Anaerobic precipitation of manganese and co-existing metals in mine impacted water treated with crab shell-associated minerals

The chemical and physical treatment mechanisms by which crab shell removes metals from mine impacted water (MIW) were evaluated under anaerobic and biologically limited conditions in closed systems and kinetic tests. Raw (R-SC20) and deproteinized (DP-SC20) crab shell were tested and compared to limestone to quantify the contribution of chitin-associated minerals and proteins to alkalinity generation and metal precipitation. Single-metal closed systems (initial Mn and Fe = 0.18 mM and Al = 0.34 mM) containing 5 g/L of either R- or DP-SC20, yielded an increase in pH from 3 to 9.2-10.2, generation of 0.83-1.87 mM of alkalinity, and resulted in ?95% removal of metals within 72 h. In contrast, 5-125 g limestone/L only raised the pH to 7.8-8.3, produced lower alkalinity (0.56-0.63 mM), and resulted in less metal removal (?85%). In kinetic tests with 5 g-DP-SC20/L, removal of ?95% of the initial metal load was achieved after 0.5, 6, and 48 h for Al, Fe, and Mn, respectively. Geochemical calculations (PHREEQC) indicate that limestone-treated systems were close to equilibrium with calcite (CaCO₃), whereas octacalcium phosphate (Ca₄H(PO₄)₃) appears to be a controlling phase in systems treated with R- and DP-SC20. The probable mechanisms for Mn removal are the precipitation of rhodochrosite (MnCO₃) and/or sorption. In the case of Al and Fe, geochemical calculations point to the precipitation of hydroxides; however, visual observations in Fe systems suggest the formation of green rust, a precursor of other, more stable phases like goethite or lepidocrocite. Several factors may account for the faster changes observed with R- and DP-SC20 compared to limestone: increased dissolution and degree of supersaturation, the presence of phosphates, the release of organic compounds, and a significantly larger surface area. These results are the first to verify and quantify the capacity of crab shell-associated minerals to treat MIW under biologically limited conditions.     

Control of deep convection by sub-cloud lifting processes: the ALP closure in the LMDZ5B general circulation model

Recently, a new conceptual framework for deep convection scheme triggering and closure has been developed and implemented in the LMDZ5B general circulation model, based on the idea that deep convection is controlled by sub-cloud lifting processes. Such processes include boundary-layer thermals and evaporatively-driven cold pools (wakes), which provide an available lifting energy that is compared to the convective inhibition to trigger deep convection, and an available lifting power (ALP) at cloud base, which is used to compute the convective mass flux assuming the updraft vertical velocity at the level of free convection. While the ALP closure was shown to delay the local hour of maximum precipitation over land in better agreement with observations, it results in an underestimation of the convection intensity over the tropical ocean both in the 1D and 3D configurations of the model. The specification of the updraft vertical velocity at the level of free convection appears to be a key aspect of the closure formulation, as it is weaker over tropical ocean than over land and weaker in moist mid-latitudes than semi-arid regions. We propose a formulation making this velocity increase with the level of free convection, so that the ALP closure is adapted to various environments. Cloud-resolving model simulations of observed oceanic and continental case studies are used to evaluate the representation of lifting processes and test the assumptions at the basis of the ALP closure formulation. Results favor closures based on the lifting power of sub-grid sub-cloud processes rather than those involving quasi-equilibrium with the large-scale environment. The new version of the model including boundary-layer thermals and cold pools coupled together with the deep convection scheme via the ALP closure significantly improves the representation of various observed case studies in 1D mode. It also substantially modifies precipitation patterns in the full 3D version of the model, including seasonal means, diurnal cycle and intraseasonal variability.     

The SORCE Science Data System

The SORCE Science Data System produces total solar irradiance (TSI) and spectral solar irradiance (SSI) data products on a daily basis, which are formulated using measurements from the four primary instruments onboard the SORCE spacecraft. The Science Data System utilizes raw spacecraft and instrument telemetry, calibration data, and other ancillary information to produce and distribute a variety of data products that have been corrected for all known instrumental and operational effects. SORCE benefits from a highly optimized object-oriented data processing system in which all data are stored in a commercial relational database system, and the software itself determines the versions of data products at run-time. This unique capability facilitates optimized data storage and CPU utilization during reprocessing activities by requiring only new data versions to be generated and stored. This paper provides an overview of the SORCE data processing system, details its design, implementation, and operation, and provides details on how to access SORCE science data products.     

