Discrimination between climate and human-induced dryland degradation

In this study we present a technique to discriminate between climate or human-induced dryland degradation, based on evaluations of AVHRR NDVI data and rainfall data. Since dryland areas typically have high inter-annual rainfall variations and rainfall has a dominant role in determining vegetation growth, minor biomass trends imposed by human influences are difficult to verify. By performing many linear regression calculations between different periods of accumulated precipitation and the annual NDVI_max, we identify the rainfall period that is best related to the NDVI_max and by this the proportion of biomass triggered by rainfall. Positive or negative deviations in biomass from this relationship, expressed in the residuals, are interpreted as human-induced. We discuss several approaches that use either a temporally fixed NDVI peaking time or an absolute one, a best mean rainfall period for the entire drylands or the best rainfall period for each individual pixel. Advantages and disadvantages of either approach or one of its combinations for discriminating between climate and human-induced degradation are discussed. Depending on the particular land-use either method has advantages. To locate areas with a high likelihood of human-induced degradation we therefore recommend combining results from each approach.     

On the effect of a low viscosity asthenosphere on the temporal change of the geoid—A challenge for future gravity missions

New satellite technology to measure changes in the Earth’s gravity field gives new possibilities to detect layers of low viscosity inside the Earth. We used density models for the Earth mantle based on slab history as well as on tomography and fitted the viscosity by comparison of predicted gravity to the new CHAMP gravity model. We first confirm that the fit to the observed geoid is insensitive to the presence of a low viscosity anomaly in the upper mantle as long as the layer is thin ( 200 km) and the viscosity reduction is less than two orders of magnitude. Then we investigated the temporal change in geoid by comparing two stages of slablet sinking based on subduction history or by advection of tomography derived densities and compared the spectra of the geoid change for cases with and without a low viscosity layer, but about equal fit to the observed geoid. The presence of a low viscosity layer causes relaxation at smaller wavelength and thus leads to a spectrum with relatively stronger power in higher modes and a peak around degrees 5 and 6. Comparing the spectra to the expected degree resolution for GRACE data for a 5 years mission duration shows a weak possibility to detect changes in the Earth’s gravity field due to large scale mantle circulation, provided that other causes of geoid changes can be taken into account with sufficient accuracy. A discrimination between the two viscosity cases, however, demands a new generation of gravity field observing satellites.     

Geomorphic and sedimentological signature of a two‐phase outburst flood from moraine‐dammed Queen Bess Lake,British Columbia,Canada

On 12 August 1997, the lower part of Diadem Glacier in the southern Coast Mountains of British Columbia fell into Queen Bess Lake and produced a train of large waves. The waves overtopped the broad end moraine at the east end of the lake and ?ooded the valley of the west fork of Nostetuko River. The displacement waves also incised the out?ow channel across the moraine. Stratigraphic and sedimentologic evidence supports the conclusion that the ?ood had two phases, one related to wave overtopping and a second to breach formation. Empirical equations were used to calculate the peak discharge of the ?ood at various points along the west fork of the Nostetuko valley and to describe the attenuation of the ?ood wave. The velocity of the ?ood was also calculated to determine the time it took for the ?ood to reach the main fork of Nostetuko River. The highest peak discharges were achieved in the upper reach of the valley during the displacement phase of the ?ood. Peak discharge declined rapidly just below the moraine dam, with little change thereafter for approximately 7 km. Empirical formulae and boulder measurements indicate a rise in peak discharge in the lower part of the west fork valley. We suggest that ?ow in the upper part of the valley records the passage of two separate ?ood peaks and that the rise in discharge in the lower part of the valley is due to amalgamation of the wave and breach peaks. Hydraulic ponding in con?ned reaches of the valley extended the duration of the ?ood. In addition, erosion of vegetation and sediment in the channel and valley sides may also have exerted an in?uence on the duration and nature of ?ooding. Sediments were deposited both upstream and downstream of channel constrictions and on a large fan extending out into the trunk Nostetuko River valley. This study extends our understanding of the variety and complexity of outburst ?oods from naturally dammed lakes. It also shows that simple empirical and other models for estimating peak discharges of outburst ?oods are likely to yield erroneous results. Copyright © 2005 John Wiley & Sons, Ltd.     

