Dependence of DOLP on Coronal Electron Temperature,Speed, and Structure

We study the predictive capabilities of magnetic-feature properties (MF) generated by the Solar Monitor Active Region Tracker (SMART: Higgins et al. in Adv. Space Res. 47, 2105, 2011) for solar-flare forecasting from two datasets: the full dataset of SMART detections from 1996 to 2010 which has been previously studied by Ahmed et al. (Solar Phys. 283, 157, 2013) and a subset of that dataset that only includes detections that are NOAA active regions (ARs). The main contributions of this work are: we use marginal relevance as a filter feature selection method to identify the most useful SMART MF properties for separating flaring from non-flaring detections and logistic regression to derive classification rules to predict future observations. For comparison, we employ a Random Forest, Support Vector Machine, and a set of Deep Neural Network models, as well as lasso for feature selection. Using the linear model with three features we obtain significantly better results (True Skill Score: TSS = 0.84) than those reported by Ahmed et al. (Solar Phys. 283, 157, 2013) for the full dataset of SMART detections. The same model produced competitive results (TSS = 0.67) for the dataset of SMART detections that are NOAA ARs, which can be compared to a broader section of flare-forecasting literature. We show that more complex models are not required for this data.

     

Petrogenesis of main group pallasite meteorites based on relationships among texture,mineralogy, and geochemistry

Main group pallasite meteorites are samples of a single early magmatic planetesimal, dominated by metal and olivine but containing accessory chromite, sulfide, phosphide, phosphates, and rare phosphoran olivine. They represent mixtures of core and mantle materials, but the environment of formation is poorly understood, with a quiescent core–mantle boundary, violent core–mantle mixture, or surface mixture all recently suggested. Here, we review main group pallasite data sets and petrologic characteristics, and present new observations on the low‐MnO pallasite Brahin that contains abundant fragmental olivine, but also rounded and angular olivine and potential evidence of sulfide–phosphide liquid immiscibility. A reassessment of the literature shows that low‐MnO and high‐FeO subgroups preferentially host rounded olivine and low‐temperature P₂O₅‐rich phases such as the Mg‐phosphate farringtonite and phosphoran olivine. These phases form after metal and silicate reservoirs back‐react during decreasing temperature after initial separation, resulting in oxidation of phosphorus and chromium. Farringtonite and phosphoran olivine have not been found in the common subgroup PMG, which are mechanical mixtures of olivine, chromite with moderate Al₂O₃ contents, primitive solid metal, and evolved liquid metal. Lower concentrations of Mn in olivine of the low‐MnO PMG subgroup, and high concentrations of Mn in low‐Al₂O₃ chromites, trace the development and escape of sulfide‐rich melt in pallasites and the partially chalcophile behavior for Mn in this environment. Pallasites with rounded olivine indicate that the core–mantle boundary of their planetesimal may not be a simple interface but rather a volume in which interactions between metal, silicate, and other components occur.     

Semiempirical band structure calculations on skutterudite-type compounds

Semiempirical band structure calculations were performed on several skutterudite-type compounds by using the extended Hückel method. Starting with the molecular orbital calculations on isolated P₄ and As₄ rings, the reason for the band dispersions of the skutterudites was found to be the interactions between the nonmetal atoms. Both the intermolecular and the intramolecular interactions between the phosphorus atoms are stronger than those between the arsenic atoms. Hence, the dispersion of the bands in CoP₃ is larger than that in CoAs₃. The COOP (crystal orbital overlap population) integrals of the intramolecular P-P bonds reveal the relation between the valence electron count and the observed bond lengths. The P-P bonds in the skutterudite-type compounds like TP₃ (T = Co, Rh, Ir) become stronger by reduction as in NiP₃ and weaker by oxidation as in RT₄X₁₂ (X = P, As, Sb; R = alkaline earth or rare earth metals) because the bands near the Fermi level are bonding. The electronic reason for the geometric distortion of the Ge₂Y₂ (Y = S, Se) units of mixed skutterudites TGe_1.5Y_1.5 is caused by an electron pair gap on germanium, which corresponds to low electron density perpendicular to the ring plane on the germanium atoms. Received: 6 October 1998 / Revised, accepted: 18 June 1999     

The phenomenon of deficient electron microprobe totals in radiation-damaged and altered zircon

