Pressure dependence on partition coefficients for trace elements between olivine and the coexisting melts

Partition coefficients between olivine and melt at upper mantle conditions, 3 to 14 GPa, have been determined for 27 trace elements (Li, Be, B, Na, Mg, Al, Si, P, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Rb, Sr, Y, Zr, Cs, Ba, La and Ce) using secondary-ion mass-spectrometry (SIMS) and electron-probe microanalysis (EPMA). The general pattern of olivine/melt partitioning on Onuma diagrams resembles those reported previously for natural systems. This agreement strongly supports the argument that partitioning is under structural control of olivine even at high pressure. The partition coefficients for mono- and tri-valent cations show significant pressure dependence, both becoming larger with pressure, and are strongly correlated with coupled substitution into cation sites in the olivine structure. The dominant type of trace element substitution for mono- and tri-valent cations into olivine changes gradually from (Si, Mg)↔(Al, Cr) at low pressure to (Si, Mg)↔(Al, Al) and (Mg, Mg)↔(Na, Al) at high pressure. The change in substitution type results in an increase in partition coefficients of Al and Na with pressure. An inverse correlation between the partition coefficients for divalent cations and pressure has been observed, especially for Ni, Co and Fe. The order of decreasing rate of partition coefficient with pressure correlates to strength of crystal field effect of the cation. The pressure dependence of olivine/melt partitioning can be attributed to the compression of cation polyhedra induced by pressure and the compensation of electrostatic valence by cation substitution. Received: March 6, 1997 / Revised, accepted: March 12, 1998     

Micro-X-ray fluorescence-based comparison of skeletal structure and P, Mg, Sr, O and Fe in a fossil of the cold-water coral Desmophyllum sp., NW Pacific

Micro-scale distributions of trace and minor elements in, for example, coral skeletons are crucial as geochemical tracers of past environmental conditions, because they have the inherent advantage of accounting for confounding diagenetic and physiological effects. To extract reproducible paleoceanographic records from coral skeletons, a selective measurement of specific ultrastructures at high spatial resolution is required. Compared to warm-water reef-building corals, such data are limited in cold-water corals and, to the best of the authors’ knowledge, the latter have to date not been examined by means of micro-X-ray fluorescence. This technique was used for micrometer-scale imaging of P, Mg, Sr, O, and Fe intensities (counts per unit time) in a fossil specimen (as yet unknown age) of the cold-water coral Desmophyllum sp. from surface sediments of the NW Pacific. Cross plots confirmed that the micro-XRF signals were associated with corresponding trends in elemental concentration (ppm). Two major structural components of the septum—centers of calcification (COCs) and the surrounding fibrous aragonite portion—differed in composition. The COCs were characterized by higher intensities of P and Mg (650 and 220 counts per 5 s, respectively), and lower intensities of Sr (2,800) and O (580; corresponding values for the fibrous aragonite are 370, 180, 3,300 and 620 counts per 5 s, respectively). Oxygen intensity values were mostly homogeneous, but slightly lower in COCs and substantially higher in a well-defined patch in the fibrous aragonite. The mostly homogeneous P signals in the fibrous aragonite confirm the utility of this structural component and of coral septa in general for tracer studies of oceanic P. Nevertheless, spot occurrences of elevated P (>950 counts per 5 s) spanning tens of micrometers in specific parts of the fibrous region of the septum would cause overestimates of oceanic P, and should evidently not be overlooked in future research. The distribution of Fe showed no correlation with P, indicating no significant contamination in the form of P-bearing diagenetic ferromanganese precipitates. Such hotspots plausibly reflect the presence of other mineral phases, such as crystalline hydroxylapatite inclusions or contamination with organic material. The P signal intensity was positively correlated with Mg (r=0.553, p<0.001), and negatively with Sr (r=–0.489, p<0.001) and O (r=–0.311, p<0.001). There was no discernible evidence of control by water temperature in the Sr distribution pattern. These findings establish micro-X-ray fluorescence as a highly suitable pre-screening tool in cold-water coral sclerochronology, which can serve to refine sampling strategies without sample damage, and complement other micrometer-scale spatial distribution analyses of elements (notably, Ca) based on well-known approaches involving micro-milling, electron microprobes, secondary ion mass spectrometry, and laser ablation.     

