Stable isotope profiles (Ca,O, C) through modern brachiopod shells of T. septentrionalis and G. vitreus: Implications for calcium isotope paleo-ocean chemistry

Brachiopod shells are widely used as an archive to reconstruct elemental and isotopic composition of seawater. Studies, focused on oxygen and carbon isotopes over the last decades, are increasingly extending to the emerging calcium isotope system. To date, only little attention has been paid to test the reliability of fossil brachiopods on their modern counterparts.In this context, the present study investigates two modern brachiopods, Terebratulina septentrionalis (eastern Canada, 5–30 m depth, 7.1 °C seasonal temperature variation, two-layer shell) and Gryphus vitreus (northern Mediterranean, 200 m depth, constant all-year round temperature, three-layer shell). Both species were sampled along the ontogenetic growth direction and calcium, oxygen, and carbon isotopes as well as elemental concentration were measured. Calcium isotopes were analyzed on TIMS. The elemental composition was analyzed by LA-ICP-MS and ICP-AES.The results indicate an intra-specimen δ^44/40Ca variation ranging from 0.16 to 0.33‰, pointing to a fairly homogenous distribution of calcium isotopes in brachiopod shells. However, in the light of the suggested 0.7‰ increase in calcium isotopes over the Phanerozoic such intra-specimen variations constrain ocean reconstruction. δ^44/40Ca values of T. septentrionalis do not seem to be affected by growth rate. Calcium isotopic values of G. vitreus are heavy in the central part of the shell and trend towards lighter values in peripheral areas approaching the maximum isotopic composition of T. septentrionalis. The maximum inter-species δ^44/40Ca difference of 0.62‰ between T. septentrionalis and G. vitreus indicates that care should be taken when using different taxa, species with different strontium content or brachiopods with specialized shell structure, such as G. vitreus, for ocean water reconstruction in terms of Ca isotopic composition. T. septentrionalis may record Ca isotopic fractionation related to seasonal seawater temperature variations in its shell but this is difficult to resolve at the current analytical precision. Average δ¹⁸O-derived temperatures of the two investigated species are close to on-site measured temperatures.     

Stability of the glacial thermohaline circulation and its dependence on the background hydrological cycle

Different reconstructions of glacial sea-surface temperatures (SST) are used to force a hybrid coupled atmosphere–ocean model. The resulting glacial states differ in global salinity and temperature distributions, and consequently in the strength of the thermohaline circulation. Stability analysis of the Atlantic Ocean circulation, by means of freshwater-flux hysteresis maps, reveals mono-stability for each glacial background state, which appears to be a robust feature of the glacial ocean. We show that this behaviour is directly linked to the hydrological cycle. A monotonic relation between the freshwater input necessary for reaching the off-mode and the hydrological budget in the Atlantic catchment area, accounts for the sensitivity of the oceans circulation. The most sensitive part of the hydrological balance appears to be in the tropical and subtropical regions suggesting that the Achilles heel of the global conveyor belt circulation is not restricted to the northern North Atlantic where convection occurs.     

Die masse von M33

According to the Bottlinger law the mass of M33 is determined with (1.29±0.23)×10¹⁰ M from measurements of the velocities of the neutral hydrogen by Warneret al. (1973).

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Mitteilungen Serie A.     

Der offene Sternhaufen M6 (NGC 6405)

The open star cluster M6 (NGC 6405) is investigated by strip counts on reproductions of the chart of Vleeming (1974). The results are collected in Part 3.

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Mitteilungen Serie A.     

Isotropic and anisotropic correlations in turbulent wind speed data

The correlations in turbulent wind speed data from the open ocean are studied. They are calculated as Fourier transforms of the spectraldensities, which are computed from Fourier transforms of the measured windspeed components. All correlations are found to decay within a few seconds.It is shown that the spectra are most efficiently calculated using data sections whose length does not exceed the observed correlation decay time.Longer runs include more random noise without containing more information.The ratio of the along-wind to transverse spectral levels is investigatedand found to be in excellent agreement with the assumption of isotropy inthe inertial wave number range.     

