Thermal Equilibrium States of Europa's Ice Shell: Implications for Internal Ocean Thickness and Surface Heat Flow

Ice-shell thickness and ocean depth are calculated for steady state models of tidal dissipation in Europa's ice shell using the present-day values of the orbital elements. The tidal dissipation rate is obtained using a viscoelastic Maxwell rheology for the ice, the viscosity of which has been varied over a wide range, and is found to strongly increase if an (inviscid) internal ocean is present. To determine steady state values, the tidal dissipation rate is equated to the heat-transfer rate through the ice shell calculated from a parameterized model of convective heat transfer or from a thermal conduction model, if the ice layer is found to be stable against convection. Although high dissipation rates and heat fluxes of up to 300 mWm⁻² are, in principle, possible for Europa, these values are unrealistic because the states for which they are obtained are thermodynamically unstable. Equilibrium models have surface heat flows around 20 mWm⁻² and ice-layer thicknesses around 30 km, which is significantly less than the total thickness of the H₂O-layer. These results support models of Europa with ice shells a few tens of kilometers thick and around 100-km-thick subsurface oceans.     

Stabilisation of soil organic matter by interactions with minerals as revealed by mineral dissolution and oxidative degradation

Soil organic matter is known to contain a stable fraction with an old radiocarbon age. Size and stabilisation processes leading to the formation of this old soil carbon pool are still unclear. Our study aims to differentiate old organic matter from young and labile carbon compounds in two acid forest soils (dystric cambisol, haplic podzol). To identify such fractions soil samples were exposed to oxidation with Na₂S₂O₈ and to dissolution by hydrofluoric acid (HF). A negative correlation between ¹⁴C activity and carbon release after dissolution of the mineral matrix by HF indicates a strong association of stabilised carbon compounds with the mineral phase. A negative correlation between the ¹⁴C activity and the relative proportion of carbon resistant to oxidation by Na₂S₂O₈ shows that young carbon is removed preferentially by this treatment. The fraction remaining after oxidation represents a certain stabilised, long residence time carbon pool. This old fraction comprises between 1 and 30% of the total soil organic carbon in the surface horizons, but reaches up to 80% in the sub-surface horizons. Old OC is mainly stabilised by organo-mineral associations with clay minerals and/or iron oxides, whereas intercalation in clay minerals was not found to be important.     

Evidence for a nitrogen flux directly derived from the European subcontinental mantle in the Western Eger Rift, Central Europe

In the Czech-German border region of the Vogtland and NW Bohemia (western Eger rift, Central Europe), chemical and isotopic compositions (C, N, He, Ar) of free gas from a thermal water escape (fluorite mine, Schönbrunn), two mineral springs (“Eisenquelle,” Bad Brambach; “Sprudel III,” Bad Elster) and a mofette (Bublak) located along an ∼40-km long traverse are reported. The gases of Bublak and Bad Brambach are CO₂-rich (>99 vol.%) and have δ¹³C values of −1.95 and −4.29‰, respectively. With distance from the center of CO₂ degassing (Bublak) the δ¹³C values decrease, most likely due to physico-chemical fractionation of CO₂ between gaseous and aqueous phases rather than to admixture of organic/biogenic CO₂. The δ¹⁵N values range between −3.2 and −0.6‰, compared to an upper mantle value of −4.0 ± 1.0‰. The four locations are characterized by ³He/⁴He ratios decreasing from 5.9 R_a in the center (Bublak) to 0.8 R_a in the periphery (Schönbrunn) and give evidence for mixing of He from a deep-seated magmatic source with a crustal source. The location with the highest ³He/⁴He ratio (5.9 R_a) is accompanied by the highest ⁴⁰Ar/³⁶Ar (550). We argue that the nitrogen of the Bublak mofette gas is a mixture of predominantly atmospheric and mantle-derived components, whereas at the other three locations crustal nitrogen may also be present. The Bublak δ¹⁵N value of ≈−4.5 ± 1.0‰ represents the first free gas δ¹⁵N reference from the European subcontinental mantle (ESCM) and indicates that, in contrast to the ³He/⁴He ratios, the δ¹⁵N values are equal for ESCM and MORB, respectively.     

Deformation of oceanic lithosphere near slow-spreading ridge discontinuities

Transform and non-transform discontinuities that offset slow spreading mid-ocean ridges involve complex thermal and mechanical interactions. The truncation of the ridge axis influences the dynamics of spreading and accretion over a certain distance from the segment-end. Likewise, the spreading system is expected to influence the lithospheric plate adjacent to the ridge-end opposite of the discontinuity. Tectonic effects of the truncated ridge are noticeable in for example the contrast between seafloor topography at inside corners and outside corners, along-axis variations in rift valley depth, style of crustal accretion, and ridge segment retreat and lengthening. Along such slow-spreading discontinuities and their fossil traces, oceanic core complexes or mega-mullion structures are rather common extensional tectonic features. In an attempt to understand deformation of oceanic lithosphere near ridge offsets, the evolution of discontinuities, and conditions that may favor oceanic core complex formation, a three-dimensional thermo-mechanical model has been developed. The numerical approach allows for a more complete assessment of lithosphere deformation and associated stress fields in inside corners than was possible in previous 3-D models. The initial suite of results reported here focuses on deformation when axial properties do not vary along-strike or with time, showing the extent to which plate boundary geometry alone can influence deformation. We find that non-transform discontinuities are represented by a wide, oblique deformation zone that tends to change orientation with time to become more parallel to the ridge segments. This contrasts with predicted deformation near transform discontinuities, where initial orientation is maintained in time. The boundary between the plates is found to be vertical in the center of the offset and curved at depth in the inside corners near the ridge–transform intersection. Ridge–normal tensile stresses concentrate in line with the ridge tip, extending onto the older plate across the discontinuity, and high stress amplitudes are absent in the inside corners during the magmatic accretionary phase simulated by our models. With the tested rheology and boundary conditions, inside corner formation of oceanic core complexes is predicted to be unlikely during magmatic spreading phases. Additional modeling studies are needed for a full understanding of extensional stress release in relatively young oceanic lithosphere.     

