Small volume andesite magmas and melt–mush interactions at Ruapehu, New Zealand: evidence from melt inclusions

Historical eruptions from Mt. Ruapehu (New Zealand) have been small (<0.001 km³ of juvenile magma) and have often occurred without significant warning. Developing better modelling tools requires an improved understanding of the magma storage and transport system beneath the volcano. Towards that end, we have analysed the volatile content and major element chemistry of groundmass glass and phenocryst-hosted melt inclusions in erupted samples from 1945 to 1996. We find that during this time period, magma has been stored at depths of ~2–9 km, consistent with inferences from geophysical data. Our data also show that Ruapehu magmas are relatively H₂O-poor (<2 wt%) and CO₂-rich (≤1,000 ppm) compared to typical arc andesites. Surprisingly, we find that melt inclusions are often more evolved than their transporting melt (as inferred from groundmass glass compositions). Furthermore, even eruptions that are separated by less than 2 years exhibit distinct major element chemistry, which suggests that each eruption involved magma with a unique ascent history. From these data, we infer that individual melt batches rise through, and interact with, crystal mush zones formed by antecedent magmas. From this perspective, we envision the magmatic system at Ruapehu as frequently recharged by small magma inputs that, in turn, cool and crystallise to varying degrees. Melts that are able to erupt through this network of crystal mush entrain (to a greater or lesser extent) exotic crystals. In the extreme case (such as the 1996 eruption), the resulting scoria contain melt inclusion-bearing crystals that are exotic to the transporting magma. Finally, we suggest that complex interactions between recharge and antecedent magmas are probably common, but that the small volumes and short time scales of recharge at Ruapehu provide a unique window into these processes.     

Anthropogenic Nutrient Sources Supplied to a Chesapeake Bay Tributary Support Algal Growth: A Bioassay and High-Resolution Mass Spectrometry Approach

Three anthropogenic sources (urban, soil, and industrial runoff) were characterized for bulk nutrient and dissolved organic matter (DOM) composition using wet chemistry and Fourier transform ion cyclotron resonance mass spectrometry. Each source was unique based on its chemical composition. Dissolved inorganic nitrogen (N) comprised 91, 60, and 20 % of the total N pool in the soil, urban, and industrial sources, respectively. The DOM composition was dominated by terrestrial compounds in the soil, condensed hydrocarbons, lipids and proteins in the urban, and lipid-like compounds in the industrial source. A York River (VA) phytoplankton assemblage, dominated by Cochlodinium polykrikoides, was amended with the sources during a 7-day bioassay. There was a doubling of chlorophyll a and/or cell concentrations within 2 days, in the +Urban and +Soil treatments. The + Industrial treatment supported algal growth, but increases in cell abundances were only statistically significant at the end of the experiment (days 5–7), suggesting that this material was less labile to the original York River community than the other anthropogenic nutrient sources, on the relatively short timescale of the study.     

SEASONAL INORGANIC NITROGEN RELEASE IN ALPINE LAKES ON THE COLORADO WESTERN SLOPE

In the Rocky Mountains, the association of increases in acidic deposition with increased atmospheric loading of sulfate and direct changes in surface water chemistry has been well established. The importance, though, of increased nitrogen (N) deposition in the episodic acidification of alpine lakes and N saturation in alpine ecosystems is only beginning to be documented. In alpine areas of the Colorado Front Range, modest loadings of N in deposition have been associated with leakage of N to surface waters. On the Colorado western slope, however, no leakage of N to surface waters has been reported. A 1995 study that included early season under-ice water samples that were not available in earlier studies showed that there is, in fact, N leakage to surface waters in some western slope basins. Under-ice nitrate (NO^- ₃) concentrations were as high as 10.5 μeq L^-1 and only decreased to detection limits in September. Landscape type appears to be important in leakage of N to surface waters, which is associated with basins having steep slopes, thin soils, and large amounts of exposed bedrock. NO^- ₃ leakage compounds the existing sensitivity to episodic acidification from low acid neutralizing capacity (ANC), which is less than 40 μeq L^-1 in those basins. [Key words: episodic acidification, nitrogen deposition, nitrate, alpine ecosystems, landscape type, Rocky Mountains.]     

High-resolution spectroscopic observations of post-asymptotic giant branch candidates from the Edinburgh–Cape Survey

High spectral resolution  ( R ∼ 40 000)  and signal-to-noise optical spectra, obtained at the Very Large Telescope (VLT), are presented for three post–asymptotic giant branch (AGB) candidates selected from the Edinburgh–Cape (EC) Faint Blue Object Survey. The stellar atmospheric parameters and chemical compositions, derived using sophisticated non-local thermodynamic equilibrium calculations, reveal that EC 14102-1337 and EC 20068-7324 are both in an evolved post–horizontal branch (HB) evolutionary state. However, EC 11507-2253 is most likely a post-AGB star.     

