Periglacial landscape evolution and environmental changes of Arctic lowland areas for the last 60 000 years (western Laptev Sea coast, Cape Mamontov Klyk)

Non-glaciated Arctic lowlands in north-east Siberia were subjected to extensive landscape and environmental changes during the Late Quaternary. Coastal cliffs along the Arctic shelf seas expose terrestrial archives containing numerous palaeoenvironmental indicators (e.g., pollen, plant macro-fossils and mammal fossils) preserved in the permafrost. The presented sedimentological (grain size, magnetic susceptibility and biogeochemical parameters), cryolithological, geochronological (radiocarbon, accelerator mass spectrometry and infrared-stimulated luminescence), heavy mineral and palaeoecological records from Cape Mamontov Klyk record the environmental dynamics of an Arctic shelf lowland east of the Taymyr Peninsula, and thus, near the eastern edge of the Eurasian ice sheet, over the last 60 Ky. This region is also considered to be the westernmost part of Beringia, the non-glaciated landmass that lay between the Eurasian and the Laurentian ice caps during the Late Pleistocene. Several units and subunits of sand deposits, peat–sand alternations, ice-rich palaeocryosol sequences (Ice Complex) and peaty fillings of thermokarst depressions and valleys were presented. The recorded proxy data sets reflect cold stadial climate conditions between 60 and 50 Kya, moderate inderstadial conditions between 50 and 25 Kya and cold stadial conditions from 25 to 15 Kya. The Late Pleistocene to Holocene transition, including the Allerød warm period, the early to middle Holocene thermal optimum and the late Holocene cooling, are also recorded. Three phases of landscape dynamic (fluvial/alluvial, irregular slope run-off and thermokarst) were presented in a schematic model, and were subsequently correlated with the supraregional environmental history between the Early Weichselian and the Holocene.     

Lead in the North Sea and the north east Atlantic Ocean

Lead has been determined in 105 water samples from the north east Atlantic and from the North Sea. Rigorous precautions were applied to avoid contamination during sampling and analysis.Two different analytical methods were used: ASV and AAS. Determinations with ASV were carried out on board, directly after sampling. After two months storage, acidified samples were analysed by AAS after freon dithiocarbamate extraction and nitric acid back extraction. Particulate lead was determined by AAS after an acid digestion.The profiles of lead concentration versus depth show around 160 pM at the surface and around 20 pM at the bottom, both in the Atlantic and in the Norwegian Sea. The shapes of the profiles are different, however, depending on the hydrography of the area sampled. The profiles from the north east Atlantic coincide with a recently published profile from the north west Atlantic. Moreover, these profiles have lead concentrations about a factor of three higher than those in the Pacific.Considering the high lead input to the North Sea, the lead concentrations found there are remarkably low, probably because of scavenging effects in estuaries leading to a short residence time in the water column. The dominant lead input in offshore regions is from the atmosphere. The highest lead levels are found in the northern North Sea, around 300 pM in surface water.In the Atlantic, particulate lead is a minor part of the total lead whereas in the North Sea the particulate fraction is larger, up to 40%.     

Holocene relative sea-level change, isostatic subsidence and the radial viscosity structure of the mantle of northwest Europe (Belgium, the Netherlands, Germany, southern North Sea)