The phenomenon of deficient electron microprobe analyses, with sums of analyzed constituents often below 95 wt%, is assigned to the analysis of altered, porous minerals. With the example of three zircon populations we show that low totals are related to textural features (i.e., numerous pores of tens to hundreds of nanometers size) as well as to the chemical composition (i.e., water content well within the wt% range, which may affect partial sample degradation under the electron beam). The formation of the spongy texture is explained by the alteration of a previously radiation-damaged and, thus, volume-expanded material in a fluid-driven replacement reaction. The smaller volume of the reaction product (crystalline, non volume-expanded zircon) accounts for the formation of numerous voids and pores, which are perfect candidates for the incorporation of water. The alteration has also resulted in uptake of non-formula elements such as Al, P, Ca, Fe, Y, and REEs whereas Si and Zr are depleted. In one case, strong uptake of non-radiogenic Pb in altered zircon was observed. Because porous, low-total zircon has formed in secondary alteration process, its occurrence can be considered as an indicator of a secondary alteration history of the host rock. Low-total zircon is easily recognized by very low electron back-scatter intensities, which are closely related to the two main causes of the analytical shortfall (i.e., water content and porosity) and often lowered furthermore by the presence of light non-formula elements (especially P and Fe) up to the wt% range.     

Continental climate in the East Siberian Arctic during the last interglacial: Implications from palaeobotanical records

To evaluate the consequences of possible future climate changes and to identify the main climate drivers in high latitudes, the vegetation and climate in the East Siberian Arctic during the last interglacial are reconstructed and compared with Holocene conditions. Plant macrofossils from permafrost deposits on Bol'shoy Lyakhovsky Island, New Siberian Archipelago, in the Russian Arctic revealed the existence of a shrubland dominated by Duschekia fruticosa, Betula nana and Ledum palustre and interspersed with lakes and grasslands during the last interglacial. The reconstructed vegetation differs fundamentally from the high arctic tundra that exists in this region today, but resembles an open variant of subarctic shrub tundra as occurring near the tree line about 350 km southwest of the study site. Such difference in the plant cover implies that, during the last interglacial, the mean summer temperature was considerably higher, the growing season was longer, and soils outside the range of thermokarst depressions were drier than today. Our pollen-based climatic reconstruction suggests a mean temperature of the warmest month (MTWA) range of 9–14.5 °C during the warmest interval of the last interglacial. The reconstruction from plant macrofossils, representing more local environments, reached MTWA values above 12.5 °C in contrast to today's 2.8 °C. We explain this contrast in summer temperature and soil moisture with a combination of summer insolation higher than present and climatic continentality in arctic Yakutia stronger than present as result of a considerably less inundated Laptev Shelf during the last interglacial.     

In situ micro‐Raman and X‐ray diffraction study of diamonds and petrology of the new ureilite UAE 001 from the United Arab Emirates

Abstract— A new olivine‐pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo_79.8–81.8) and pyroxene (En_73.9–75.2, Fs_15.5–16.9, Wo_8.8–9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo_96.1–96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro‐Raman and in situ synchrotron X‐ray diffraction. The main diamond Raman band (LO = TO mode at ?1332 cm^?1) is broadened when compared to well‐ordered diamond single crystals. Full widths at half maximum (FWHM) values scatter around 7 cm^?1. These values resemble FWHM values obtained from chemical vapor deposition (CVD) diamond. In situ XRD measurements show that diamonds have large grain sizes, up to >5 μm. Some of the graphite measured is compressed graphite. We explore the possibilities of CVD versus impact shock origin of diamonds and conclude that a shock origin is much more plausible. The broadening of the Raman bands might be explained by prolonged shock pressure resulting in a transitional Raman signal between experimentally shock‐produced and natural diamonds.     

Tenoumer impact crater,Mauritania: Impact melt genesis from a lithologically diverse target

Impact melt rocks from the 1.9 km diameter, simple bowl‐shaped Tenoumer impact crater in Mauritania have been analyzed chemically and petrologically. They are heterogeneous and can be subdivided into three types based on melt matrix color, occurrence of lithic clast components, amount of vesiculation (melt degassing), different proportions of carbonate melt mingled into silicate melt, and bulk rock chemical composition. These heterogeneities have two main causes (1) due to the small size of the impact crater, there was probably no coherent melt pool where a homogeneous mixture of melts, derived from different target lithologies, could be created; and (2) melt rock heterogeneity occurring at the thin section scale is due to fast cooling during and after the dynamic ejection and emplacement process. The overall period of crystal growth from these diverse melts was extremely short, which provides a further indication that complete chemical equilibration of the phases could not be achieved in such short time. Melt mixing processes involved in the generation of impact melts are, thus, recorded in nonequilibrium growth features. Variable mixing processes between chemically different melt phases and the formation of hybrid melts can be observed even at millimeter scales. Due to extreme cooling rates, different mixing and mingling stages are preserved in the varied parageneses of matrix minerals and in the mineral chemistry of microlites. ⁴⁰Ar³⁹Ar step‐heating chronology on specimens from three melt rock samples yielded five concordant inverse isochron ages. The inverse isochron plots show that minute amounts of inherited ⁴⁰Ar* are present in the system. We calculated a weighted mean age of 1.57 ± 0.14 Ma for these new results. This preferred age represents a refinement from the previous range of 21 ka to 2.5 Ma ages based on K/Ar and fission track dating.     

