Measuring the sizes of stars

The Chatterton Astronomy Department aims to apply interferometers with very high resolving power to optical astronomy. The programme of the stellar intensity interferometer at Narrabri Observatory was completed in 1972 and since then the work has been directed towards building a more sensitive instrument with higher resolving power. As a first step a much larger intensity interferometer was designed but was not built because it was large, expensive and not as sensitive as desired. Efforts are now being made to design a more sensitive and cheaper instrument. A version of Michelson’s stellar interferometer is being built using modern techniques. It is hoped that it will reach stars of magnitude +8 and will work reliably in the presence of atmospheric scintillation. It is expected to cost considerably less than an intensity interferometer of comparable performance. The pilot model of this new instrument is almost complete and should be ready for test in 1984. Text of an Academy Lecture delivered at the Raman Research Institute, Bangalore on January 27, 1984.     

The ECOMAN project: A novel approach to defining sustainable ecosystem function

The ECOMAN was initiated in 2001 by the University of Plymouth, UK, Plymouth Marine Laboratory and the Department of the Environment, Fisheries and Rural Affairs (DEFRA) to address the need for more pragmatic assessment techniques linking environmental degradation with its causes. The primary aim of the project was to develop an evidence-based approach in which suites of easy-to-use, cost-effective and environmentally valid biological responses (biomarkers) could be used together to assess the health of coastal systems through the general condition of individuals. A range of sub-lethal endpoints, chosen to reflect successive levels of biological organisation (molecular, cellular, physiological), was evaluated in common coastal organisms showing different feeding types (filter feeding, grazing, predation) and habitat requirements (estuary, rocky shore). Initially, the suite of biomarkers was used in laboratory studies to determine the relative sensitivities of key species within different functional groups to common contaminants. These results were then validated in field studies performed in a range of ecosystems exhibiting different degrees/signatures of contamination. Here, an example is provided of a field study in the Humber Estuary, UK, which illustrates how multivariate statistical analysis can be used to identify patterns of response to discriminate between contaminated and clean sites. The use of a holistic, integrated approach of this kind is advocated as a practical means of assessing the impact of chemical contamination on organismal health and of ranking the status of marine ecosystems.     

Geography and global health

In the wake of the report of the World Health Organisation's Commission on the Social Determinants of Health, Closing the gap in a generation (Marmot 2008), this invited commentary considers the scope for geographical research on global health. We reflect on current work and note future possibilities, particularly those that take a critical perspective on the interplay of globalisation, security and health.     

A paleolimnological record of rainfall and drought from East Java, Indonesia during the last 1,400?years

Variations in the location and strength of convection in the Western Pacific Warm Pool (WPWP) have a profound impact on the distribution and amount of global rainfall. Much of the variability in WPWP convection is attributed to variations in the El Ni?o-Southern Oscillation, for which the long-term trends and forcing mechanisms remain poorly understood. Despite the importance of WPWP convection to global climate change, we have very few paleohydrological reconstructions from the region. Here we present a new paleolimnologic and paleohydrologic record spanning the past 1,400 years using a multi-proxy dataset from Lake Logung, located in East Java, Indonesia that provides insights into centennial-scale trends in warm pool hydrology. Organic matter δ¹³C data indicate that East Java became wetter over the last millennium until ca. 1800 Common Era (CE), consistent with evidence for the southward migration of the Intertropical Convergence Zone (ITCZ) during this time. Superimposed on this long-term trend are four decade- to century-scale droughts, inferred from organic matter δ¹³C and calcite abundance data. They are centered at 1030, 1550, 1830, and 1996 CE. The three more recent droughts correlate with hydrologic anomalies documented in other proxy records from the WPWP region on both sides of the equator, and the two most recent droughts correlate in time with historically documented periods of multiple, intense El Ni?o events. Thus, our record provides strong evidence that century-scale hydrologic variability in this region relates to changes in the Walker Circulation. Human activity within the lake catchment is apparent since 1860 CE.     

Reducing greenhouse gas emissions from deforestation and forest degradation in developing countries: revisiting the assumptions

The United Nations Framework on Climate Change (UNFCCC), at its thirteenth meeting in 2005 (COP-11), agreed to start a work program to explore a range of policy approaches and positive incentives for Reducing Emissions from Deforestation and Degradation (REDD). This process was further encouraged in the 2007 COP-13 with the explicit consideration of REDD activities as a means to enhance mitigation action by developing countries in the future. This paper outlines the context of this ongoing political process by reviewing the science indicating that land-use change is a key contributor of greenhouse emissions globally and the assumptions that REDD activities may be competitive—in terms of cost effectiveness—in comparison to other mitigation options. The paper then examines REDD proposals submitted by Parties before COP-13 and identifies key economic, technological, methodological and institutional challenges associated with their implementation. These proposals are discussed in the light of major drivers of deforestation and ongoing efforts to address deforestation. This reveals another set of challenges which, if not taken into account, may undermine REDD effectiveness. The paper aims to aid the policy process and contribute to the best possible design of a REDD framework under the future climate regime.     

