic velocity model for the UK, Ireland and surrounding seas

A regional model of the 3-D variation in seismic P -wave velocity structure in the crust of NW Europe has been compiled from wide-angle reflection/refraction profiles. Along each 2-D profile a velocity–depth function has been digitised at 5 km intervals. These 1-D velocity functions were mapped into three dimensions using ordinary kriging with weights determined to minimise the difference between digitised and interpolated values. An analysis of variograms of the digitised data suggested a radial isotropic weighting scheme was most appropriate. Horizontal dimensions of the model cells are optimised at 40 × 40 km and the vertical dimension at 1 km. The resulting model provides a higher resolution image of the 3-D variation in seismic velocity structure of the UK, Ireland and surrounding areas than existing models. The construction of the model through kriging allows the uncertainty in the velocity structure to be assessed. This uncertainty indicates the high density of data required to confidently interpolate the crustal velocity structure, and shows that for this region the velocity is poorly constrained for large areas away from the input data.     

Optimum damping in linear isolation systems

Optimum isolation damping for minimum acceleration response of base-isolated structures subjected to stationary random excitation is investigated. Three linear models are considered to account for the energy dissipation mechanism of the isolation system: a Kelvin element, a linear hysteretic element and a standard solid linear element, commonly used viscoelastic models for isolation systems comprising natural rubber bearings and viscous dampers. The criterion selected for optimality is the minimization of the mean-square floor acceleration response. The effects of the frequency content of the excitation and superstructure properties on the optimum damping and on the mean-square acceleration response are addressed. The study basically shows that the attainable reduction in the floor acceleration largely depends on the energy dissipation mechanism assumed for the isolation system as well as on the frequency content of the ground acceleration process. Special care should be taken in accurately modelling the mechanical behaviour of the energy dissipation devices.     

Seismic response of heavily damped base isolation systems

The development of an efficient energy-dissipating mechanism that works in conjunction with laminated elastomeric bearings in order to reduce the lateral deformation of the isolation system has always been a goal of base isolation research. Theoretically, this deformation will be reduced to the minimum if damping augmentation of the isolation system can reach a critical value. However, augmenting the isolation damping may cause some unwanted side effects. The purpose of this paper is to study the influence of isolation damping on the seismic response of heavily damped base-isolated buildings. The base isolation system is assumed to be linearly viscoelastic and is analysed using the complex mode method. Solutions derived by using perturbation techniques for a two-degree-of-freedom system and the computer simulation for a multiple-degree-of-freedom system reveal that augmenting the isolation damping can reduce efficiently the deformation of the isolation system, but at the price of increasing the high-frequency vibration in the superstructure. When the damping ratio of the isolation system is beyond some level, increasing the isolation damping will enlarge the extreme values of the base and superstructural accelerations. It is also found that approximate solutions derived from the use of classical damping and classical modes of vibration in the seismic analysis of heavily damped base isolation systems can be substantially in error.     

X-ray absorption spectroscopy identifies calcium-uranyl-carbonate complexes at environmental concentrations

Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO₂-CO₃ complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO₂-CO₃ complex. Such a complex might exist even at high calcium concentrations, as some UO₂-CO₃ complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 μM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO₂-CO₃ complex to approximately 0.6 and enables spectroscopic identification of the Na-UO₂-CO₃ complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.     

Renewable energy strategies in England, Australia and New Zealand

The development of renewable energy sources is of prime interest to many countries seeking to pursue greenhouse gas emission reduction obligations. The increased use of renewables offers the possibility of not only contributing to emission reduction, but at the same time improving energy supply diversity and security, and developing employment and business in related supply industries. Two main mechanisms are in common use, one a quota (quantity) instrument often associated with tradable certificates, and the other a prescribed pricing mechanism. This paper considers the renewable energy development strategies of three countries (the UK, Australia, and New Zealand) all using a variant of the quota/certificate approach as the central instrument in their programs. The regulatory frameworks defining the application of the certificate systems differ notably, and the likely differing outcomes suggest that these regulatory settings may be at least as important as the selection of the basic policy instrument, in determining the overall success of programs of this nature.     

The C/CO ratio in B335 and the decaying dark matter neutrino hypothesis

C¹⁸O J  = 2–1, C¹⁷O J  = 2–1 and [C  I ] ³P₁–³P₀ emission from the dense cold cloud B335 has been observed and modelled in order to determine the C/CO ratio. The observed ratio is compared with a prediction by Tarafdar who assumes a mechanism in which the CO dissociation is caused by photons of energy ∼ 13.8 eV. These were postulated by Sciama to result from the decay of dark matter neutrinos. Our value for the C/CO ratio sets an upper limit to the strength of the neutrino decay dissociation process, thus providing a significant datum for interstellar chemistry theory.     

Magmatic and hydrothermal inclusions in carbonatite of the Magnet Cove Complex,Arkansas

The carbonatite at Magnet Cove, Arkansas, USA contains a great variety and abundance of magmatic and hydrothermal inclusions that provide an informative, though fragmentary, record of the original carbonatite melt and of late hydrothermal solutions which permeated the complex in postmagmatic time. These inclusions were studied by optical and scanning electron microscopy. Primary magmatic inclusions in monticellite indicate that the original carbonatite melt contained approximately 49.7 wt% CaO, 16.7% CO₂, 15.7% SiO₂, 11.4% H₂O, 4.4% FeO+Fe₂O₃, 1.1% P₂O₅ and 1.0% MgO. The melt was richer in SiO₂ and iron oxides than the carbonatite as now exposed; this is attributed to crystal settling and relative enrichment of calcite at shallower levels. The density of the carbonatite melt as revealed by the magmatic inclusions was approximately 2.2–2.3 g/cc. Such a light melt should separate rapidly from any denser parent material and could be driven forcibly into overlying crustal rocks by buoyant forces alone. Fluid inclusions in apatite suggest that a separate (immiscible) phase composed of supercritical CO₂ fluid of low density coexisted with the carbonatite magma, but the inclusion record in this mineral is inconclusive with respect to the nature of any other coexisting fluids. Maximum total pressure during CO₂ entrapment was about 450 bars, suggesting depths of 1.5 km or less for apatite crystallization and supporting earlier proposals of a shallow, subvolcanic setting for the complex. Numerous secondary inclusions in the Magnet Cove calcite contain an intriguing variety of daughter minerals including some 19 alkali, alkaline earth and rare earth carbonates, sulfates and chlorides few of which are known as macroscopic phases in the complex. The exotic fluids from which the daughter minerals formed are inferred to have cooled and diluted through time by progressive mixing with local groundwaters. These fluids may be responsible for certain late veins and elemental enrichments associated with the complex.     

Area and volume computation of longitude–latitude grids and three‐dimensional meshes

Longitude–latitude grids are commonly used for surface analyses and data storage in GIS. For volumetric analyses, three‐dimensional meshes perpendicularly raised above or below the gridded surface are applied. Since grids and meshes are defined with geographic coordinates, they are not equal area or volume due to convergence of the meridians and radii. This article compiles and presents known geodetic considerations and relevant formulae needed for longitude–latitude grid and mesh analyses in GIS. The effect of neglecting these considerations is demonstrated on area and volume calculations of ecological marine units.