Sources and transport of carbon and nitrogen in the River Sava watershed, a major tributary of the River Danube

Carbon and nitrogen dynamics were examined throughout the River Sava watershed, a major tributary of the River Danube, in 2005 and 2006. The River Sava exported 2.1 × 10¹¹ mol C/yr as dissolved inorganic carbon (DIC), and emitted 2.5 × 10¹⁰ mol C/yr as CO₂ to the atmosphere. Stable carbon isotope ratios indicate that up to 42% of DIC originated from carbonate weathering and 23% from degradation of organic matter. Loads of dissolved and particulate organic carbon increased with discharge and export rates were calculated to be 2.1 × 10¹⁰ mol C/yr and up to 4.1 × 10⁹ mol C/yr, respectively. Isotopic compositions (δ¹³C and δ¹⁵N) and C/N ratios indicated that soil organic matter was the dominant source of particulate organic matter for 59% of the samples. Eighteen percent of the samples were dominated by plankton, 12% by periodic inputs of fresh terrestrial plant detritus with C/N > 15, and about 11% of the samples were dominated by the contribution of aquatic vascular plants. Nitrate inputs were controlled by land use in the River Sava watershed. δ¹⁵N_NO3 values <6‰ were found in predominantly forested watersheds, while values >6‰ typically represented watersheds with a higher percentage of agricultural and/or urban land use. Elevated δ¹⁵N_NO3 values (up to +25.5‰) at some sites were probably due to the combined effects of low-flow and inputs from sewage and/or animal waste.     

Regional stratigraphy and subsidence of Orphan Basin near the time of breakup and implications for rifting processes

The stratigraphic, subsidence and structural history of Orphan Basin, offshore the island of Newfoundland, Canada, is described from well data and tied to a regional seismic grid. This large (400 by 400 km) rifted basin is part of the non‐volcanic rifted margin in the northwest Atlantic Ocean, which had a long and complex rift history spanning Middle Jurassic to Aptian time. The basin is underlain by variably thinned continental crust, locally <10‐km thick. Our work highlights the complex structure, with major upper crustal faults terminating in the mid‐crust, while lower crustal reflectivity suggests ductile flow, perhaps accommodating depth‐dependent extension. We describe three major stratigraphic horizons connected to breakup and the early post‐rift. An Aptian–Albian unconformity appears to mark the end of crustal rifting in the basin, and a second, more subdued Santonian unconformity was also noted atop basement highs and along the proximal margins of the basin. Only minor thermal subsidence occurred between development of these two horizons. The main phase of post‐rift subsidence was delayed until post‐Santonian time, with rapid subsidence culminating in the development of a major flooding surface in base Tertiary time. Conventional models of rifting events predict significant basin thermal subsidence immediately following continental lithospheric breakup. In the Orphan Basin, however, this subsidence was delayed for about 25–30 Myr and requires more thinning of the mantle lithosphere than the crust. Models of the subsidence history suggest that extreme thinning of the lithospheric mantle continued well into the post‐rift period. This is consistent with edge‐driven, small‐scale convective flow in the mantle, which may thin the lithosphere from below. A hot spot may also have been present below the region in Aptian–Albian time.     

Geologically controlled bi-directional exchange of groundwater with a hypersaline lake in the Canadian prairies

Hypersaline lakes occur in hydrologically closed basins due to evaporitic enrichment of dissolved salts transported to the lakes by surface water and groundwater. At the hypersaline Lydden Lake in Saskatchewan, Canada, groundwater/lake-water interaction is strongly influenced by the geological heterogeneity of glacial deposits, whereby a highly permeable glaciofluvial sand/gravel deposit is underlain by glaciolacustrine deposits consisting of dense clay interspersed with silt/sand lenses. Pressure head distribution in a near shore area indicates a bi-directional flow system. It consists of topographically driven flow of fresh groundwater towards the lake in the sand/gravel aquifer and density-driven, landward flow of saline groundwater in the underlying glaciolacustrine deposits. Electrical resistivity tomography, and chemical and isotopic composition of groundwater clearly show the landward intrusion of saline water in the heterogeneous unit. The feasibility of bi-directional flow and transport is supported by numerical simulations of density-coupled groundwater flow and transport. The results suggest that the geologically controlled groundwater exchange processes have substantial influences on both inputs and outputs of dissolved minerals in hypersaline lakes in closed basins.     

Direct impacts of commercial and recreational fishing on spiny lobster,Panulirus interruptus,populations at Santa Catalina Island,California, United States

The California spiny or red rock lobster, Panulirus interruptus, is an ecologically and economically important species that has been exploited since the 1800s. No previous study in California has assessed the impacts of the recreational or commercial lobster harvest. Before the 2003–04 commercial and recreational lobster seasons, we conducted a fishery‐independent trap survey at Santa Catalina Island to document the impact of the lobster fisheries on the size structure, abundance, and sex ratios of mature P. interruptus (>65 mm carapace length (CL)). We concurrently sampled a predominantly commercially fished area, a recreationally fished area, and a 23‐year‐old invertebrate no‐take (INT) reserve. Relative to the INT reserve, legal‐size lobsters in the recreational area were similar in CL, but 31% less abundant. Legal‐size lobsters in the commercial area were 8% smaller and 70% less abundant than those in the INT reserve. The sex ratio of legal‐size lobsters, although near 50:50 in the recreational and INT reserve areas, was male‐dominated (67:33) in the commercial area. Differences in CPUE and mean CL of sub‐legal lobsters in the recreational and commercial areas suggest that factors in addition to harvesting pressure may affect these populations. Total biomass of mature lobsters in the recreational and commercial areas was 92% and 45%, respectively, of biomass in the INT reserve. Fecundity in the recreational and commercial areas was 83% and 42%, respectively, of fecundity in the INT reserve. This study provides preliminary data for future ecological studies and fisheries management evaluations.