A statistical study of gamma-ray burst afterglows measured by the Swift Ultraviolet Optical Telescope

We present the first statistical analysis of 27 Ultraviolet Optical Telescope (UVOT) optical/ultraviolet light curves of gamma-ray burst (GRB) afterglows. We have found, through analysis of the light curves in the observer's frame, that a significant fraction rise in the first 500 s after the GRB trigger, all light curves decay after 500 s, typically as a power law with a relatively narrow distribution of decay indices, and the brightest optical afterglows tend to decay the quickest. We find that the rise could be either produced physically by the start of the forward shock, when the jet begins to plough into the external medium, or geometrically where an off-axis observer sees a rising light curve as an increasing amount of emission enters the observers line of sight, which occurs as the jet slows. We find that at 99.8 per cent confidence, there is a correlation, in the observed frame, between the apparent magnitude of the light curves at 400 s and the rate of decay after 500 s. However, in the rest frame, a Spearman rank test shows only a weak correlation of low statistical significance between luminosity and decay rate. A correlation should be expected if the afterglows were produced by off-axis jets, suggesting that the jet is viewed from within the half-opening angle θ or within a core of a uniform energy density  θ_c  . We also produced logarithmic luminosity distributions for three rest-frame epochs. We find no evidence for bimodality in any of the distributions. Finally, we compare our sample of UVOT light curves with the X-ray Telescope (XRT) light-curve canonical model. The range in decay indices seen in UVOT light curves at any epoch is most similar to the range in decay of the shallow decay segment of the XRT canonical model. However, in the XRT canonical model, there is no indication of the rising behaviour observed in the UVOT light curves.     

A meteorite crater on Earth formed on September 15, 2007: The Carancas hypervelocity impact

Abstract— On September 15, 2007, a bright fireball was observed and a big explosion was heard by many inhabitants near the southern shore of Lake Titicaca. In the community of Carancas (Peru), a 13.5 m crater and several fragments of a stony meteorite were found close to the site of the impact. The Carancas event is the first impact crater whose formation was directly observed by several witnesses as well as the first unambiguous seismic recording of a crater‐forming meteorite impact on Earth. We present several lines of evidence that suggest that the Carancas crater was a hypervelocity impact. An event like this should have not occurred according to the accepted picture of stony meteoroids ablating in the Earth's atmosphere, therefore it challenges our present models of entry dynamics. We discuss alternatives to explain this particular event. This emphasizes the weakness in the pervasive use of “average” parameters (such as tensile strength, fragmentation behavior and ablation behavior) in current modeling efforts. This underscores the need to examine a full range of possible values for these parameters when drawing general conclusions from models about impact processes.     

Arsenite sequestration at the surface of nano-Fe(OH)2, ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens

X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [Fe^II₄Fe^III₂(OH)₁₂CO₃: GR1(CO₃)], which completely converted into ferrous-carbonate hydroxide (Fe^II₂(OH)₂CO₃: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO₃) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO₃) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO₃) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)₂ phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)₂ nanoparticles as oligomers binding to the edges of Fe(OH)₆ octahedra at the edges of the octahedral layers of Fe(OH)₂. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.     

Biogenic nanoparticulate UO2: Synthesis, characterization, and factors affecting surface reactivity

The surface reactivity of biogenic, nanoparticulate UO₂ with respect to sorption of aqueous Zn(II) and particle annealing is different from that of bulk uraninite because of the presence of surface-associated organic matter on the biogenic UO₂. Synthesis of biogenic UO₂ was accomplished by reduction of aqueous uranyl ions, by Shewanella putrefaciens CN32, and the resulting nanoparticles were washed using one of two protocols: (1) to remove surface-associated organic matter and soluble uranyl species (NAUO2), or (2) to remove only soluble uranyl species (BIUO2). A suite of bulk and surface characterization techniques was used to examine bulk and biogenic, nanoparticulate UO₂ as a function of particle size and surface-associated organic matter. The N₂-BET surface areas of the two biogenic UO₂ samples following the washing procedures are 128.63 m² g⁻¹ (NAUO2) and 92.56 m² g⁻¹ (BIUO2), and the average particle sizes range from 5-10 nm based on TEM imaging. Electrophoretic mobility measurements indicate that the surface charge behavior of biogenic, nanoparticulate UO₂ (both NAUO2 and BIUO2) over the pH range 3-9 is the same as that of bulk. The U L_III-edge EXAFS spectra for biogenic UO₂ (both NAUO2 and BIUO2) were best fit with half the number of second-shell uranium neighbors compared to bulk uraninite, and no oxygen neighbors were detected beyond the first shell around U(IV) in the biogenic UO₂. At pH 7, sorption of Zn(II) onto both bulk uraninite and biogenic, nanoparticulate UO₂ is independent of electrolyte concentration, suggesting that Zn(II) sorption complexes are dominantly inner-sphere. The maximum surface area-normalized Zn(II) sorption loadings for the three substrates were 3.00 ± 0.20 μmol m⁻² UO₂ (bulk uraninite), 2.34 ± 0.12 μmol m⁻² UO₂ (NAUO2), and 2.57 ± 0.10 μmol m⁻² UO₂ (BIUO2). Fits of Zn K-edge EXAFS spectra for biogenic, nanoparticulate UO₂ indicate that Zn(II) sorption is dependent on the washing protocol. Zn-U pair correlations were observed at 2.8 ± 0.1 Å for NAUO2 and bulk uraninite; however, they were not observed for sample BIUO2. The derived Zn-U distance, coupled with an average Zn-O distance of 2.09 ± 0.02 Å, indicates that Zn(O,OH)₆ sorbs as bidentate, edge-sharing complexes to UO₈ polyhedra at the surface of NAUO2 nanoparticles and bulk uraninite, which is consistent with a Pauling bond-valence analysis. The absence of Zn-U pair correlations in sample BIUO2 suggests that Zn(II) binds preferentially to the organic matter coating rather than the UO₂ surface. Surface-associated organic matter on the biogenic UO₂ particles also inhibited particle annealing at 90 °C under anaerobic conditions. These results suggest that surface-associated organic matter decreases the reactivity of biogenic, nanoparticulate UO₂ surfaces relative to aqueous Zn(II) and possibly other environmental contaminants.