Lattice vibration spectra. LXVIII. Single-crystal Raman spectra of marcasite-type iron chalcogenides and pnictides,FeX2 (X=S,Se, Te; P,As, Sb)

Single-crystal Raman spectra of marcasite-type FeS₂, FeSe₂, and FeTe₂ and loellingite-type FeP₂, FeAs₂, and FeSb₂ are presented and discussed with reference to the energies of the two X-X stretching modes v _x-x (A _g, B _1g) and the four X₂ librations Rx₂ (A _g, B _1g, B _2g, B _3g). The main results obtained are that (i) the intraionic X-X bonds of FeS₂ marcasite and FeS₂ pyrite are nearly equal in strengths (mean values of the S-S stretching modes 418 and 420 cm^-1, respectively) and (ii) the interactions of the metal ions and the dumbbell-like X₂ units increase on going from the chalcogenides to the respective pnictides and from FeS₂ marcasite to pyrite (as shown from the frequencies of the X₂ librations).     

Selective feeding and grazing rates of oyster (Crassostrea virginica) larvae on natural phytoplankton assemblages

Results of laboratory feeding experiments suggest that oyster (Crassostrea virginica) larvae select small phytoplanktonic organisms (<10 μm) over larger-celled forms from natural estuarine assemblages, but that little selection occurs within the small phytoplankton fraction. Laboratory-reared larvae grazed each of five small-celled phytoplankton groups enumerated (coccoids, centrate diatoms, pennate diatoms, dinoflagellates, and flagellates) at rates proportional to phytoplankton group densities in controls (no larvae added). Larval grazing rates (number of cells removed per larva per hour) were inversely proportional to both larval density and experimental duration.     

Heavy metal inflow into the floodplains at the mouth of the river Weiße Elster (Central Germany)

From 1998 to 2002 investigations were carried out to estimate both the quantity and quality (heavy metal contents) of suspended matter loads discharged into a floodplain area measuring approx. 5 km² of the Central German river Weiße Elster, a tributary of the river Saale in the Elbe river basin. Flood sediments, suspended particulate matter, and floodplain soils were investigated especially for the main pollutants Cd, Zn, Cu, Pb, Cr, and Hg. Supplementary gamma spectroscopy examinations were performed to help to identify the age of deposits in order to estimate sedimentation rates for last decades. The recent flood sediments are contaminated by up to 33 times the geogenic background (Cd). Up to 55% of the total annual SPM load of the river Weiße Elster is relocated into the investigated retention area in the flood‐stricken year 2002. The sedimentation rates for the last 50 years vary between 0.5 mm/a and 1 mm/a in far away and rarely flooded parts and between 1 mm/a and 2 mm/a in the frequently flooded parts of the inflow of the retention area.     

The influence of sea waves on the wind profile

From wind profile and wave measurements performed during the JONSWAP II experiment, relations between the dimensionless profile slope and the significant wave height are derived. It is shown that the wind profile is distorted by the waves especially in the vicinity of the water surface. The wave influence on the profile seems to be restricted to heights below about three wave heights. Above this level, the dimensionless profile slope is an approximately constant value corresponding to a drag coefficient of about 1.15 × 10^–3.     

Convex optimization under inequality constraints in rank-deficient systems

Many geodetic applications require the minimization of a convex objective function subject to some linear equality and/or inequality constraints. If a system is singular (e.g., a geodetic network without a defined datum) this results in a manifold of solutions. Most state-of-the-art algorithms for inequality constrained optimization (e.g., the Active-Set-Method or primal-dual Interior-Point-Methods) are either not able to deal with a rank-deficient objective function or yield only one of an infinite number of particular solutions. In this contribution, we develop a framework for the rigorous computation of a general solution of a rank-deficient problem with inequality constraints. We aim for the computation of a unique particular solution which fulfills predefined optimality criteria as well as for an adequate representation of the homogeneous solution including the constraints. Our theoretical findings are applied in a case study to determine optimal repetition numbers for a geodetic network to demonstrate the potential of the proposed framework.     

Factors affecting the Nd3+ (REE3+) luminescence of minerals

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.     

Polyfluorinated compounds in waste water treatment plant effluents and surface waters along the River Elbe, Germany

Polyfluorinated compounds (PFCs) were investigated in waste water treatment plant (WWTP) effluents and surface waters of the River Elbe from samples collected in 2007. Concentrations of various PFCs, including C₄–C₈ perfluorinated sulfonates (PFSAs), C₆ and C₈ perfluorinated sulfinates, 6:2 fluorotelomer sulfonate, C₅–C₁₃ perfluorinated carboxylic acids (PFCAs), C₄ and C₈ perfluoroalkyl sulfonamides and 6:2, 8:2 and 10:2 unsaturated fluorotelomercarboxylic acids were quantified. ∑PFC concentrations of the river water ranged from 7.6 to 26.4 ng L⁻¹, whereas ∑PFC concentrations of WWTP effluents were approximately 5–10 times higher (30.5–266.3 ng L⁻¹), indicating that WWTPs are potential sources of PFCs in the marine environment. PFC patterns of different WWTP effluents varied depending on the origin of the waste water, whereas the profile of PFC composition in the river water was relatively constant. In both kinds of water samples, perfluorooctanoic acid (PFOA) was the major PFC, whereas perfluorobutane sulfonate (PFBS) was the predominant PFSA.     

A High-Resolution Solar Telescope Using Dark-Lens Diffractive Optics

A telescope based upon dark-lens diffractive optics would be a uniquely new instrument for solar astronomy. The image formation process in such a telescope gives an intrinsically higher resolving power and a greatly reduced image intensity compared to that of refracting or reflecting optical systems of similar lens dimension. This low image intensity would be an advantage for solar observations made using a very large imaging element. After a brief overview of the history of solar instrument development, a quantitative evaluation of the dark-lens diffracting solar telescope concept is presented, showing the potential of this imaging method to meet or even to exceed the most demanding resolution goals currently being considered for future space-borne solar telescopes.