Gravimetrische Feldmessungen und Modellberechnungen im Gebiet des Krimmler Ache-Tales und Obersulzbachtales (Großvenediger Gebiet / Österreich)

Gravity measurements in the Krimmler Ache Tal and Obersulzbachtal (Oberpinzgau/ Austria) have been carried out. The results of the measurements are presented as follows:

1. Profiles of Bouguer anomalies (BA),
2. Profiles of regional and residual anomalies.

Superficial geological structures are simulated by synthetic models and taken into account for correcting geologically the measured BA's. By the aid of a three-dimensional underground model a first estimation concerning deapth and position of geological structures is possible.     

First health and pollution study on harbor seals (Phoca vitulina) living in the German Elbe estuary

The Elbe is one of the major rivers releasing pollutants into the coastal areas of the German North Sea. Its estuary represents the habitat of a small population of harbor seals (Phoca vitulina). Only little is known about the health status and contamination levels of these seals. Therefore, a first-ever seal catch was organized next to the islands of Neuwerk and Scharhörn in the region of the Hamburg Wadden Sea National Park. The investigations included a broad set of health parameters and the analysis of metals and organic pollutants in blood samples. Compared to animals of other Wadden Sea areas, the seals showed higher γ-globulin levels, suggesting higher concentrations of pathogens in this near-urban area, elevated concentrations for several metals in particular for V, Sn, Pb, and Sr, and comparable ranges for chlorinated organic contaminants, except for elevated levels of hexachlorobenzene, which indicates characteristic inputs from the Elbe.     

Effects of the herbicide diuron on the early life history stages of coral

The effects of the herbicide diuron on the early life history stages of broadcast spawning and brooding corals were examined in laboratory experiments. Fertilisation of Acropora millepora and Montipora aequituberculata oocytes were not inhibited at diuron concentrations of up to 1000 microg l(-1). Metamorphosis of symbiont-free A. millepora larvae was only significantly inhibited at 300 microg l(-1) diuron. Pocillopora damicornis larvae, which contain symbiotic dinoflagellates, were able to undergo metamorphosis after 24 h exposure to diuron at 1000 microg l(-1). Two-week old P. damicornis recruits on the other hand were as susceptible to diuron as adult colonies, with expulsion of symbiotic dinoflagellates (bleaching) evident at 10 microg l(-1) diuron after 96 h exposure. Reversible metamorphosis was observed at high diuron concentrations, with fully bleached polyps escaping from their skeletons. Pulse amplitude modulation (PAM) chlorophyll fluorescence techniques demonstrated a reduction in photosynthetic efficiency (Delta F/F(m)') in illuminated P. damicornis recruits after a 2 h exposure to 1 microg l(-1) diuron. The dark-adapted quantum yields (F(v)/F(m)) also declined, indicating chronic photoinhibition and damage to photosystem II.     

Pyritization processes and greigite formation in the advancing sulfidization front in the upper Pleistocene sediments of the Black Sea

Pyritization in late Pleistocene sediments of the Black Sea is driven by sulfide formed during anaerobic methane oxidation. A sulfidization front is formed by the opposing gradients of sulfide and dissolved iron. The sulfidization processes are controlled by the diffusion flux of sulfide from above and by the solid reactive iron content. Two processes of diffusion-limited pyrite formation were identified. The first process includes pyrite precipitation with the accumulation of iron sulfide precursors with the average chemical composition of FeS_n (n = 1.10-1.29), including greigite. Elemental sulfur and polysulfides, formed from H₂S by a reductive dissolution of Fe(III)-containing minerals, serve as intermediates to convert iron sulfides into pyrite. In the second process, a “direct” pyrite precipitation occurs through prolonged exposure of iron-containing minerals to dissolved sulfide. Methane-driven sulfate reduction at depth causes a progressive formation of pyrite with a δ³⁴S of up to +15.0‰. The S-isotopic composition of FeS₂ evolves due to contributions of different sulfur pools formed at different times. Steady-state model calculations for the advancement of the sulfidization front showed that the process started at the Pleistocene/Holocene transition between 6360 and 11 600 yr BP. Our study highlights the importance of anaerobic methane oxidation in generating and maintaining S-enriched layers in marine sediments and has paleoenvironmental implications.     