A high-resolution ocean-atmosphere coupled downscaling of the present climate over California

A fully coupled regional ocean-atmosphere model system that consists of the regional spectral model and the regional ocean modeling system for atmosphere and ocean components, respectively, is applied to downscale the present climate (1985–1994) over California from a global simulation of the Community Climate System Model 3.0 (CCSM3). The horizontal resolution of the regional coupled modeling system is 10 km, while that of the CCSM3 is at a spectral truncation of T85 (approximately 1.4°). The effects of the coupling along the California coast in the boreal summer and winter are highlighted. Evaluation of the sea surface temperature (SST) and 2-m air temperature climatology shows that alleviation of the warm bias along the California coast in the global model output is clear in the regional coupled model run. The 10-m wind is also improved by reducing the northwesterly winds along the coast. The higher resolution coupling effect on the temperature and specific humidity is the largest near the surface, while the significant impact on the wind magnitude appears at a height of approximately 850-hPa heights. The frequency of the Catalina Eddy and its duration are increased by more than 60 % in the coupled downscaling, which is attributed to enhanced offshore sea-breeze. Our study indicates that coupling is vital to regional climate downscaling of mesoscale phenomena over coastal areas.     

Projected climate change scenario over California by a regional ocean–atmosphere coupled model system

This study examines a future climate change scenario over California in a 10-km coupled regional downscaling system of the Regional Spectral Model for the atmosphere and the Regional Ocean Modeling System for the ocean forced by the global Community Climate System Model version 3.0 (CCSM3). In summer, the coupled and uncoupled downscaled experiments capture the warming trend of surface air temperature, consistent with the driving CCSM3 forcing. However, the surface warming change along the California coast is weaker in the coupled downscaled experiment than it is in the uncoupled downscaling. Atmospheric cooling due to upwelling along the coast commonly appears in both the present and future climates, but the effect of upwelling is not fully compensated for by the projected large-scale warming in the coupled downscaling experiment. The projected change of extreme warm events is quite different between the coupled and uncoupled downscaling experiments, with the former projecting a more moderate change. The projected future change in precipitation is not significantly different between coupled and uncoupled downscaling. Both the coupled and uncoupled downscaling integrations predict increased onshore sea breeze change in summer daytime and reduced offshore land breeze change in summer nighttime along the coast from the Bay area to Point Conception. Compared to the simulation of present climate, the coupled and uncoupled downscaling experiments predict 17.5 % and 27.5 % fewer Catalina eddy hours in future climate respectively.     

A conceptual hydrogeological model of ophiolitic aquifers (serpentinised peridotite): The test example of Mt. Prinzera (Northern Italy)

The main aim of this study is the experimental analysis of the hydrogeological behaviour of the Mt. Prinzera ultramafic massif in the northern Apennines, Italy. The analysed multidisciplinary database has been acquired through (a) geologic and structural survey; (b) geomorphologic survey; (c) hydrogeological monitoring; (d) physico‐chemical analyses; and (e) isotopic analyses. The ultramafic medium is made of several lithological units, tectonically overlapped. Between them, a low‐permeability, discontinuous unit has been identified. This unit behaves as an aquitard and causes a perched groundwater to temporary flow within the upper medium, close to the surface. This perched groundwater flows out along several structurally controlled depressions, and then several high‐altitude temporary springs can be observed during recharge, together with several perennial basal (i.e., low altitude) springs, caused by the compartmentalisation of the system because of high‐angle tectonic discontinuities.     

Probabilistic estimates of future changes in California temperature and precipitation using statistical and dynamical downscaling

Sixteen global general circulation models were used to develop probabilistic projections of temperature (T) and precipitation (P) changes over California by the 2060s. The global models were downscaled with two statistical techniques and three nested dynamical regional climate models, although not all global models were downscaled with all techniques. Both monthly and daily timescale changes in T and P are addressed, the latter being important for a range of applications in energy use, water management, and agriculture. The T changes tend to agree more across downscaling techniques than the P changes. Year-to-year natural internal climate variability is roughly of similar magnitude to the projected T changes. In the monthly average, July temperatures shift enough that that the hottest July found in any simulation over the historical period becomes a modestly cool July in the future period. Januarys as cold as any found in the historical period are still found in the 2060s, but the median and maximum monthly average temperatures increase notably. Annual and seasonal P changes are small compared to interannual or intermodel variability. However, the annual change is composed of seasonally varying changes that are themselves much larger, but tend to cancel in the annual mean. Winters show modestly wetter conditions in the North of the state, while spring and autumn show less precipitation. The dynamical downscaling techniques project increasing precipitation in the Southeastern part of the state, which is influenced by the North American monsoon, a feature that is not captured by the statistical downscaling.     

