Monitoring persistent organic pollutants in leatherback turtles (Dermochelys coriacea) confirms maternal transfer

To assess threats to endangered species, it is critical to establish baselines for contaminant concentrations that may have detrimental consequences to individuals or populations. We measured contaminants in blubber and fat from dead leatherback turtles and established baselines in blood and eggs in nesting turtles. In fat, blubber, blood and eggs, the predominant PCBs were 153 + 132, 187 + 182, 138 + 163, 118, and 180 + 193. Total PCBs, 4,4′-DDE, total PBDEs and total chlordanes were significantly and positively correlated between blood and eggs, suggesting maternal transfer. Significant positive relationships also existed between fat and blubber in stranded leatherbacks. Less lipophilic PCBs appeared to more readily transfer from females to their eggs. PBDE profiles in the four tissues were similar to other wildlife populations but different from some turtle studies. Concentrations were lower than those shown to have acute toxic effects in other aquatic reptiles, but may have sub-lethal effects on hatchling body condition and health.     

Gas emissions from failed and actual eruptions from Cook Inlet Volcanoes,Alaska, 1989–2006

Cook Inlet volcanoes that experienced an eruption between 1989 and 2006 had mean gas emission rates that were roughly an order of magnitude higher than at volcanoes where unrest stalled. For the six events studied, mean emission rates for eruptions were ∼13,000 t/d CO₂ and 5200 t/d SO₂, but only ∼1200 t/d CO₂ and 500 t/d SO₂ for non-eruptive events (‘failed eruptions’). Statistical analysis suggests degassing thresholds for eruption on the order of 1500 and 1000 t/d for CO₂ and SO₂, respectively. Emission rates greater than 4000 and 2000 t/d for CO₂ and SO₂, respectively, almost exclusively resulted during eruptive events (the only exception being two measurements at Fourpeaked). While this analysis could suggest that unerupted magmas have lower pre-eruptive volatile contents, we favor the explanations that either the amount of magma feeding actual eruptions is larger than that driving failed eruptions, or that magmas from failed eruptions experience less decompression such that the majority of H₂O remains dissolved and thus insufficient permeability is produced to release the trapped volatile phase (or both). In the majority of unrest and eruption sequences, increases in CO₂ emission relative to SO₂ emission were observed early in the sequence. With time, all events converged to a common molar value of C/S between 0.5 and 2. These geochemical trends argue for roughly similar decompression histories until shallow levels are reached beneath the edifice (i.e., from 20–35 to ∼4–6 km) and perhaps roughly similar initial volatile contents in all cases. Early elevated CO₂ levels that we find at these high-latitude, andesitic arc volcanoes have also been observed at mid-latitude, relatively snow-free, basaltic volcanoes such as Stromboli and Etna. Typically such patterns are attributed to injection and decompression of deep (CO₂-rich) magma into a shallower chamber and open system degassing prior to eruption. Here we argue that the C/S trends probably represent tapping of vapor-saturated regions with high C/S, and then gradual degassing of remaining dissolved volatiles as the magma progresses toward the surface. At these volcanoes, however, C/S is often accentuated due to early preferential scrubbing of sulfur gases. The range of equilibrium degassing is consistent with the bulk degassing of a magma with initial CO₂ and S of 0.6 and 0.2 wt.%, respectively, similar to what has been suggested for primitive Redoubt magmas.     

Influence of gusset plate connections and braces on the seismic performance of X‐braced frames

