Sampling of Mars analogue materials in a laboratory environment

Acta Geotechnica - Two laboratory test series were performed with the aim of ensuring the proper functionality of the key sampling mechanisms installed aboard the Mars rover ExoMars, currently...     

Periglacial landscape evolution and environmental changes of Arctic lowland areas for the last 60 000 years (western Laptev Sea coast, Cape Mamontov Klyk)

Non-glaciated Arctic lowlands in north-east Siberia were subjected to extensive landscape and environmental changes during the Late Quaternary. Coastal cliffs along the Arctic shelf seas expose terrestrial archives containing numerous palaeoenvironmental indicators (e.g., pollen, plant macro-fossils and mammal fossils) preserved in the permafrost. The presented sedimentological (grain size, magnetic susceptibility and biogeochemical parameters), cryolithological, geochronological (radiocarbon, accelerator mass spectrometry and infrared-stimulated luminescence), heavy mineral and palaeoecological records from Cape Mamontov Klyk record the environmental dynamics of an Arctic shelf lowland east of the Taymyr Peninsula, and thus, near the eastern edge of the Eurasian ice sheet, over the last 60 Ky. This region is also considered to be the westernmost part of Beringia, the non-glaciated landmass that lay between the Eurasian and the Laurentian ice caps during the Late Pleistocene. Several units and subunits of sand deposits, peat–sand alternations, ice-rich palaeocryosol sequences (Ice Complex) and peaty fillings of thermokarst depressions and valleys were presented. The recorded proxy data sets reflect cold stadial climate conditions between 60 and 50 Kya, moderate inderstadial conditions between 50 and 25 Kya and cold stadial conditions from 25 to 15 Kya. The Late Pleistocene to Holocene transition, including the Allerød warm period, the early to middle Holocene thermal optimum and the late Holocene cooling, are also recorded. Three phases of landscape dynamic (fluvial/alluvial, irregular slope run-off and thermokarst) were presented in a schematic model, and were subsequently correlated with the supraregional environmental history between the Early Weichselian and the Holocene.     

Carbonate removal by acidification causes loss of nitrogenous compounds in continental margin sediments

This study reports on measurements of organic carbon (C_org) and total nitrogen (N_tot) in surface sediments originating from 6 transects along the northwest European continental margin. After elimination of carbonates by an acidification technique using sulphurous acid, both elements were analysed in the same sediment sample using an elemental analyser. C_org and N_tot in the sample were comparatively low, ranging between 1 and 10 mg C and 0.2 to 1 mg N g⁻¹ dry sediment. In a second analysis, the samples were analysed without acid addition, resulting in N_tot concentrations of 0–50% higher compared to their acidified counterparts. As a consequence, molar C/N ratios derived from the analysis of C_org and N_tot in the acidified sample ranged between 6 to 11, while the N_tot separate analysis reduced C/N ratios to 6 to 8. It is suggested that the addition of sulphurous acid to eliminate inorganic carbon volatilises nitrogenous organic matter.     

Total body burden and tissue distribution of polyfluorinated compounds in harbor seals (Phoca vitulina) from the German Bight

Total body burden and tissue distribution of polyfluorinated compounds (PFCs) were investigated in harbor seals (Phoca vitulina) from the German Bight in 2007. A total number of 18 individual PFCs from the following groups could be quantified in the different tissues: perfluorinated carboxylic acids (PFCAs) and perfluorinated sulfonates (PFSAs) and their precursors perfluorinated sulfinates (PFSiAs), perfluorinated sulfonamides, and sulfonamido ethanols. Perfluorooctanesulfonate (PFOS) was the predominant compound in all measured seal tissues (up to 1665 ng g⁻¹ wet weight in liver tissue). The dominant PFCAs were perfluorononanoic acid (PFNA) and perfluorodecanoic acid (PFDA), but their concentrations were much lower compared to PFOS. The mean whole body burden in harbor seals of all detected PFCs was estimated to be 2665 ± 1207 μg absolute. The major amount of the total PFCs burden in the bodies was in blood (38%) and liver (36%), followed by muscle (13%), lung (8%), kidney (2%), blubber (2%), heart (1%), brain (1%), thymus (<0.01%) and thyroid (<0.01%). These data suggest large differences in body burden and accumulation pattern of PFCs in marine mammals.     

Sources of polyfluoroalkyl compounds in the North Sea, Baltic Sea and Norwegian Sea: Evidence from their spatial distribution in surface water

The spatial distribution of 15 polyfluoroalkyl compounds (PFCs) in surface water was investigated in the North Sea, Baltic Sea and Norwegian Sea. In addition, an interlaboratory comparison of the sampling techniques and analysis was conducted. Highest concentration in the North Sea was found near the coast, whereas the ∑PFC concentration decreased rapidly from 18.4 to 0.07 ng l⁻¹ towards the open North Sea. The river Elbe could identify as a local input source for PFCs into the North Sea, whereas perfluorobutanoic acid (PFBA) was transported into the sampling area with the easterly current. In contrast to the North Sea, the distribution of PFCs in the Baltic Sea was relatively homogenous, where diffuse sources dominated. In general, the composition profile was influenced from local sources caused by human activities, whereas atmospheric depositions of here analysed PFCs were negligible, but it could have possibly an influence on low contaminated sites like the open North Sea or Norwegian Sea.     