LakeCC: a tool for efficiently identifying lake basins with application to palaeogeographic reconstructions of North America

Along the margins of continental ice sheets, lakes formed in isostatically depressed basins during glacial retreat. Their shorelines and extent are sensitive to the ice margin and the glacial history of the region. Proglacial lakes, in turn, also impact the glacial isostatic adjustment due to loading, and ice dynamics by posing a marine-like boundary condition at the ice margin. In this study we present a tool that efficiently identifies lake basins and the corresponding maximum water level for a given ice sheet and topography reconstruction. This algorithm, called the LakeCC model, iteratively checks the whole map for a set of increasing water levels and fills isolated basins until they overflow into the ocean. We apply it to the present-day Great Lakes and the results show good agreement (∼1−4%) with measured lake volume and depth. We then apply it to two topography reconstructions of North America between the Last Glacial Maximum and the present. The model successfully reconstructs glacial lakes such as Lake Agassiz, Lake McConnell and the predecessors of the Great Lakes. LakeCC can be used to judge the quality of ice sheet reconstructions. © 2019 The Authors Journal of Quaternary Science Published by John Wiley & Sons Ltd.     

In situ hydrocarbon concentrations from pressurized cores in surface sediments, Northern Gulf of Mexico

Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C₁ through C₅) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg^− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH₄. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH₄ concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.     

The geodynamic and limnological evolution of Balkan Lake Ohrid,possibly the oldest extant lake in Europe

Studies of the upper 447 m of the DEEP site sediment succession from central Lake Ohrid, Balkan Peninsula, North Macedonia and Albania provided important insights into the regional climate history and evolutionary dynamics since permanent lacustrine conditions established at 1.36 million years ago (Ma). This paper focuses on the entire 584-m-long DEEP sediment succession and a comparison to a 197-m-long sediment succession from the Pestani site ~5 km to the east in the lake, where drilling ended close to the bedrock, to unravel the earliest history of Lake Ohrid and its basin development. ²⁶Al/¹⁰Be dating of clasts from the base of the DEEP sediment succession implies that the sedimentation in the modern basin started at c. 2 Ma. Geophysical, sedimentological and micropalaeontological data allow for chronological information to be transposed from the DEEP to the Pestani succession. Fluvial conditions, slack water conditions, peat formation and/or complete desiccation prevailed at the DEEP and Pestani sites until 1.36 and 1.21 Ma, respectively, before a larger lake extended over both sites. Activation of karst aquifers to the east probably by tectonic activity and a potential existence of neighbouring Lake Prespa supported filling of Lake Ohrid. The lake deepened gradually, with a relatively constant vertical displacement rate of ~0.2 mm a⁻¹ between the central and the eastern lateral basin and with greater water depth presumably during interglacial periods. Although the dynamic environment characterized by local processes and the fragmentary chronology of the basal sediment successions from both sites hamper palaeoclimatic significance prior to the existence of a larger lake, the new data provide an unprecedented and detailed picture of the geodynamic evolution of the basin and lake that is Europe’s presumed oldest extant freshwater lake.     

Climate simulation over CORDEX Africa domain using the fifth-generation Canadian Regional Climate Model (CRCM5)

The new fifth-generation Regional Climate Model (CRCM5) was driven by ERA reanalyses for the period 1984–2008 over the African continent following the CORDEX experimental protocol. Overall the model succeeds in reproducing the main features of the geographical distribution and seasonal cycle of temperature and precipitation, the diurnal cycle of precipitation, and the West African Monsoon (WAM). Biases in surface temperature and precipitation are discussed in relation with some circulation defects noted in the simulation. In the African regions near the equator, the model successfully reproduces the double peak of rainfall due to the double passage of the tropical rainbelt, although it better simulates the magnitude and timing of the second peak of precipitation. CRCM5 captures the timing of the monsoon onset for the Sahel region but underestimates the magnitude of precipitation. The simulated diurnal cycle is quite well simulated for all of the regions, but is always somewhat in advance for the timing of rainfall peak. In boreal summer the CRCM5 simulation exhibits a weak cold bias over the Sahara and the maximum temperature is located too far south, resulting in a southward bias in the position of the Saharan Heat Low. The region of maximum ascent in the deep meridional circulation of the Hadley cell is well located in the CRCM5 simulation, but it is somewhat too narrow. The core of the African Easterly Jet is of the right strength and almost at the right height, but it is displayed slightly southward, as a consequence of the southward bias in the position of the Saharan Heat Low and the thermal wind relationship. These biases appear to be germane to the WAM rainfall band being narrower and not moving far enough northward, resulting in a dry bias in the Sahel.