Braced frames are one of the most economical and efficient seismic resisting systems yet few full‐scale tests exist. A recent research project, funded by the National Science Foundation (NSF), seeks to fill this gap by developing high‐resolution data of improved seismic resisting braced frame systems. As part of this study, three full‐scale, two‐story concentrically braced frames in the multi‐story X‐braced configuration were tested. The experiments examined all levels of system performance, up to and including fracture of multiple braces in the frame. Although the past research suggests very limited ductility of SCBFs with HSS rectangular tubes for braces recent one‐story tests with improved gusset plate designs suggest otherwise. The frame designs used AISC SCBF standards and two of these frames designs also employed new concepts developed for gusset plate connection design. Two specimens employed HSS rectangular tubes for bracing, and the third specimen had wide flange braces. Two specimens had rectangular gusset plates and the third had tapered gusset plates. The HSS tubes achieved multiple cycles at maximum story drift ratios greater than 2% before brace fracture with the improved connection design methods. Frames with wide flange braces achieved multiple cycles at maximum story drift greater than 2.5% before brace fracture. Inelastic deformation was distributed between the two stories with the multi‐story X‐brace configuration and top story loading. Copyright © 2010 John Wiley & Sons, Ltd.     

Geomorphic and climatic change over the past 12,900 yr at Swiftcurrent Lake, Glacier National Park, Montana, USA

Glaciated alpine landscapes are sensitive to changes in climate. Shifts in temperature and precipitation can cause significant changes to glacier size and terminus position, the production and delivery of organic mass, and in the hydrologic energy related to the transport of water and sediment through proglacial environments. A sediment core representing a 12,900-yr record collected from Swiftcurrent Lake, located on the eastern side of Glacier National Park, Montana, was analyzed to assess variability in Holocene and latest Pleistocene environment. The spectral signature of total organic carbon content (%TOC) since ~ 7.6 ka matches that of solar forcing over 70-500 yr timescales. Periodic inputs of dolomite to the lake reflect an increased footprint of Grinnell Glacier, and occur during periods when sediment sinks are reduced, glacial erosion is increased, and hydrologic energy is increased. Grain size, carbon/nitrogen (C/N) ratios, and %TOC broadly define the termination of the Younger Dryas chronozone at Swiftcurrent Lake, as well as major Holocene climate transitions. Variability in core parameters is linked to other records of temperature and aridity in the northern Rocky Mountains over the late Pleistocene and Holocene.     

Physical properties of sediment from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

This study characterizes cored and logged sedimentary strata from the February 2007 BP Exploration Alaska, Department of Energy, U.S. Geological Survey (BPXA-DOE-USGS) Mount Elbert Gas Hydrate Stratigraphic Test Well on the Alaska North Slope (ANS). The physical-properties program analyzed core samples recovered from the well, and in conjunction with downhole geophysical logs, produced an extensive dataset including grain size, water content, porosity, grain density, bulk density, permeability, X-ray diffraction (XRD) mineralogy, nuclear magnetic resonance (NMR), and petrography.This study documents the physical property interrelationships in the well and demonstrates their correlation with the occurrence of gas hydrate. Gas hydrate (GH) occurs in three unconsolidated, coarse silt to fine sand intervals within the Paleocene and Eocene beds of the Sagavanirktok Formation: Unit D-GH (614.4 m-627.9 m); unit C-GH1 (649.8 m-660.8 m); and unit C-GH2 (663.2 m-666.3 m). These intervals are overlain by fine to coarse silt intervals with greater clay content. A deeper interval (unit B) is similar lithologically to the gas-hydrate-bearing strata; however, it is water-saturated and contains no hydrate.In this system it appears that high sediment permeability (k) is critical to the formation of concentrated hydrate deposits. Intervals D-GH and C-GH1 have average “plug” intrinsic permeability to nitrogen values of 1700 mD and 675 mD, respectively. These values are in strong contrast with those of the overlying, gas-hydrate-free sediments, which have k values of 5.7 mD and 49 mD, respectively, and thus would have provided effective seals to trap free gas. The relation between permeability and porosity critically influences the occurrence of GH. For example, an average increase of 4% in porosity increases permeability by an order of magnitude, but the presence of a second fluid (e.g., methane from dissociating gas hydrate) in the reservoir reduces permeability by more than an order of magnitude.     

