Hindcast of the Argo merchant spill using the uri oil spill fates model

A comprehensive oilspill fates model, developed by Cornillon and Spaulding at the University of Rhode Island, has been employed to hindcast the well-studied Argo Merchant spill. Using data collected during the spill to define the environmental conditions and the oil composition, properties and release rates, the oil spill fates model was used to predict the spatial and temporal distribution of spilled oil from December 16 to 31, 1976. Comparison of model predictions to observations for spilled oil mass balance, surface trajectories and oiled surface area was in general quite good. Improved predictions require a better definition of the wind and tidally-forced circulation in the vicinity of the wreck site, a more soundly based theory for oil entrainment or dispersion into the water column and an oil spreading theory which more accurately addresses the complex behaviour of a weathering multicomponent petroleum hydrocarbon.     

Rhizocarpon calibration curve for the Aoraki/Mount Cook area of New Zealand

Development of Rhizocarpon growth curve from the Aoraki/Mount Cook area of New Zealand provides a means to assess Little Ice Age glacier behaviour and suggests approaches that have wider application. Employing a sampling strategy based on large populations affords the opportunity to assess which of various metrics (e.g. single largest, average of five largest, mean of an entire population) best characterise Rhizocarpon growth patterns. The 98% quantile from each population fitted with a quadric curve forms a reliable representation of the growth pattern. Since this metric does not depend on the original sample size, comparisons are valid where sample strategy must be adapted to local situations or where the original sample size differs. For the Aoraki/Mount Cook area a surface 100 years old will have a 98% quantile lichen diameter of 34.3 mm, whereas a 200‐year‐old surface will have a lichen diameter of 73.7 mm. In the Southern Alps, constraints from the age range of calibration points, the flattening of the quadric calibration curve and ecological factors limit the useful age range to approximately 250 years. Copyright © 2005 John Wiley & Sons, Ltd.     

Assessing Collaborative Governance Outcomes and Indicators across Spatial and Temporal Scales: Stewardship Contract Implementation by the United States Forest Service

Abstract

Scholarship on collaboration in natural resource management is restricted by a lack of large-N assessments and mixed methods approach to examine relationships between collaborative structures and processes, and management actions and outcomes. This paper examines the relationship between perceived levels of collaboration, collaborative process indicators, and benefits of USDA Forest Service stewardship contracts at a broad spatial and temporal scale using mixed methodology. This study found higher levels of collaboration were strongly associated with jointly initiated processes that included a breadth of interests and utilized a broad range of outreach mechanisms and opportunities for engagement. Highly collaborative processes were closely linked with attaining project objectives and social and economic benefits. Findings contribute to defining collaboration by uncovering the relationship between perceived levels of collaboration, the role of process characteristics, and perceived benefits of collaborative stewardship contracting processes through a large-N dataset (n?=?1,064) and case study (n?=?61) findings.     

How do Canadian media report climate change impacts on health? A newspaper review

Climatic Change - Research on climate change media coverage is growing. Few studies, however, have investigated how the media portrays climate change impacts on human health. This review,...     

Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.     

Trace element composition of igneous zircon: a thermal and compositional record of the accumulation and evolution of a large silicic batholith, Spirit Mountain, Nevada

Hafnium, U, Th, and REE content of zircons from the Spirit Mountain batholith in southern Nevada correlate with calculated temperatures from the Ti-in-zircon thermometer to support field and petrologic evidence of rejuvenation of crystal mush and melt extraction events during the 2-million year accumulation of the granitoid batholith. Marked variation in zircon composition from sample to sample, from grain to grain within individual samples, and from zone to zone within individual grains documents in detail a history of fluctuating conditions with repeated episodes of replenishment, reheating, crystal mush rejuvenation, fractional crystallization, and melt segregation. The zircons exhibit compositional and thermal variability indicative of variations in host melt composition due to (1) melt rejuvenation, mixing, and fractionation (2) coeval growth of other REE-rich accessory minerals, and possibly (3) fluctuation in fO₂.     

Multiwavelength study of Cygnus A – III. Evidence for relic lobe plasma

We study the particle energy distribution in the cocoon surrounding Cygnus A, using radio images between 151 MHz and 15 GHz and a 200 ks Chandra Advanced CCD Imaging Spectrometer-Imaging (ACIS-I) image. We show that the excess low-frequency emission in the lobe further from the Earth cannot be explained by absorption or excess adiabatic expansion of the lobe or a combination of both. We show that this excess emission is consistent with emission from a relic counterlobe and a relic counterjet that are being re-energized by compression from the current lobe. We detect hints of a relic hotspot at the end of the relic X-ray jet in the more distant lobe. We do not detect relic emission in the lobe nearer to the Earth as expected from light traveltime effects assuming intrinsic symmetry. We determine that the duration of the previous jet activity phase was slightly less than that of the current jet-active phase. Further, we explain some features observed at 5 and 15 GHz as due to the presence of a relic jet.     

An investigation of the presence and nature of phyllosilicates on the surfaces of C asteroids by an analysis of the continuum slopes in their near‐infrared spectra

Abstract– To understand the nature of C asteroid surfaces, which are often related to phyllosilicates and C chondrites, we report near‐infrared spectra for a suite of phyllosilicates, heated to 100–1100 °C in 100 °C intervals, and compare the results for telescope IRTF spectra for 11 C asteroids. As C asteroids have relatively featureless spectra, we focus on “continuum plots” (1.0–1.75 μm slope against 1.8–2.5 μm slope). We compare the continuum plots of the 11 C asteroids and our heated phyllosilicates with literature data for C chondrites. The CI, CR, CK, and CV chondrite meteorites plot in the C asteroid field, whereas CM chondrites plot in a close but discrete field. All are well separated from the large phyllosilicate field. Heating kaolinite and montmorillonite to ≥700 °C moves their continua slopes into the C asteroid field, whereas chlorite and serpentine slopes move into the CM chondrite field. Water losses during heating are generally 10–15 wt% and were associated with a 20–70% albedo drop. Our data are consistent with surfaces of the C asteroids consisting of the dehydration products of montmorillonite whereas the CM chondrites are the dehydration products of serpentine and chlorite. The presence of opaque minerals and evaporites does not provide quantitative explanations for the difference in continua slopes of the phyllosilicates and C asteroids. The CM chondrites can also be linked to the C asteroids by heating. We suggest that the CM chondrites are interior samples, and the presence of a 3 μm feature in C asteroid spectra also indicates the excavation of material.