Palaeoenvironmental Reconstruction from Near-Surface Pan Sediments: An Example from Lebatse Pan, Southeast Kalahari, Botswana

Recent studies of pan sediment stratigraphy in southern Africa have indicated the potential of geophysical and geochemical analyses for elucidating the evolution of pans and the environmental conditions under which formation took place. We have investigated three cores, of 1.8 to 2.6 m in length, from Lebatse Pan in southeast Kalahari, Botswana, and compare the results with the few other similar studies available. Through the sedimentological characteristics of Lebatse we identify cycles of deposition, chemical precipitation and post-depositional alteration under shifting environmental conditions from c . 60,000 years ago to the present. Four periods are separated by depositional hiatuses, marking dry conditions during which deflation of the pan cannot be excluded. During the two oldest periods the sequence of finely laminated, magnesia-rich sediments suggests deposition in a permanent shallow waterbody under evaporative conditions, causing chemical precipitation of dolomite from groundwater. Less evaporative conditions are inferred for the third period of deposition between hiatuses H2 and H1. The youngest period, ¹⁴C-dated to 29,000 years BP, is characterised by water-logged conditions and the development of reed beds. It is believed to have been laid down under fluctuating water levels. The cycles of deposition exhibited in the pan cores appear synchronous with wetter periods in the Southern Kalahari, indicated by the limited evidence currently available.     

Climatic Changes from 12,000 to 4,000 Years Ago in the Austrian Central Alps Tracked by Sedimentological and Biological Proxies of a Lake Sediment Core

Major and trace elements, minerals, and grain-size were analysed from the early to mid-Holocene (12 to 4 ky BP) period of a sediment core from the Alpine lake Oberer Landschitzsee (ObLAN, 2076 m a.s.l.), which is located on predominantly crystalline bedrock on the southern slopes of the Austrian Central Alps. Geochemistry and mineralogy were compared with diatom-inferred (Di-) ‘date of autumn mixing’ (A_mix), DOC, pH, and selected indicator pollen species from the same sediment core. Principal components analysis (PCA) indicated a positive correlation between processes triggered by temperature and precipitation (e.g., lake mixing, DOC). PCA grouped indicators of physical weathering and enhanced catchment run-off (sand, quartz, feldspar), elements of weathering (e.g., Ti, Rb, Mn) under dryer conditions (clay to silt fractions), and elements that probably were related to changes in redox conditions (Cu, Fe, S, Zn). The duration and height of the snow-pack played an important role in this high-alpine environment, affecting weathering, erosion, pH, and lake stratification. Low Alnus viridis pollen abundance, together with markers for increased elements of erosion, indicated extensive snow-pack. Changes in S coupled with As, and elements indicating increased weathering, reflected climate oscillations. LOI was affected by productivity and erosion. High (late) Di–A_mix coupled with increased Di-DOC indicated prolonged summers with increased productivity. Cold and wet (snow-rich) phases and subsequent melting caused low pH and a decoupling of the significant linear correlation between sedimentary Ca and Di-pH. Weathering and leaching during climate deteriorations opposed the long-term trend in a loss of cations and forced in-lake alkalinity generation during the following lake warming. Overall, the multi-proxy study indicated complex climate-driven processes within different time-scales (long-term trends, climate oscillations, seasonality). The climate oscillations within 12–5 ky BP corresponded well with the cool and wet phases known from central Europe suggesting a dominant common Atlantic climate impact. When Mediterranean climate established between 5 and 4 ky BP, its influence on the southern slopes of the Alps increased.     

Diatoms from the genus Achnanthidium in flowing waters of the Appalachian Mountains (North America): Ecology, distribution and taxonomic notes

Diatoms from the genus Achnanthidium are abundant in rivers, streams, and springs of the Appalachian Mountains. They inhabit clean and polluted waters, including those affected by acid mine drainage. The identification of Achnanthidium taxa is difficult due to their small cell size and insufficient information in the diatom floras. We studied the taxonomy and ecology of Achnanthidium in Appalachian rivers by analyzing a data set of benthic diatom samples and corresponding water chemistry data collected during several water-quality surveys from 181 sampling sites. Ten species were identified using scanning electron and light microscopy: A. alpestre (Lowe & Kociolek) Lowe & Kociolek, A. atomus (Hustedt) Monnier, Lange-Bertalot, & Ector, A. deflexum (Reimer) Kingston, A. duthii (Sreenivasa) Edlund, A. eutrophilum (Lange-Bertalot) Lange-Bertalot, A. cf. gracillimum (Meister) Lange-Bertalot, A. cf. latecephalum Kobayasi, A. minutissimum (Kützing) Czarnecki (sensu lato), A. reimeri (Camburn) comb. nov., and A. rivulare Potapova & Ponader. The distribution of common taxa in relation to water chemistry was studied by fitting non-parametric regression models (generalized additive models, GAM, and non-parametric multiplicative regression models, NPMR) to species relative abundances. Studied Achnanthidium species differed considerably in their responses to water chemistry. These results suggest that species-level identifications will lead to more accurate bioassessments.