The loss of the chemical tanker Ievoli Sun in the English Channel,October 2000

A chemical product tanker, The Ievoli Sun, was abandoned and later sank approximately 11 miles NW of Alderney in the English Channel in October 2000. The vessel carried a mixed cargo comprising 4000 tonnes of styrene, and 1000 tonnes each of methyl ethyl ketone and isopropyl alcohol. These chemicals are of low to moderate toxicity to aquatic life, are not persistent and have a low potential for bio-accumulation. Both of the solvents are miscible in water, whilst styrene is practically insoluble and, following release, it will rise to the sea surface and rapidly evaporate. More than 1000 tonnes of styrene are believed to have been lost to sea during the incident, resulting in an aerial plume of vapour which crossed Alderney and episodic contamination of air and water in the immediate vicinity of the wreck site. Analysis of edible tissues using coupled gas chromatography/mass spectrometry demonstrated low-level styrene contamination of crabs recovered from pots laid very close to the wreck site prior to the incident. These concentrations posed no risks to human consumers, and no fishery controls were implemented. The remainder of the styrene and the ship's main bunker fuel were recovered from the wreck on the seabed, whilst the two chemical solvents were released to the water column in a slow, controlled manner.     

Recent climatic change,greenhouse gas emissions and future climate: The implications for India

Summary In this paper, we discuss past climatic trends over India, greenhouse gas emissions due to energy consumption, forest and land-use changes, climate change scenarios for the year 2050, potential consequences for agriculture and cyclone activity and the possibility that India might limit the increasing trend in its emissions.India's mean surface air temperature has increased significantly by about 0.4°C over the past ccntury. Neither monsoon nor annual rainfall shows any significant trend. On average, there has been a rise in sea levels around India over recent decades, though considerable uncertainties exist in the accuracy and interpretation of the available data.Carbon emissions from the energy sector amount to 71 MT a year, equivalent to all other sectors combined. From land-use data, a marginal net sequestration of 5.25 million tonnes of carbon occurred during 1986. Following the IPCC guidelines, methane emissions from rice and livestock are estimated at 17.4 and 12.8 Tg/year, respectively.According to recent climate model projections, India may experience a further rise in temperature of 1 °C by the year 2050, about four times the rate of warming experienced over the past 100 years. A modest increase in precipitation amounts might occur. Cereals production is estimated to decrease and the nutrition security of the population-rich but land-hungry region of India might be hampered. An increase in local tropical cyclone activity may occur over thc next century, posing added problems as large areas in the coastal regions have a dense population.About 70% of the electricity generation in India is from coal-based power stations. Altering this dependence significantly to reduce emissions would imply a substantial change in the present energy policy of India. There is great potential for improving energy efficiency and conservation. The adoption of cleaner coal-technologies should be considered, as must the development of renewable, non-conventional energy sources. In all cases, serious institulional barriers and resource limitations need to be addressed. The scope for carbon sequestration is limiled by land availabilily and other factors. It is argued that any response to global warming must be located firmly in the framework of sustainable development.With 5 Figures     

Non-classical damping in dynamic analysis of base-isolated structures with internal equipment

It has been shown that the use of base isolation not only attenuates the response of a primary structural system but also reduces the response of a secondary system mounted on or within the main structure. The isolation system, superstructure and equipment may be made of different materials with significantly different energy dissipation characteristics such that the damping matrix for the combined system is non-classical and can only be approximately expressed by modal damping ratios if the classical mode method is used for analysis. The object of this paper is to evaluate the accuracy of this procedure in approximating the responses of base-isolated structures and internal equipment. The complex mode method can provide exact solutions to problems with non-classical damping and is used here to find the exact response of the isolation-superstructure-equipment system. The entire system is assumed to be linear elastic with viscous damping and the superstructure is assumed to be proportionally damped so that the deformation of the superstructure can be expressed in terms of its classical modes. Recognizing that the ratio of the equipment mass to the structural mass and the ratio of the stiffness of the isolation system to the superstructural stiffness are both small, perturbation methods are used to find the response. This study shows that the response of base-isolated structures can be determined by the classical mode method to some degree of accuracy, but the higher frequency content is distorted. The equipment response derived by the classical mode method is much smaller than the exact solution so that the complex mode method should be applied to find equipment response.     