A comprehensive observational database of Holocene relative sea-level (RSL) index points from northwest Europe (Belgium, the Netherlands, northwest Germany, southern North Sea) has been compiled in order to compare and reassess the data collected from the different countries/regions and by different workers on a common time–depth scale. RSL rise varies in magnitude and form between these regions, revealing a complex pattern of differential crustal movement which cannot be solely attributed to tectonic activity. It clearly contains a non-linear, glacio- and/or hydro-isostatic subsidence component, which is only small on the Belgian coastal plain but increases significantly to a value of ca 7.5 m relative to Belgium since 8 cal. ka BP along the northwest German coast. The subsidence is at least in part related to the Post-Glacial collapse of the so-called peripheral forebulge which developed around the Fennoscandian centre of ice loading during the Last Glacial Maximum. The RSL data have been compared to geodynamic Earth models in order to infer the radial viscosity structure of the Earth's mantle underneath NW Europe (lithosphere thickness, upper- and lower-mantle viscosity), and conversely to predict RSL in regions where we have only few observational data (e.g. in the southern North Sea). A very broad range of Earth parameters fit the Belgian RSL data, suggesting that glacial isostatic adjustment (GIA) only had a minor effect on Belgian crustal dynamics during and after the Last Ice Age. In contrast, a narrow range of Earth parameters define the southern North Sea region, reflecting the greater influence of GIA on these deeper/older samples. Modelled RSL data suggest that the zone of maximum forebulge subsidence runs in a relatively narrow, WNW–ESE trending band connecting the German federal state of Lower Saxony with the Dogger Bank area in the southern North Sea. Identification of the effects of local-scale factors such as past changes in tidal range or tectonic activity on the spatial and temporal variations of sea-level index points based on model-data comparisons is possible but is still complicated by the relatively large range of Earth model parameters fitting each RSL curve, emphasising the need for more high-quality observational data.     

Designing Service Architectures for Distributed Geoprocessing: Challenges and Future Directions

In this paper we study the feasibility of using services offered by a Spatial Data Infrastructure as a basis for distributed service oriented geoprocessing. By developing a prototype we demonstrate that a Spatial Data Infrastructure facilitates rapid development of applications that solve typical problems for an existing risk management application. The prototype provides users with a distributed application that enables the assessment of fire damage areas based on land cover data in a given area. The services involved in the application include: Web Feature Services, Web Map Services, a Gazetteer Service, a Catalogue Service, and Geoprocessing Services. We present the architecture of the application and describe details about implementation‐specific issues. We conclude that current OGC specifications provide a sound basis for developing service oriented architectures for geographic applications; however, in particular for geoprocessing applications, we question the feasibility of the use of Web Feature Services as data sources for larger amounts of data and call for further research in this direction.     

Iron deficiency in pyrrhotite of suevites from the Chesapeake Bay impact crater,USA—A consequence of shock metamorphism?

Abstract– Pyrrhotite from suevite of the 35 Ma Chesapeake Bay impact structure (CBIS) shows a shock metamorphism and we report on several mineralogical and magnetic features. Pyrrhotite shows strong brittle deformation with a high density of stacking faults, twinning parallel to the hexagonal (001) planes and average fault distances in the order of 10 nm. Although the determination of a superstructure was not possible due to the lattice defects, the reflections of the NiAs subcell, which is typical of all pyrrhotite modifications, were clearly detected. This phase is ferrimagnetic with a Curie temperature (T_C) between 350 and 365 °C, and suevite with this phase does not show the 34 K transition. The most peculiar feature is the low metal/sulfur ratio of 0.81, which indicates a distinctly higher vacancy concentration than for 4C pyrrhotite and a composition close to smythite (Fe₉S₁₁). This phase carries a stable natural remanent magnetization and is relatively hard magnetic. Steep inclinations of the natural remanent magnetization vector, however, suggest that this phase has been remagnetized by the drilling process. A possible explanation is the magnetic domain size of faultless areas of about 10 nm in diameter, which is at the lower limit of the single domain size near the threshold, below which superparamagnetic behavior occurs. The low thermal stability of this phase excludes postshock heating above 300 °C for the suevite of the CBIS. Our results imply that the iron‐deficient pyrrhotite is produced by shock metamorphism, although an iron loss due to shock has never been reported before for pyrrhotite.     

Retention of uranium in complexly altered zircon: An example from Bancroft,Ontario