Solar-cycle evolution of the coronal general magnetic field of 1959–1974 and the synchronous variation of high-speed solar wind streams and galactic cosmic rays

The simultaneous enhancement or subsidence of both the high-speed solar wind streams and the galactic cosmic rays in the minimum or the maximum phase of the solar cycle are interpreted in a unified manner by the concept of geometrical evolution of the general magnetic field of the corona-heliomagnetosphere system. The coronal general magnetic field evolves from an open dipole-like configuration in the minimum phase to a closed configuration with many loop-like formations in the maximum phase of the solar cycle. This concept, developed in a theoretical solar-cycle model driven by the dynamo action of the global convection, is examined and found to be valid by studying the evolution of the coronal general magnetic field calculated from the observed surface general magnetic field of 1959–1974. It is also found that the energy density of the poloidal component of the general surface field, from which the coronal field originates, attained a maximum in the maximum phase and showed a evolution with virtually no phase delay with respect to that of the toroidal component of the field, to which the sunspot activity is related. The subsidence of the high-speed solar wind in the maximum phase is understood as a braking of the solar wind streams by the tightly closed and strong coronal field lines in the lower corona in the maximum phase. The field lines of the heliomagnetosphere, which originate from the coronal field lines drawn by the solar wind, are inferred to be also more tightly closed at the heliopause in the maximum phase than in the minimum phase. The decrease of the galactic cosmic rays in the maximum phase (known as the Forbush's negative correlation between the galactic cosmic ray intensity and the solar activity or the Forbush solar-cycle modulation of the galactic cosmic rays) is interpreted as a braking of the cosmic rays by the closed magnetic field lines at the heliopause. The observed phase lag (approximately one year) of the galactic cosmic ray modulation with respect to the evolution of the solar cycle, and the observed absence of the gradient of the total cosmic ray intensity between 1 AU and 8 AU, are discussed to support this view of the cosmic ray modulation at the remote heliopause, and reject other hypotheses to explain the phenomenon in terms of the magnetic irregularities of various kinds carried by the solar wind: The short-term Forbush decrease at a time of a flare shows that the magnetic irregularities can react on the cosmic rays relatively near the Sun if they even played a dominant role in the long-term modulation. The concept of the general magnetic field of the corona and the surface is also used to understand the basic nature of the surface field itself, by comparing the geometry of the calculated coronal field lines with the eclipse photographs of the corona, and by discussing, in the context of the coronal general magnetic field associated with the solar cycle, the process of the emergence of the coronal field lines from the interior and the formation of the transequatorial arches and loops connecting the two hemispheres in the corona.     

Relationship of topography to surface water chemistry with particular focus on nitrogen and organic carbon solutes within a forested watershed in Hokkaido,Japan

We studied the relationships between streamwater chemistry and the topography of subcatchments in the Dorokawa watershed in Hokkaido Island, northern Japan, to examine the use of topography as a predictor of streamwater chemistry in a watershed with relatively moderate terrain compared with other regions of Japan. Topographic characteristics of the Dorokawa watershed and its subcatchments were expressed as topographic index (TI) values, which ranged from 4·5 to 20·4 for individual grid cells (50 × 50 m²), but averaged from 6·4 to 7·4 for the 20 subcatchments. Streamwater samples for chemical analyses were collected four times between June and October 2002 from 20 locations in the watershed. The pH of water that passed through the watershed increased from ～5·0 to 7·0, with major increases in Na⁺ and Ca²⁺ and marked decreases in NO₃^? and SO . Distinctive spatial patterns were observed for dissolved organic carbon (DOC), dissolved organic nitrogen (DON), and NO₃^? concentrations of streamwater across the watershed. Statistical analyses indicated significant linear relationships between the average TI values of subcatchments and DOC, DON, and NO₃^? concentrations. Furthermore, the proportion of DOC in streamwaters in the wet season increased with TI values relative to other nitrogen species, whereas NO₃^? concentrations decreased with TI. The gradients of soil wetness and the presence of wetlands explained many of the observed spatial and temporal patterns of DOC, DON, and NO₃^? concentrations in the surface waters of the Dorokawa watershed. Our results suggest that the TI is especially useful for predicting the spatial distribution of DOC, DON and NO₃^? in the surface waters of Hokkaido, where topographical relief is moderate and wetlands more common than in other regions of Japan. Copyright © 2006 John Wiley & Sons, Ltd.     

Linking Individual and Collective Agency for Enhancing Community Resilience in Northern Ghana

This article aims to explore the relationship between individual adaptive actions and enhancement of community resilience to climate change as a communal objective. It proposes to pay attention to the concept of reflexivity as the primary individual capacity to link adaptive actions and community resilience. Drawing on the field research conducted in northern Ghana in 2015, this article specifically examines life histories of four small farmers and shows that they individually take adaptive actions and reflect on these actions. However, little opportunity exists for them to systematically communicate the reflections with others to learn from their experiences, nurture collective agency and enhance community resilience. The article concludes by outlining new strategies needed to facilitate the communication in particular cultural and policy contexts.