1998 Eruption at Volcán Cerro Azul, Galápagos Islands: I. Syn-Eruptive Petrogenesis

The 1998 eruption of Volcán Cerro Azul in the Galápagos Islands produced two intra-caldera vents and a flank vent that erupted more than 1.0×10⁸ m³ of lava. Lava compositions changed notably during the 5-week eruption, and contemporaneous eruptions in the caldera and on the flank produced different compositions. Lavas erupted from the flank vent range from 6.3 to 14.1% MgO, nearly the entire range of MgO contents previously reported from the volcano. On-site monitoring of eruptive activity is linked with petrogenetic processes such that geochemical variations are evaluated in a temporal context. Lavas from the 1998 eruption record two petrogenetic stages characterized by progressively more mafic lavas as the eruption proceeded. Crystal compositions, whole rock major and trace element compositions, and isotope ratios indicate that early lavas are the product of mixing between 1998 magma and remnant magma of the 1979 eruption. Intra-caldera lavas and later lavas have no 1979 signature, but were produced by the 1998 magma incorporating olivine and clinopyroxene xenocrysts. Thus, early magma petrogenesis is characterized by mixing with the 1979 magma, followed by the magma progressively entraining wehrlite cumulate mush.Editorial Responsibility: M.R. Carroll     

Adsorption of rare earth elements onto Carrizo sand: Experimental investigations and modeling with surface complexation

Rare earth element (REE) adsorption onto sand from a well characterized aquifer, the Carrizo Sand aquifer of Texas, has been investigated in the laboratory using a batch method. The aim was to improve our understanding of REE adsorption behavior across the REE series and to develop a surface complexation model for the REEs, which can be applied to real aquifer-groundwater systems. Our batch experiments show that REE adsorption onto Carrizo sand increases with increasing atomic number across the REE series. For each REE, adsorption increases with increasing pH, such that when pH >6.0, >98% of each REE is adsorbed onto Carrizo sand for all experimental solutions, including when actual groundwaters from the Carrizo Sand aquifer are used in the experiments. Rare earth element adsorption was not sensitive to ionic strength and total initial REE concentrations in our batch experiments. It is possible that the differences in experimental ionic strength conditions (i.e., 0.002-0.01 M NaCl) chosen were insufficient to affect REE adsorption behavior. However, cation competition (e.g., Ca, Mg, and Zn) did affect REE adsorption onto Carrizo sand, especially for light rare earth elements (LREEs) at low pH. Rare earth element adsorption onto Carrizo sand can be successfully modeled using a generalized two-layer surface complexation model. Our model calculations suggest that REE complexation with strong surface sites of Carrizo sand exceeds the stability of the aqueous complexes LnOH²⁺, LnSO₄⁺, and LnCO₃⁺, but not that of Ln(CO₃)₂^- or LnPO₄^o in Carrizo groundwaters. Thus, at low pH (<7.3), where major inorganic ligands did not effectively compete with surface sites for dissolved REEs, free metal ion (Ln³⁺) adsorption was sufficient to describe REE adsorption behavior. However, at higher pH (>7.3) where solution complexation of the dissolved REEs was strong, REEs were adsorbed not only as free metal ion (Ln³⁺) but also as aqueous complexes (e.g., as Ln(CO₃)₂^- in Carrizo groundwaters). Because heavy rare earth elements (HREEs) were preferentially adsorbed onto Carrizo sand compared to LREEs, original HREE-enriched fractionation patterns in Carrizo groundwaters from the recharge area flattened along the groundwater flow path in the Carrizo Sand aquifer due to adsorption of free- and solution-complexed REEs.     

Are peatlands in different states with respect to their thermodynamic behaviour? A simple test of peatland energy and entropy budgets

Whilst all ecosystems must obey the second law of thermodynamics, these physical bounds and controls on ecosystem evolution and development are largely ignored across the ecohydrological literature. To unravel the importance of these underlying restraints on ecosystem form and function, and their power to inform our scientific understanding, we have calculated the entropy budget of a range of peat ecosystems. We hypothesize that less disturbed peatlands are ‘near equilibrium’ with respect to the second law of thermodynamics and thus respond to change by minimizing entropy production. This ‘near equilibrium’ state is best achieved by limiting evaporative losses. Alternatively, peatlands ‘far-from-equilibrium’ respond to a change in energy inputs by maximizing entropy production which is best achieved by increasing evapotranspiration. To test these alternatives this study examined the energy balance time series from seven peatlands across a disturbance gradient. We estimate the entropy budgets for each and determine how a change in net radiation (ΔR_n) was transferred to a change in latent heat flux (ΔλE). The study showed that: (i) The transfer of net radiation to latent heat differed significantly between peatlands. One group transferred up to 64% of the change in net radiation to a change in latent heat flux, while the second transferred as little as 27%. (ii) Sites that transferred the most energy to latent heat flux were those that produced the greatest entropy. The study shows that an ecosystem could be ‘near equilibrium’ rather than ‘far from equilibrium’.