Resolving archaeological populations with Sr-isotope mixing models

Strontium isotope analysis of tooth enamel is a useful provenancing technique to investigate the childhood origins and residential mobility of ancient people. However, where different geographical target regions have similar biosphere ⁸⁷Sr/⁸⁶Sr it is often difficult to resolve the ⁸⁷Sr/⁸⁶Sr ranges of two different groups of people and establish what constitutes the local range at each site. Here a multi-period study is presented from the Outer Hebrides, Scotland and an investigation of Neolithic and Early Bronze Age populations from the Yorkshire Wolds, NE England. The aim is to demonstrate that, despite complex human dietary strategies, simple mixing systems with only two end-members do occur in archaeological human populations in certain geological provinces and, despite overlapping ⁸⁷Sr/⁸⁶Sr ranges, it is possible to separate two populations based on the structure within the data set.     

Mangrove conversion and aquaculture development in Vietnam: A remote sensing-based approach for evaluating the Ramsar Convention on Wetlands

Remote sensing data have been proposed as a potential tool for monitoring environmental treaties. However, to date, satellite images have been used primarily for visualization, but not for systematic monitoring of treaty compliance. In this paper, we present a methodology to operationalize the use of satellite imagery to assess the impact of the Ramsar Convention on Wetlands. The approach uses time series analysis of landscape pattern metrics to assess land cover conditions before and after designation of Ramsar status to monitor compliance with the Convention. We apply the methodology to two case studies in Vietnam and evaluate the success of Ramsar using four metrics: (1) total mangrove extent; (2) mangrove fragmentation; (3) mangrove density; and (4) aquaculture extent. Results indicate that the Ramsar Convention did not slow the development of aquaculture in the region, but total mangrove extent has remained relatively constant, primarily due to replanting efforts. Yet despite these restoration efforts, the mangroves have become fragmented and survival rates for replanting efforts are low. The methodology is cost effective and especially useful to evaluate Ramsar sites that rely mainly on self-reporting methods and where third parties are not actively involved in the monitoring process. Finally, the case study presented in this paper demonstrates that with the appropriate satellite record, in situ measurements and field observations, remote sensing is a promising technology that can help monitor compliance with international environmental agreements.     

Temporal variations of colloidal carrier phases and associated trace elements in a boreal river

Elemental size distributions, from truly dissolved through colloidal to particulate, have been studied in a subarctic boreal river. The measurements, carried out during 2002, ranged from winter to summer conditions, including an intense spring flood event. Results are reported for a total of 42 elements. Size distributions were characterised using a combination of cross-flow (ultra)filtration (CFF), flow field-flow fractionation (FlFFF), and diffusive gradients in thin-films (DGT). The three techniques showed similar trends, but quantitative comparisons reveal some important differences that warrant further investigation.Previous work has identified two colloidal carrier phases in fresh waters, dominated by iron and carbon, respectively. The majority of the elements studied are associated with one or both of these colloidal carrier phases. The exceptions are the alkali metals and several anions that are only very weakly associated with colloidal material, and which therefore occur mainly as truly dissolved material (<1 kDa in molecular weight). We discuss the likely origin for the two colloidal carrier phases and consider how associated trace elements fit into the geochemical framework. The relative affinities of the elements for iron and carbon colloidal carrier phases are related to their chemistries, and are compared with earlier data from the Delsjö Creek in southern Sweden.Elemental colloidal concentrations show strong seasonal variations related to changes in the colloidal carrier phase(s) with which they associate. In particular, many elements show a strong spring maximum in colloidal concentrations associated with the strong maximum in colloidal carbon concentration during the spring flood.     

Heat as a tracer to estimate dissolved organic carbon flux from a restored wetland

Heat was used as a natural tracer to characterize shallow ground water flow beneath a complex wetland system. Hydrogeologic data were combined with measured vertical temperature profiles to constrain a series of two-dimensional, transient simulations of ground water flow and heat transport using the model code SUTRA (Voss 1990). The measured seasonal temperature signal reached depths of 2.7 m beneath the pond. Hydraulic conductivity was varied in each of the layers in the model in a systematic manual calibration of the two-dimensional model to obtain the best fit to the measured temperature and hydraulic head. Results of a series of representative best-fit simulations represent a range in hydraulic conductivity values that had the best agreement between simulated and observed temperatures and that resulted in simulated pond seepage values within 1 order of magnitude of pond seepage estimated from the water budget. Resulting estimates of ground water discharge to an adjacent agricultural drainage ditch were used to estimate potential dissolved organic carbon (DOC) loads resulting from the restored wetland. Estimated DOC loads ranged from 45 to 1340 g C/(m2 year), which is higher than estimated DOC loads from surface water. In spite of the complexity in characterizing ground water flow in peat soils, using heat as a tracer provided a constrained estimate of subsurface flow from the pond to the agricultural drainage ditch.     