River discharge reduces reef coral diversity in Palau

Coral community structure is often governed by a suite of processes that are becoming increasingly influenced by land-use changes and related terrestrial discharges. We studied sites along a watershed gradient to examine both the physical environment and the associated biological communities. Transplanted corals showed no differences in growth rates and mortality along the watershed gradient. However, coral cover, coral richness, and coral colony density increased with increasing distance from the mouth of the bay. There was a negative relationship between coral cover and mean suspended solids concentration. Negative relationships were also found between terrigenous sedimentation rates and the richness of adult and juvenile corals. These results have major implications not only for Pacific islands but for all countries with reef systems downstream of rivers. Land development very often leads to increases in river runoff and suspended solids concentrations that reduce coral cover and coral diversity on adjacent reefs.     

Variable Tl,Pb, and Cd concentrations and isotope compositions of enstatite and ordinary chondrites—Evidence for volatile element mobilization and decay of extinct 205Pb

New Tl, Pb, and Cd concentration and Tl, Pb isotope data are presented for enstatite as well as L- and LL-type ordinary chondrites, with additional Cd stable isotope results for the former. All three chondrite suites have Tl and Cd contents that vary by more than 1–2 orders of magnitude but Pb concentrations are more uniform, as a result of terrestrial Pb contamination. Model calculations based on Pb isotope compositions indicate that for more than half of the samples, more than 50% of the measured Pb contents are due to addition of modern terrestrial Pb. In part, this is responsible for the relatively young and imprecise Pb-Pb ages determined for EH, L, and LL chondrites, which are hence only of limited chronological utility. In contrast, four particularly pristine EL chondrites define a precise Pb-Pb cooling age of 4559 ± 6 Ma. The enstatite chondrites (ECs) have highly variable ε^114/110Cd of between about +3 and +70 due to stable isotope fractionation from thermal and shock metamorphism. Furthermore, nearly all enstatite meteorites display ε²⁰⁵Tl values from −3.3 to +0.8, while a single anomalous sample is highly fractionated in both Tl and Cd isotopes. The majority of the ECs thereby define a correlation of ε²⁰⁵Tl with ε^114/110Cd, which suggests that at least some of the Tl isotope variability reflects stable isotope fractionation rather than radiogenic ingrowth of ²⁰⁵Tl from ²⁰⁵Pb decay. Considering L chondrites, most ε²⁰⁵Tl values range between −4 and +1, while two outliers with ε²⁰⁵Tl ≤ −10 are indicative of stable isotope fractionation. Considering only those L chondrites which are least likely to feature Pb contamination or stable Tl isotope effects, the results are in accord with the former presence of live ²⁰⁵Pb on the parent body, with an initial ²⁰⁵Pb/²⁰⁴Pb = (1.5 ± 1.4) × 10⁻⁴, which suggests late equilibration of the Pb-Tl system 26–113 Ma after carbonaceous chondrites (CCs). The LL chondrites display highly variable ε²⁰⁵Tl values from −12.5 to +14.9, also indicative of stable isotope effects. However, the data for three pristine LL3/LL4 chondrites display an excellent correlation between ε²⁰⁵Tl and ²⁰⁴Pb/²⁰³Tl. This defines an initial ²⁰⁵Pb/²⁰⁴Pb of (1.4 ± 0.3) × 10⁻⁴, equivalent to a ²⁰⁵Pb-²⁰⁵Tl cooling age of 55 + 12/−24 Ma (31–67 Ma) after CCs.     