A comparison of peak and plate electrodes in electrical resistivity tomography: application to the chalky groundwater of the Beauvais aquifer (northern part of the Paris basin,France)

Electrical resistivity tomography was used in order to explore an experimental site of the LaSalle Beauvais Polytechnic Institute (France). The test was conducted along a profile line of 315 m length, using 64 electrodes deployed at an inter‐electrode spacing of 5 m, and the data were recorded using gradient, Wenner and pole–dipole arrays. The performance of plate electrodes (non‐conventional flat‐based) is compared with the performance of peak electrodes (conventional spike). The hydrogeophysical investigation of the chalk aquifer system of Beauvais shows that the performance of plate electrodes is satisfactory, leading to inversions of small root‐mean‐square errors. Peak and the plate electrodes were tested before and after injection of a salt tracer in the piezometer of the experimental site. The study demonstrates the usefulness of plate electrodes (efficient, less time consuming) and the possibility of aquifer characterization by a salt tracer. Copyright © 2010 John Wiley & Sons, Ltd.     

Lead in the North Sea and the north east Atlantic Ocean

Lead has been determined in 105 water samples from the north east Atlantic and from the North Sea. Rigorous precautions were applied to avoid contamination during sampling and analysis.Two different analytical methods were used: ASV and AAS. Determinations with ASV were carried out on board, directly after sampling. After two months storage, acidified samples were analysed by AAS after freon dithiocarbamate extraction and nitric acid back extraction. Particulate lead was determined by AAS after an acid digestion.The profiles of lead concentration versus depth show around 160 pM at the surface and around 20 pM at the bottom, both in the Atlantic and in the Norwegian Sea. The shapes of the profiles are different, however, depending on the hydrography of the area sampled. The profiles from the north east Atlantic coincide with a recently published profile from the north west Atlantic. Moreover, these profiles have lead concentrations about a factor of three higher than those in the Pacific.Considering the high lead input to the North Sea, the lead concentrations found there are remarkably low, probably because of scavenging effects in estuaries leading to a short residence time in the water column. The dominant lead input in offshore regions is from the atmosphere. The highest lead levels are found in the northern North Sea, around 300 pM in surface water.In the Atlantic, particulate lead is a minor part of the total lead whereas in the North Sea the particulate fraction is larger, up to 40%.     

Holocene relative sea-level change, isostatic subsidence and the radial viscosity structure of the mantle of northwest Europe (Belgium, the Netherlands, Germany, southern North Sea)

A comprehensive observational database of Holocene relative sea-level (RSL) index points from northwest Europe (Belgium, the Netherlands, northwest Germany, southern North Sea) has been compiled in order to compare and reassess the data collected from the different countries/regions and by different workers on a common time–depth scale. RSL rise varies in magnitude and form between these regions, revealing a complex pattern of differential crustal movement which cannot be solely attributed to tectonic activity. It clearly contains a non-linear, glacio- and/or hydro-isostatic subsidence component, which is only small on the Belgian coastal plain but increases significantly to a value of ca 7.5 m relative to Belgium since 8 cal. ka BP along the northwest German coast. The subsidence is at least in part related to the Post-Glacial collapse of the so-called peripheral forebulge which developed around the Fennoscandian centre of ice loading during the Last Glacial Maximum. The RSL data have been compared to geodynamic Earth models in order to infer the radial viscosity structure of the Earth's mantle underneath NW Europe (lithosphere thickness, upper- and lower-mantle viscosity), and conversely to predict RSL in regions where we have only few observational data (e.g. in the southern North Sea). A very broad range of Earth parameters fit the Belgian RSL data, suggesting that glacial isostatic adjustment (GIA) only had a minor effect on Belgian crustal dynamics during and after the Last Ice Age. In contrast, a narrow range of Earth parameters define the southern North Sea region, reflecting the greater influence of GIA on these deeper/older samples. Modelled RSL data suggest that the zone of maximum forebulge subsidence runs in a relatively narrow, WNW–ESE trending band connecting the German federal state of Lower Saxony with the Dogger Bank area in the southern North Sea. Identification of the effects of local-scale factors such as past changes in tidal range or tectonic activity on the spatial and temporal variations of sea-level index points based on model-data comparisons is possible but is still complicated by the relatively large range of Earth model parameters fitting each RSL curve, emphasising the need for more high-quality observational data.