Seismic response of the superstructure and attached equipment in a base-isolated building

Base isolation can be used both to protect the structure and simultaneously to reduce the response of internal equipment. The seismic response of a base-isolated structure has been studied through the shaking table test or numerical calculation before. The object of this paper is to analyse a base-isolated structure by a different analytical approach—perturbation analysis. Recognizing that the horizontal stiffness of an isolation system is much smaller than that of the superstructure, the mathematical expressions of the modal properties of base-isolated structures are derived by the perturbation method in terms of the modal properties of the superstructure and used to study the dynamic response of superstructure and attached equipment in the base-isolated building. This study shows that the first base-isolated mode not only controls the superstructural response but also dominates the response of high-frequency attachment. The contribution of higher modes to the response of base-isolated structures, which is proportional to the horizontal stiffness of isolation system, is very small.     

Pollutant transport in a shallow unconfined aquifer in Perry,Ohio

The groundwater system in northern Perry Township in Lake County, Ohio, is a shallow, unconfined aquifer consisting of periglacial lake beach deposits and less permeable lacustrine plain deposits. Groundwater flow is generally toward Lake Erie from south to north and is controlled by the top of the Ashtabula Till, but strong, local variations are caused by northward flowing streams During the study period, water levels in most wells exhibited a seasonal fluctuation of less than 0 3 m from their mean values. The areal distributions of chloride and nitrate concentrations indicate that road salt runoff easily infiltrates the aquifer and that nitrate may be sourced from fertilizer application. Ground-water flow and solute transport models indicate that in excess of 27 years are required to obtain chemical steady-state under hydrologic steady-state conditions. The simulations also demonstrate that nitrate loading must occur in more than one cultivated field in order to obtain the observed wide-spread nitrate distribution.     

Nitrate and herbicide loading in two groundwater basins of Illinois'' sinkhole plain

This investigation was designed to estimate the mass loading of nitrate (NO₃⁻) and herbicides in spring water discharging from groundwater basins in an agriculturally dominated, mantled karst terrain. The loading was normalized to land use and NO₃⁻ and herbicide losses were compared to estimated losses in other agricultural areas of the Midwestern USA. Our study area consisted of two large karst springs that drain two adjoining groundwater basins (total area of 37.7 km²) in southwestern Illinois' sinkhole plain, USA. The springs and stream that they form were monitored for almost 2 years. Nitrate–nitrogen (NO₃–N) concentrations at three monitoring sites were almost always above the background concentration (1.9 mg/l). NO₃–N concentrations at the two springs ranged from 1.08 to 6.08 with a median concentration of 3.61 mg/l. Atrazine and alachlor concentrations ranged from <0.01 to 34 μg/l and <0.01 to 0.98 μg/l, respectively, with median concentrations of 0.48 and 0.12 μg/l, respectively. Approximately 100,000 kg/yr of NO₃–N, 39 kg/yr of atrazine, and 2.8 kg/yr of alachlor were discharged from the two springs. Slightly more than half of the discharged NO₃⁻ came from background sources and most of the remainder probably came from fertilizer. This represents a 21–31% loss of fertilizer N from the groundwater basins. The pesticide losses were 3.8–5.8% of the applied atrazine, and 0.05–0.08% of the applied alachlor. The loss of atrazine adsorbed to the suspended solid fraction was about 2 kg/yr, only about 5% of the total mass of atrazine discharged from the springs.     

The influence of sampling design on spatial data quality in a geographic citizen science project

Geographic citizen science has much potential to assist in wildlife research and conservation, but the quality of observation data is a key concern. We examined the effects of sampling design on the quality of spatial data collected for a koala citizen science project in Australia. Data were collected from three samples—volunteers (n = 454), an Internet panel (n = 103), and landowners (n = 35)—to assess spatial data quality, a dimension of citizen science projects rarely considered. The locational accuracy of koala observations among the samples was similar when benchmarked against authoritative data (i.e., an expert‐derived koala distribution model), but there were differences in the quantity of data generated. Fewer koala location data were generated per participant by the Internet panel sample than the volunteer or landowner samples. Spatial preferences for land uses affecting koala conservation were also mapped, with landowners more likely to map locations for residential and tourism development and volunteers less likely. These spatial preferences have the potential to influence the social acceptability of future koala conservation proposals. With careful sampling design, both citizen observations and land use preferences can be included within the same project to augment scientific assessments and identify conservation opportunities and constraints.