Validation of official erosion modelling based on high‐resolution radar rain data by aerial photo erosion classification

The universal soil loss equation (USLE) is the most frequently applied erosion prediction model and it is also implemented as an official decision‐making instrument for agricultural regulations. The USLE itself has been already validated using different approaches. Additional errors, however, arise from input data and interpolation procedures that become necessary for field‐specific predictions on a national scale for administrative purposes. In this study, predicted event soil loss using the official prediction system in Bavaria (Germany) was validated by comparison with aerial photo erosion classifications of 8100 fields. Values for the USLE factors were mainly taken from the official Bavarian high‐resolution (5 × 5 m²) erosion cadastre. As series of erosion events were examined, the cover and management factor was replaced by the soil loss ratio. The event erosivity factor was calculated from high‐resolution (1 × 1 km², 5 min), rain gauge‐adjusted radar rain data (RADOLAN). Aerial photo erosion interpretation worked sufficiently well and average erosion predictions and visual classifications correlated closely. This was also true for data broken down to individual factors and different crops. There was no reason to assume a general invalidity of the USLE and the official parametrization procedures. Event predictions mainly suffered from errors in the assumed crop stage period and tillage practices, which do not reflect interannual and farm‐specific variation. In addition, the resolution of radar data (1 km²) did not seem to be sufficient to predict short‐term erosion on individual fields given the strong spatial gradients within individual rains. The quality of the input data clearly determined prediction quality. Differences between USLE predictions and observations are most likely caused by parametrization weaknesses but not by a failure of the model itself. Copyright © 2017 John Wiley & Sons, Ltd.     

A geomorphological seabed classification for the Weddell Sea,Antarctica

Sea floor morphology plays an important role in many scientific disciplines such as ecology, hydrology and sedimentology since geomorphic features can act as physical controls for e.g. species distribution, oceanographically flow-path estimations or sedimentation processes. In this study, we provide a terrain analysis of the Weddell Sea based on the 500 m × 500 m resolution bathymetry data provided by the mapping project IBCSO. Seventeen seabed classes are recognized at the sea floor based on a fine and broad scale Benthic Positioning Index calculation highlighting the diversity of the glacially carved shelf. Beside the morphology, slope, aspect, terrain rugosity and hillshade were calculated and supplied to the data archive PANGAEA. Applying zonal statistics to the geomorphic features identified unambiguously the shelf edge of the Weddell Sea with a width of 45–70 km and a mean depth of about 1200 m ranging from 270 m to 4300 m. A complex morphology of troughs, flat ridges, pinnacles, steep slopes, seamounts, outcrops, and narrow ridges, structures with approx. 5–7 km width, build an approx. 40–70 km long swath along the shelf edge. The study shows where scarps and depressions control the connection between shelf and abyssal and where high and low declination within the scarps e.g. occur. For evaluation purpose, 428 grain size samples were added to the seabed class map. The mean values of mud, sand and gravel of those samples falling into a single seabed class was calculated, respectively, and assigned to a sediment texture class according to a common sediment classification scheme.     

Ant mounds as a source of sediment in a tropical rainforest?

In Lutzito catchment on Barro Colorado Island, Panama, extraordinarily high suspended‐sediment yields of 1–2 Mg ha^?1 year^?1 were generated despite the dense forest cover coinciding with erosion‐resistant soils. We hypothesized that ant mounding activity is an important zoogeomorphological mechanism in this area, providing relevant quantities of easily transportable material at the soil surface. To test this hypothesis, all ant mound material was collected collected for dry mass determination from thirty 4 m² plots installed in the study area every 1–3 days during the 39‐day sampling period. Additionally, three ground‐nesting ant species responsible for mounds in the study area, Ectatomma ruidum, Trachymyrmex cornetzi and Strumigenys marginiventris, were identified. On the basis of the total of 1.38 kg of material collected in the wet season of 2011, the estimate for the whole 8 months wet season amounts to 725 kg ha^?1. As this value is in the same order of magnitude as sediment output, it shows that ants may act as important ecosystem engineers and contribute to sediment production here by providing large quantities of fine‐grained, readily erodible material at the soil surface for subsequent transport to the streambed. Copyright © 2014 John Wiley & Sons, Ltd.