Young Populations in the Nuclei of Barred Galaxies

We have conducted UBVRI and H_α CCD photometry of five barred galaxies (NGC 2523, NGC 2950, NGC 3412, NGC 3945 and NGC 5383),along with SPH simulations, in order to understand the origin of young stellar populations in the nuclei of barred galaxies. The H_α emission, which is thought to be emitted by young stellar populations, is either absent or strongly concentrated in the nuclei of early-type galaxies (NGC 2950, NGC 3412 and NGC 3945),while they are observed in the nuclei and circumnuclear regions of intermediate-type galaxies with strong bars (NGC 2523 and NGC 5383).SPH simulations of realistic mass models for these galaxies show that some disc material can be driven into the nuclear region by a strong bar potential. This implies that the young stellar populations in the circumnuclear regions of barred galaxies can be formed out of such gas. The existence of nuclear dust lanes is an indication of an ongoing gas inflow and extremely young stellar populations in these galaxies, because nuclear dust lanes such as those in NGC 5383 are not long-lasting features according to our simulations. This revised version was published online in July 2006 with corrections to the Cover Date.     

Observations at terrestrial impact structures: Their utility in constraining crater formation

Abstract— Hypervelocity impact involves the near instantaneous transfer of considerable energy from the impactor to a spatially limited near‐surface volume of the target body. Local geology of the target area tends to be of secondary importance, and the net result is that impacts of similar size on a given planetary body produce similar results. This is the essence of the utility of observations at impact craters, particularly terrestrial craters, in constraining impact processes. Unfortunately, there are few well‐documented results from systematic contemporaneous campaigns to characterize specific terrestrial impact structures with the full spectrum of geoscientific tools available at the time. Nevertheless, observations of the terrestrial impact record have contributed substantially to fundamental properties of impact. There is a beginning of convergence and mutual testing of observations at terrestrial impact structures and the results of modeling, in particular from recent hydrocode models. The terrestrial impact record provides few constraints on models of ejecta processes beyond a confirmation of the involvement of the local substrate in ejecta lithologies and shows that Z‐models are, at best, first order approximations. Observational evidence to date suggests that the formation of interior rings is an extension of the structural uplift process that occurs at smaller complex impact structures. There are, however, major observational gaps and cases, e.g., Vredefort, where current observations and hydrocode models are apparently inconsistent. It is, perhaps, time that the impact community as a whole considers documenting the existing observational and modeling knowledge gaps that are required to be filled to make the intellectual breakthroughs equivalent to those of the 1970s and 1980s, which were fueled by observations at terrestrial impact structures. Filling these knowledge gaps would likely be centered on the later stages of formation of complex and ring structures and on ejecta.     

Morphology and evolution of supraglacial hummocks on debris-covered Himalayan glaciers

Thick supraglacial debris layers often have an undulating, hummocky topography that influences the lateral transport of debris and meltwater and provides basins for supraglacial ponds. The role of ablation and other processes associated with supraglacial debris in giving rise to this hummocky topography is poorly understood. Characterizing hummocky topography is a first step towards understanding the feedbacks driving the evolution of debris-covered glacier surfaces and their potential impacts on mass balance, hydrology and glacier dynamics. Here we undertake a geomorphological assessment of the hummocky topography on five debris-covered glaciers in the Everest region of the central Himalaya. We characterize supraglacial hummocks through statistical analyses of their vertical relief and horizontal geometry. Our results establish supraglacial hummocks as a distinct landform. We find that a typical hummock has an elongation ratio of 1.1:1 in the direction of ice flow, length of 214 ± 109 m and width of 192 ± 88 m. Hummocky topography has a greater amplitude across-glacier (15.4 ± 10.9 m) compared to along the glacier flow line (12.6 ± 8.3 m). Consequently, hummock slopes are steeper in the across-glacier direction (8.7 ± 4.3°) than in the direction of ice flow (5.6 ± 4.0°). Longer, wider and higher-amplitude hummocks are found on larger glaciers. We postulate that directional anisotropy in the hummock topography arises because, while the pattern of differential ablation driving topography evolution is moderated by processes including the gravitational redistribution of debris across the glacier surface, it also inherits an orientation preference from the distribution of englacial debris in the underlying ice. Our morphometric data inform future efforts to model these interactions, which should account for additional factors such as the genesis of supraglacial ponds and ice cliffs and their impact on differential ablation.     

