Fluid inclusion evidence for impact‐related hydrothermal fluid and hydrocarbon migration in Creataceous sediments of the ICDP‐Chicxulub drill core Yax‐1

Fluid inclusions studies in quartz and calcite in samples from the ICDP‐Chicxulub drill core Yaxcopoil‐1 (Yax‐1) have revealed compelling evidence for impact‐induced hydrothermal alteration. Fluid circulation through the melt breccia and the underlying sedimentary rocks was not homogeneous in time and space. The formation of euhedral quartz crystals in vugs hosted by Cretaceous limestones is related to the migration of hot (>200 °C), highly saline, metal‐rich, hydrocarbon‐bearing brines. Hydrocarbons present in some inclusions in quartz are assumed to derive from cracking of pre‐impact organic matter. The center of the crater is assumed to be the source of the hot quartz‐forming brines. Fluid inclusions in abundant newly‐formed calcite indicate lower cyrstallization temperatures (75–100 °C). Calcite crystallization is likely related to a later stage of hydrothermal alteration. Calcite precipitated from saline fluids, most probably from formation water. Carbon and oxygen isotope compositions and REE distributions in calcites and carbonate host rocks suggest that the calcite‐forming fluids have achieved close equilibrium conditions with the Cretaceous limestones. The precipitation of calcite may be related to the convection of local pore fluids, possibly triggered by impact‐induced conductive heating of the sediments.     

Designation processes for marine protected areas in the coastal wetlands of South Korea

The history of Korean tidal flat management and the process for designating Coastal Wetland Protected Areas (CWPAs) are described. Korean coastal wetlands have a long history of intensive use through reclamation for agricultural and industrial uses in the 20th century. Recently, the management policy is shifting away from intensive use towards the conservation of wetlands. This shift is caused by increasing public awareness of the value of wetlands and strong institutional support from the government. Since the Wetlands Conservation Act was passed in 1999, a total of twelve CWPAs have been designated through both top-down and bottom-up processes. Three designation paths are classified based on the relevant drivers, namely government-driven designations (seven CWPAs), local community driven designations (three CWPAs), and conflict resolution (trade-offs) driven designation (two CWPAs). The lessons learned from the designation of Korean CWPAs is that diversification of designation process could facilitate voluntary participation of local stakeholders and thereby enhance the chance of successful implementation of wise use strategy of tidal flats.     

Should Women Count? A Context for the Debate*

Much recent feminist geographical scholarship emphasizes the utility of qualitative research methods; yet, a significant proportion of feminist research in geography is quantitative. Geographers' engagement with the ideas of feminist theorists has shed new light on the relationship between epistemology, methodology, and objectivity, which in turn has facilitated a reexamination of feminist uses of quantification. In providing a context for the debate over quantitative and qualitative methods, we argue that each has a place in feminist geographical research.     

A mechanism for preferential H2O leakage from fluid inclusions in quartz,based on TEM observations

Preferential leakage of H₂O from fluid inclusions containing multiple gas components has been suspected in natural metamorphic rocks and has been demonstrated experimentally for synthetic H₂O-CO₂-rich inclusions in natural quartz. Knowledge of the physical and chemical characteristics of the leakage mechanism, which may be very complex, increases the value of natural fluid inclusions to metamorphic geology. It is proposed that crystal defects play a major role in nondecrepitative preferential H₂O leakage through quartz, and remain effective during metamorphism. Inclusions with either an internal overpressure or underpressure produce strain in the adjacent quartz crystal via the nucleation of many dislocations and planar defects (like Dauphiné twin boundaries). These defects allow preferential loss of H₂O from H₂O-CO₂-rich inclusions at supercritical conditions. The transport capacity of this leakage mechanism is enhanced by nucleation of small bubbles on defect structures. The nucleation of these bubbles seems to be a recovery process in strained crystals. Solubility gradients of quartz in water in a crystal with internally underpressurized inclusions may result in optical visible implosion halos in a three dimensional spatial arrangement, caused by the growth of small bubbles at the expense of the larger original fluid inclusion. Natural fluid inclusions from Naxos (Greece) are always associated with numerous interlinked dislocations. These dislocations may have been produced by plastic derormation or by crystal growth related processes (e.g. crack healing). The presence of small bubbles on these dislocations indicates that a similar leakage mechanism for H₂O must have occurred in these rocks.     