Being beside the seaside: Beach use and preferences among coastal residents of south-eastern Australia

Beaches are the most popular recreational destinations in Australia yet how they are visited and valued by Australians is poorly known. We surveyed 385 people (13.8% of 2800 coastal residents) from south-eastern Australia to examine their use of beaches and the features that are important in their choice and enjoyment of a beach destination. Most respondents (90.3%) nominated beaches as one of their top three most valued natural recreational environments. Thirty-four recreational activities occurred at the beach (8.6 ± 0.3 [mean ± SE] activities per respondent), mostly walking (91.4%) and swimming (78.9%). Factor analyses revealed respondents valued clean, uncrowded beaches with opportunities to view wildlife (n = 338) but also desired facilities (e.g. toilets, shade, life savers, food outlets; n = 331). Difficult access and intrusive recreation activities (e.g. vehicles on beaches) detracted from people′s enjoyment. We describe a distinct dichotomy in use of ‘local’ versus ‘non-local’ beaches, where local beaches are visited more frequently, throughout more of the year, outside working hours and by smaller groups of people, compared with ‘non-local’ beaches. Coastal planners and managers not only face the challenge of increasing visitation to beaches but also the need to manage for somewhat conflicting values among beach-goers.     

Sediment trap and in-situ pump size-fractionated POC/234Th ratios in the Mediterranean Sea and Northwest Atlantic: Implications for POC export

Measurements of particle size-fractionated POC/²³⁴Th ratios and ²³⁴Th and POC fluxes were conducted using surface-tethered, free-floating, sediment traps and large-volume in-situ pumps during four cruises in 2004 and 2005 to the oligotrophic eastern Mediterranean Sea and the seasonally productive western Mediterranean and northwest Atlantic. Analysis of POC/²³⁴Th ratios in sediment trap material and 10, 20, 53, 70, and 100 μm size-fractionated particles indicate, for most stations, decreasing ratios with depth, a weak dependence on particle size, and ratios that converge to ～1–5 μmol dpm^?1 below the euphotic zone (～100–150 m) throughout the contrasting biogeochemical regimes. In the oligotrophic waters of the Aegean Sea, ²³⁴Th and POC fluxes estimated using sediment traps were consistently higher than respective fluxes estimated from water-column ²³⁴Th–²³⁸U disequilibrium, observations that are attributed to terrigenous particle scavenging of ²³⁴Th. In the more productive western Mediterranean and northwest Atlantic, ²³⁴Th and POC fluxes measured by sediment trap and ²³⁴Th–²³⁸U disequilibrium agreed within a factor of 2–4 throughout the water column. An implication of these results is that estimates of POC export by sediment traps and ²³⁴Th–²³⁸U disequilibrium can be biased differently because of differential settling speeds of POC and ²³⁴Th-carrying particles.     

An atmospheric blast/thermal model for the formation of high‐latitude pedestal craters

Abstract— Although tenuous, the atmosphere of Mars affects the evolution of impact‐generated vapor. Early‐time vapor from a vertical impact expands symmetrically, directly transferring a small percentage of the initial kinetic energy of impact to the atmosphere. This energy, in turn, induces a hemispherical shock wave that propagates outward as an intense airblast (due to high‐speed expansion of vapor) followed by a thermal pulse of extreme atmospheric temperatures (from thermal energy of expansion). This study models the atmospheric response to such early‐time energy coupling using the CTH hydrocode written at Sandia National Laboratories. Results show that the surface surrounding a 10 km diameter crater (6 km “apparent” diameter) on Mars will be subjected to intense winds (?200 m/s) and extreme atmospheric temperatures. These elevated temperatures are sufficient to melt subsurface volatiles at a depth of several centimeters for an ice‐rich substrate. Ensuing surface signatures extend to distal locations (?4 apparent crater diameters for a case of 0.1% energy coupling) and include striations, thermally armored surfaces, and/or ejecta pedestals—all of which are exhibited surrounding the freshest high‐latitude craters on Mars. The combined effects of the atmospheric blast and thermal pulse, resulting in the generation of a crater‐centered erosion‐resistant armored surface, thus provide a new, very plausible formation model for high‐latitude Martian pedestal craters.