Automatic reasoning for geometric constraints in 3D city models with uncertain observations

This paper presents a novel approach to automated geometric reasoning for 3D building models. Geometric constraints like orthogonality or parallelity play a prominent role in man-made objects such as buildings. Thus, constraint based modelling, that specifies buildings by their individual components and the constraints between them, is a common approach in 3D city models. Since prototyped building models allow one to incorporate a priori knowledge they support the 3D reconstruction of buildings from point clouds and allow the construction of virtual cities. However, high level building models have a high degree of complexity and consequently are not easily manageable. Interactive tools are needed which facilitate the development of consistent models that, for instance, do not entail internal logical contradictions. Furthermore, there is often an interest in a compact, redundancy-free representation. We propose an approach that uses algebraic methods to prove that a constraint is deducible from a set of premises. While automated reasoning in 2D models is practical, a substantial increase in complexity can be observed in the transition to the three-dimensional space. Apart from that, algebraic theorem provers are restricted to crisp constraints so far. Thus, they are unable to handle quality issues, which are, however, an important aspect of GIS data and models. In this article we present an approach to automatic 3D reasoning which explicitly addresses uncertainty. Hereby, our aim is to support the interactive modelling of 3D city models and the automatic reconstruction of buildings. Geometric constraints are represented by multivariate polynomials whereas algebraic reasoning is based on Wu’s method of pseudodivision and characteristic sets. The reasoning process is further supported by logical inference rules. In order to cope with uncertainty and to address quality issues the reasoner integrates uncertain projective geometry and statistical hypothesis tests. Consequently, it allows one to derive uncertain conclusions from uncertain premises. The quality of such conclusions is quantified in a way which is sound both from a logical and a statistical perspective.     

Improved antenna phase center models for GLONASS

Thanks to the increasing number of active GLONASS satellites and the increasing number of multi-GNSS tracking stations in the network of the International GNSS Service (IGS), the quality of the GLONASS orbits has become significantly better over the last few years. By the end of 2008, the orbit RMS error had reached a level of 3–4 cm. Nevertheless, the strategy to process GLONASS observations still has deficiencies: one simplification, as applied within the IGS today, is the use of phase center models for receiver antennas for the GLONASS observations, which were derived from GPS measurements only, by ignoring the different frequency range. Geo++ GmbH calibrates GNSS receiver antennas using a robot in the field. This procedure yields now separate corrections for the receiver antenna phase centers for each navigation satellite system, provided its constellation is sufficiently populated. With a limited set of GLONASS calibrations, it is possible to assess the impact of GNSS-specific receiver antenna corrections that are ignored within the IGS so far. The antenna phase center model for the GLONASS satellites was derived in early 2006, when the multi-GNSS tracking network of the IGS was much sparser than it is today. Furthermore, many satellites of the constellation at that time have in the meantime been replaced by the latest generation of GLONASS-M satellites. For that reason, this paper also provides an update and extension of the presently used correction tables for the GLONASS satellite antenna phase centers for the current constellation of GLONASS satellites. The updated GLONASS antenna phase center model helps to improve the orbit quality.     

Platinum group elements in impactites of the ICDP Chicxulub drill core Yaxcopoil‐1: Are there traces of the projectile?

Abstract— This study presents results of platinum group element (PGE) analyses of impactites from the Yaxcopoil‐1 (Yax‐1) and Yucatán 6 drill cores of the 180 km‐diameter Chicxulub crater. These are the main elements used for projectile identification. They were determined by nickel sulfide fire assay combined with inductively coupled plasma mass spectrometry. The concentration of PGE in the samples are low. The concentration patterns of the suevite samples resemble the pattern of the continental crust. We conclude that any meteoritic fraction in these samples is below 0.05%. A syn‐ and post‐impact modification of the PGE pattern from meteoritic toward a continental crust pattern is very unlikely. The globally distributed fallout at the Cretaceous‐Tertiary (K/T) boundary, however, has high PGE concentrations. Therefore, the lack of a significant meteoritic PGE signature in the crater is not an argument for a PGE‐poor impactor. Taking the results of three‐dimensional numerical simulations of the Chicxulub event into account, the following conclusions are drawn: 1) The main fraction of the impactor was ejected into and beyond the stratosphere, distributed globally, and deposited in the K/T boundary clay; and 2) the low amount of projectile contamination in the Yax‐1 lithologies may reflect an oblique impact. However, the role of volatiles in the mixing process between projectile and target is not well‐understood and may also have played a fundamental role.