Timescales of melt generation and the thermal evolution of the Himalayan metamorphic core,Everest region,eastern Nepal

In the Everest region of the Nepalese Himalaya, ⁴⁰Ar/³⁹Ar and U-Pb geochronology provide evidence for a complex thermal history marked by multiple episodes of granite intrusion. The oldest mobilized melt formed syn-deformational granitic sills that have U-Pb crystallization ages of 21.33±0.03 and 21.80±0.05 Ma. Preserved in these same granites is a record of earlier magmatic crystallization of xenotime, zircon and monazite between ca. 26 Ma and ca. 23 Ma. This pattern of accessory phase crystallization is interpreted to reflect incremental melting and crystallization in the source region of the sills before ultimate melt migration, and provides the earliest evidence for anatexis in the Everest region. The beginning of crustal melting in the Everest region predates the earliest known movement on both the Main Central Thrust and the South Tibetan fault systems, but is temporally associated with the implied pressure decrease between Eohimalayan and Neohimalayan metamorphism.     

The role of organochlorines in cancer-associated mortality in California sea lions (Zalophus californianus)

Wild California sea lions (Zalophus californianus) have an unusually high prevalence of neoplasms (18% of stranded dead adults) and high levels of contaminants. The contribution of organochlorine (OC) tissue burdens to the probability of sea lions dying from carcinoma was explored using a logistic regression model. Levels of PCBs and DDTs were determined in blubber of sea lions diagnosed with metastatic carcinoma and animals that had died from non-carcinoma-related incidents (e.g., gunshot, domoic acid poisoning). Animals with carcinoma had higher mean concentrations (based on wet weight) of PCBs and DDTs (more than 85% and 30% higher, respectively) in blubber than did sea lions without carcinoma; the highest concentrations of OCs in the sea lions affected with carcinoma were measured in the males. Blubber thickness was significantly different between the two groups of sea lions, but after controlling for this difference, there was still a significant effect of PCBs, but not DDTs, on the probability of sea lions dying with carcinoma. Age, sex, mass and length did not affect the probability of dying from carcinoma.     

Mining,Environmental, Petroleum,and Engineering Industry Applications of Electromagnetic Techniques in Geophysics

Electromagnetic (EM) techniques are extremely important as a direct detection geophysical tool utilized in the base metal industry. They were developed in countries such as Canada, whose thin conductive weathering overburden did not hamper the penetration of EM signals and enabled exploration to depths on the order of 300 m. As a result, EM techniques were used widely in North America and Scandinavia for many years before they became common in countries with a thick conductive overburden, such as Australia. The 1980s and 1990s have seen the use of EM methods move from anomaly finding to mapping, as well as the development of better, faster and more accurate computer modelling algorithms. A review of EM papers, for the years 1998 to 2002, showed that most dealt with EM techniques as mapping tools. Airborne, ground and marine EM techniques are still being developed, as are data processing and interpretation software. The advent of robust 2-D and 3-D computer modelling and inversion algorithms has led to the acceptance of EM methods as a mapping tool for many environmental and petroleum industry applications, a trend which is expected to increase.     

Observed oddities in the lines H,K, b and Hβ

We compare microphotometer intensity traces perpendicular to dispersion in simultaneous spectrograms of good spatial resolution traced at various 's in each of the lines. Cross correlations between the different traces show the following: (a) For each _K there is a corresponding _{b 1}at which the coefficient of correlation, r, is a maximum, usually > 0.8. (b) No such high correlations are found between H and H. (c) Comparison of traces in the continuum and at all observed 's in K, H, b₁, b₂ show a range of 's in each line over which r is very significantly negative, while H shows no such peculiarity.     

AN EVALUATION OF TRANSFER-FUNCTION/NOISE MODELS OF SUSPENDED SEDIMENT CONCENTRATION

Although a variety of regression models of suspended sediment are in wide use, their success is limited. Consistently accurate models have not been forthcoming. Transfer-function/noise models are presented as a better type of stochastic sediment model. These models match hydrological theory more closely, more accurately predict suspended sediment, better satisfy underlying statistical assumptions, and provide more heuristic value regarding current hydrological theory, than past sediment models.