Sources, distribution and storage of heavy metals in the Río Pilcomayo, Bolivia

The Río Pilcomayo rises on the Cerro Rico de Potosí precious metal-polymetallic tin deposits of Bolivia, and flows in a southeasterly direction for ca. 600 km to Bolivia's southern border with Argentina. Mining of the Potosí deposits has occurred continuously since 1545, generating large quantities of waste materials in the headwater of the basin. In addition, a tailings dam breach at the Porco mine in 1996 released an estimated 235 000 m³ of tailings and fluid into the upper reaches of the Río Pilaya, the largest tributary to the Pilcomayo.Concentrations of As, Sb, Cd, Cu, Pb, Hg, Ag, Tl and Zn in contemporary channel sediments upstream of the Pilaya confluence are significantly elevated above background values. Elevated levels appear to be associated with pyrite- and other sulphide mineral-bearing tailings materials transported more than 200 km downstream of the Potosí mines. Significant downstream declines in elemental concentrations occur within 15 km, and again between 150 and 200 km, from the mines. The initial decrease in concentrations is due to the rapid dilution of nearly pure tailings effluent released to the river from milling facilities near Potosí. The latter decrease results from a combination of geomorphic processes including the storage of sediment-borne metals within the channel bed and the influx of ‘clean’ sediment from several large tributaries. Downstream of the Pilaya confluence, concentrations of Cu, Pb, Hg and Zn are only slightly elevated above background values, and Ag, Cd, Sb and Tl cannot be distinguished from background levels. These data suggest that while the Porco tailings spill may have had a significant short-term impact on sediment and water quality along the lower reaches of the Río Pilcomayo, its longer-term impacts were limited. Metals stored and eroded from alluvial deposits of historical age in upstream reaches appear to be an important source of metals to the river today. An additional, and perhaps more significant source, is the release of tailings effluent to the river from modern milling operations. The transport of these contaminants downstream of Icla (203 km from Potosí) appears to be restricted by aggradational processes occurring in the vicinity of Puente Sucre. In addition, downstream of the confluence of the Río Pilaya, inputs of large amounts of ‘clean’ sediment have caused dilution of the metal contaminants. Data from other studies where similar geomorphic processes have occurred suggest that the metals in the upper Pilcomayo may eventually be moved downvalley as the aggradational processes are reversed and channel stabilisation occurs. Thus, the most significant impacts of metal contamination may not be realised in downstream areas for decades.     

Teaching GIS in Geography*

Although numerous courses in geographic information systems (GIS) have been introduced into the geography curriculum over the past few years, there has been remarkably little debate over the issues involved. This paper first discusses the arguments for geography as an appropriate disciplinary setting for GIS teaching at the undergraduate level. This is followed by a discussion of the nature of GIS courses and their appropriate place in the undergraduate geography curriculum. The final section of the paper describes the NCGIA Core Curriculum project and examines its significance in this broader context.     

Major and trace elements in igneous rocks from apollo 15

The concentrations of major and trace elements have been determined in igneous rocks from Apollo 15. All materials analyzed have typical depletions of Eu except for minerals separated from sample 15085. Four samples have concentrations of trace elements that are similar to those of KREEP. The samples of mare basalt from Apollo 15 have higher concentrations of FeO, MgO, Mn, and Cr and lower concentrations of CaO, Na₂O, K₂O, and rare-earth elements (REE) as compared to the samples of mare basalt from Apollos 11, 12, and 14. The samples can be divided into two groups on the basis of their normative compositions. One group is quartz normative and has low concentrations of FeO while the other is olivine normative and has high concentrations of FeO. The trace element data indicate that the samples of olivine normative basalt could be from different portions of a single lava flow. At least two and possible three parent magmas can be identified from the samples of the quartz normative group on the basis of their concentration ratios of Sm to Eu. Within each group, the compositions of the samples appear to be related by crystallization of olivine or pyroxene. Significant variations of the ratio of concentration of Sm to Eu cannot be produced without plagioclase-liquid equilibrium. The source material of mare basalt may be depleted in Eu. Alternatively, the magmas may have assimilated a small volume of material similar to KREEP.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

Synthetic Experiments Dealing with Anisotropic Model Building

It has been shown in the past that the interval-NMO velocity and the non-ellipticity parameter largely control the P-wave reflection time moveout of VTI media. To invert for these two parameters, one needs either reasonably large offsets, or some structure in the subsurface in combination with relatively mild lateral velocity variation.This paper deals with a simulation of an inversion approach, building on the assumption that accurately measured V _NMO, as defined by small offset asymptotics for a particular reflector, were available. Instead of such measurements we take synthetically computed data. First, an isotropic model is constructed which explains these V _NMO. Subsequently, residual moveout in common image gathers is modelled by ray tracing (replacing real data), along with its sensitivity for changes in the interval-NMO velocity and the non-ellipticity parameter under the constraint that V _NMO is preserved. This enables iterative updating of the non-ellipticity parameter and the interval-NMO velocity in a layer that can be laterally inhomogeneous.This approach is successfully applied for a mildly dipping reflector at the bottom of a layer with laterally varying medium parameters. With the exact V _NMO assumed to be given, lateral inhomogeneity and anisotropy can be distinguished for such a situation. However, for another example with a homogeneous VTI layer overlying a curved reflector with dip up to 30°, there appears to be an ambiguity which can be understood by theoretical analysis. Consistently with existing theory using the NMO-ellipse, the presented approach is successfully applied to the latter example if V _NMO in the strike direction is combined with residual moveout in dip direction.