Fingerprinting hydrological and biogeochemical drivers of freshwater quality

Understanding the interplay between hydrological flushing and biogeochemical cycling in streams is now possible owing to advances in high-frequency water quality measurements with in situ sensors. It is often assumed that storm events are periods when biogeochemical processes become suppressed and longitudinal transport of solutes and particulates dominates. However, high-frequency data show that diel cycles are a common feature of water quality time series and can be preserved during storm events, especially those of low-magnitude. In this study, we mine a high-frequency dataset and use two key hydrochemical indices, hysteresis and flushing index to evaluate the diversity of concentration-discharge relationships in third order agricultural stream. We show that mobilization patterns, inferred from the hysteresis index, change on a seasonal basis, with a predominance of rapid mobilization from surface and near stream sources during winter high-magnitude storm events and of delayed mobilization from subsurface sources during summer low-magnitude storm events. Using dynamic harmonic regression, we were able to separate concentration signals during storm events into hydrological flushing (using trend as a proxy) and biogeochemical cycling (using amplitude of a diel cycle as a proxy). We identified three groups of water quality parameters depending on their typical c-q response: flushing dominated parameters (phosphorus and sediments), mixed flushing and cycling parameters (nitrate nitrogen, specific conductivity and pH) and cycling dominated parameters (dissolved oxygen, redox potential and water temperature). Our results show that despite large storm to storm diversity in hydrochemical responses, storm event magnitude and timing have a critical role in controlling the type of mobilization, flushing and cycling behaviour of each water quality constituent. Hydrochemical indices can be used to fingerprint the effect of hydrological disturbance on freshwater quality and can be useful in determining the impacts of global change on stream ecology.     

Exploring aberrant bivalve shell ultrastructure and geochemistry as proxies for past sea water acidification

Throughout much of Earth's history, marine carbonates have represented one of the most important geological archives of environmental change. Several pivotal events during the Phanerozoic, such as mass extinctions or hyperthermal events have recently been associated with ocean acidification. Nevertheless, well‐defined geological proxies for past ocean acidification events are, at best, scarce. Here, experimental work explores the response of bivalve shell ultrastructure and isotope geochemistry (δ¹³C, δ¹⁸O and δ²⁶Mg) to stressful environments, in particular to sea water acidification. In this study, the common blue mussel, Mytilus edulis, was cultured (from early juvenile stages to one year of age) at four pH regimes (pH_NBS 7·2 to pH 8·0). Shell growth rate and ultrastructure of mainly the calcitic portion of the shells were compared between experimental treatments. Specimens exposed to low‐pH environments show patches of disordered calcitic fibre orientation in otherwise well‐structured shells. Furthermore, the electron backscattered diffraction analyses reveal that, under acidified conditions, the c‐axis of the calcite prisms exhibits a bimodal or multi‐modal distribution pattern. Similar shell disorder patterns have been reported from mytilids kept under naturally acidified sea water conditions. In contrast, this study found no evidence that different pH regimes affect shell carbon, oxygen or magnesium isotope ratios. Based on these observations, it is proposed that: (i) stressful environments, in this case low sea water pH, predictably affect bivalve biomineralization patterns; and (ii) these findings bear potential as a novel (petrographic) proxy for ancient sea water acidification. An assessment of the applicability of these data to well‐preserved fossil shell material from selected time intervals requires additional work.     

Incremental CH4 and N2O mitigation benefits consistent with the US Government's SC-CO2 estimates

Benefit–cost analysis can serve as an informative input into the policy-making process, but only to the degree it characterizes the major impacts of the regulation under consideration. Recently, the US, amongst other nations, has begun to use estimates of the social cost of CO₂ (SC-CO₂) to develop analyses that more fully capture the climate change impacts of GHG abatement. The SC-CO₂ represents the aggregate willingness to pay to avoid the damages associated with an additional tonne of CO₂ emissions. In comparison, the social costs of non-CO₂ GHGs have received little attention from researchers and policy analysts, despite their non-negligible climate impact. This article addresses this issue by developing a set of social cost estimates for two highly prevalent non-CO₂ GHGs, methane and nitrous oxide. By extending existing integrated assessment models, it is possible to develop a set of social cost estimates for these gases that are consistent with the SC-CO₂ estimates currently in use by the US federal government.Policy relevanceWithin the benefit–cost analyses that inform the design of major regulations, all Federal agencies within the US Government (USG) use a set of agreed upon SC-CO₂ estimates to value the impact of CO₂ emissions changes. However, the value of changes in non-CO₂ GHG emissions has not been included in USG policy analysis to date. This article addresses that omission by developing a set of social cost estimates for two highly prevalent non-CO₂ GHGs, methane and nitrous oxide. These new estimates are designed to be compatible with the USG SC-CO₂ estimates currently in use and may therefore be directly applied to value emissions changes for these non-CO₂ gases within the benefit–cost analyses used to evaluate future policies.     

Recent advances in modeling stellar interiors

Advances in stellar interior modeling are being driven by new data from large-scale surveys and high-precision photometric and spectroscopic observations. Here we focus on single stars in normal evolutionary phases; we will not discuss the many advances in modeling star formation, interacting binaries, supernovae, or neutron stars. We review briefly: (1) updates to input physics of stellar models; (2) progress in two and three-dimensional evolution and hydrodynamic models; (3) insights from oscillation data used to infer stellar interior structure and validate model predictions (asteroseismology). We close by highlighting a few outstanding problems, e.g., the driving mechanisms for hybrid γ Dor/δ Sct star pulsations, the cause of giant eruptions seen in luminous blue variables such as η Car and P Cyg, and the solar abundance problem.