Mesoproterozoic (~ 1050 Ma; Stenian) zircon crystals from the Saranac Prospect, Bancroft, Ontario, contain up to ~ 1 wt.% U and ~ 0.15 wt.% Th and, correspondingly, they are for the most part extensively radiation-damaged (calculated total α-doses 2.3?35.3 × 10¹⁸/g). The crystals show textures of complex, intense chemical alteration that is attributed to multiple, low-T replacement events along fluid-controlled reaction fronts. Centers of crystals appear totally replaced; the primary zoning is virtually erased and the material has high porosity and numerous inclusions. Interior regions surrounding the central reworked areas still exhibit primary igneous-type zoning; in those regions the alteration emanates from fractures and then follows the more radiation-damaged growth zones. Altered areas are typically recognized by their high porosity, low BSE intensity, and deficient analytical totals. Those regions often have lost a significant fraction of their radiogenic Pb. They are in general somewhat depleted in Zr, Si, and U, and are notably enriched in Ca and Fe. Element maps reveal elevated concentrations of Al and Y within filled fractures. Our observations indicate that the fluid-driven ion exchange is mainly controlled by the accessibility of micro-areas with elevated levels of radiation damage to transporting fluids via “fast pathways”. Most importantly, there is apparent Zr?Si?U equilibrium between initially existing and newly formed zircon. The retention of U after the chemical replacement (94 ± 14% relative to the original U content in the respective zones) does not significantly fall below the retention of two major cations Zr (95 ± 4%) and Si (95 ± 2%). In spite of the partially extreme hydrothermal alteration overprinting, the original U zoning in the crystals is well preserved. These observations suggest that preferential chemical leaching of U from zircon is clearly not a general feature of this mineral. This in turn seems to question the general validity of hydrothermal experiments to low-T, fluid-driven alteration of zircon in geological environments. The observed apparent immobility of U may affect the interpretation of U?Pb discordance in zircon, and the performance assessment of this mineral as potential waste form for actinides.     

Sea surface wind stress and drag coefficients: The hexos results

Turbulent fluxes have been measured in the atmospheric surface layer from a boom extending upwind from the Dutch offshore research platform Meetpost Noordwijk (MPN) during HEXMAX (Humidity Exchange over the Sea Main Experiment) in October–November, 1986. We started out to study eddy flux of water vapour, but discrepancies among simultaneous measurements made with three different anemometers led us to develop methods to correct eddy correlation measurements of wind stress for flow distortion by nearby objects. We then found excellent agreement among the corrected wind stress data sets from the three anemometers on the MPN boom and with eddy correlation measurements from a mast on a tripod. Inertial-dissipation techniques gave reliable estimates of wind stress from turbulence spectra, both at MPN and at a nearby ship. The data cover a range of wave ages and the results yield new insights into the variation of sea surface wind stress with sea state; two alternative formulas are given for the nondimensional surface roughness as a function of wave age.     

Air-sea fluxes: 25 years of progress

During the past quarter century the study of air-sea interaction has evolved from a small branch of marine climatology to play a key role in the modelling of the coupled system of ocean and atmosphere. Knowledge of air- sea fluxes has grown, based on Monin-Obukhov similarity theory for surface boundary layers and on direct and indirect techniques of measuring the fluxes. This has been the basis for providing boundary conditions needed to couple atmospheric and oceanic circulation models that are used to forecast weather and climate. An overview of current understanding is followed by a discussion of parameterisation schemes and a chronicle of some of the experimental work that has tested theories and quantified their conclusions.     

Addressing sources of uncertainty in runoff projections for a data scarce catchment in the Ecuadorian Andes

Future climate projections from general circulation models (GCMs) predict an acceleration of the global hydrological cycle throughout the 21st century in response to human-induced rise in temperatures. However, projections of GCMs are too coarse in resolution to be used in local studies of climate change impacts. To cope with this problem, downscaling methods have been developed that transform climate projections into high resolution datasets to drive impact models such as rainfall-runoff models. Generally, the range of changes simulated by different GCMs is considered to be the major source of variability in the results of such studies. However, the cascade of uncertainty in runoff projections is further elongated by differences between impact models, especially where robust calibration is hampered by the scarcity of data. Here, we address the relative importance of these different sources of uncertainty in a poorly monitored headwater catchment of the Ecuadorian Andes. Therefore, we force 7 hydrological models with downscaled outputs of 8 GCMs driven by the A1B and A2 emission scenarios over the 21st century. Results indicate a likely increase in annual runoff by 2100 with a large variability between the different combinations of a climate model with a hydrological model. Differences between GCM projections introduce a gradually increasing relative uncertainty throughout the 21st century. Meanwhile, structural differences between applied hydrological models still contribute to a third of the total uncertainty in late 21st century runoff projections and differences between the two emission scenarios are marginal.