Atmospheric Effects of the Emerging Mainland Chinese Transportation System at and Beyond the Regional Scale

Local surface travel needs in the Peoples Republic of China (mainlandChina) have traditionally been met largely by nonpolluting bicycles. A majorautomobile manufacturing/importing effort has begun in the country over thelast decade, and planning documents indicate that the Chinese may strive toacquire more than 100 million vehicles early in the next century. By analogywith large automotive fleets already existing in the western world, bothregional and global scale pollution effects are to be expected from theincrease. The present work adopts the latest projections of Chinese automobilemanufacture and performs some quantitative assessments of the extent ofpollution generation.Focus for the investigation is placed upon the oxidant ozone. Emissions of theprecursor species nitrogen oxides and volatile organics are constructed basedon data for the current automotive sector in the eastern portion of the UnitedStates. Ozone production is first estimated from measured values forcontinental/oceanic scale yields relative to precursor oxidation. Theestimates are then corroborated through idealized two dimensional modeling ofthe photochemistry taking place in springtime air flow off the Asian land massand toward the Pacific Ocean. The projected fleet sizes could increase coastaland remote oceanic ozone concentrations by tens of parts per billion (ppb)in the lower troposphere. Influences on the tropospheric aerosol system andon the major greenhouse gas carbon dioxide are treated peripherally. Nitrogenoxides created during the vehicular internal combustion process willcontribute to nitrate pollution levels measured in the open Pacific. Thepotential for soot and fugitive dust increases should be considered as theautomotive infrastructure develops. Since the emerging Chinese automotivetransportation system will represent a substantial addition to the globalfleet and all the carbon in gasoline is eventually oxidized completely, asignificant rise in global carbon dioxide inputs will ensue as well.Some policy issues are treated preliminary. The assumption is made thatalterations to regional oxidant/aerosol systems and to terrestrial climate areconceivable. The likelihood that the Chinese can achieve the latest vehiclefleet goals is discussed, from the points of view of new production, positivepollution feedbacks from a growing automobile industry, and known petroleumreserves. Vehicular fuel and maintenance options lying before the Chinese areoutlines and compared. To provide some perspective on the magnitude of theenvironmental changes associated with an Asian automotive buildup, recentestimates of the effects of future air traffic over the Pacific Rim aredescribed.     

Exposure history of the Peekskill (H6) meteorite

Abstract— The Peekskill H6 meteorite fell on 1992 October 9. We report extensive measurements of cosmic-ray produced stable nuclides of He, Ne, and Ar, of the radionuclides ²²Na, ⁶⁰Co, ¹⁴C, ³⁶Cl, ²⁶Al, and ¹⁰Be, and of cosmic-ray track densities. After correction for shielding via the ²²Ne/²¹Ne ratio, the concentrations of cosmic-ray produced ³He, ²¹Ne and ³⁸Ar give an average exposure age of 25 Ma, which is considered to be a lower limit on the true value. The ¹⁰Be/²¹Ne age is 32 Ma and falls onto a peak in the H-chondrite exposure age distribution. The activities of ²⁶Al, ¹⁴C, ³⁶Cl, and ¹⁰Be are all close to the maximum values expected for H-chondrites. Together with cosmic-ray track densities and the ²²Ne/²¹Ne ratio, these radionuclide data place the samples at a depth >20 cm in a meteoroid with a radius >40 cm. In contrast, the ⁶⁰Co activity requires a near-surface location and/or a much smaller body. Calculations show that a flattened geometry for the Peekskill meteoroid does not explain the observations in the context of a one-stage irradiation. A two-stage model can account for the data. We estimate an upper bound of 70 cm on the radius of the earlier stage of irradiation and conclude that Peekskill's radius was <70 cm when it entered the Earth's atmosphere. This size limit is somewhat smaller than the dynamic determinations (Brown et al., 1994).     

The Institutional Architecture of Extractive Reserves in Rondônia, Brazil

This paper examines the evolution and development of institutions involved in the establishment of extractive reserves. It focuses on the different actors, organizations and projects concerned with extractive reserves in Rondônia in western Amazonia, Brazil. Extractive reserves are widely seen as a means of integrating forest conservation and local socio-economic development. As such, they have gained the support of the international environmental movement, multilateral and state development organizations, and grassroots community and producer organizations. These institutions represent a vast array of diverse interests which range from conservation of biodiversity, economic and social cohesion, and regional and national development. Whilst the various actors and institutions claim mutual and complementary interests, they form shifting alliances and coalitions in order to further their interests. This paper maps these institutions and interests and describes how alliances have been formed and broken, and how this has contributed to the currently observed implementation of extractive reserves. The paper argues that extractive reserves are constrained by the dissonance or misfit in discourses and underlying worldviews, reflected by the aims and objectives, of the institutions which promote, oppose and lose and benefit from their implementation. This misfit is overcome, in part, by alliances formed between the different institutions, and in part by the creation of new institutions and projects.     

WAVELENGTH SELECTION IN MULTICOMPONENT NEAR-INFRARED CALIBRATION

Modern scanning(near-)infrared reflectance/absorption(NIR)spectroscopes measure the absorptions orreflectances at a sequence of around 1000 wavelengths.Training data may consist of 10-100 carefullydesigned sample mixtures for which the true composition of the mixture is either known by formulationor accurately determined by wet chemistry.In future one wishes to predict the true composition fromthe spectrum.In this paper we compare a simple wavelength selection approach with methods whichretain all the wavelengths.It offers a powerful yet simple technique for choosing those wavelengths thatare specific to each pure component as against the other components(including the medium)for thevarying compositions.In the presence of a defined range of ingredients it thus chooses wavelengths whichare highly selective for each particular component.It has the added advantage of selecting wavelengthswhich are little effected by interaction effects and consequent non-linearities.The calibration data used consist of 125 observations of three sugars,each varying at five levels in afull 5~3 design.The validation set consists of 21 further samples specially selected to have compositionsoutside the range of the training sample.The selection methods perform much better on this predictionset than methods which retain all the wavelengths,700 in this case.The leave-one-out cross-validationinternal to the calibration data would point to the opposite finding and suggests that such cross-validations may be overly flattering to techniques such as partial least squares and may encourageoverfitting.After selection,simple straightforward least squares methods may be used,eschewing theneed for‘shrinkage’methods such as partial least squares or ridge regression.     

雅鲁藏布江缝合带的双陆内俯冲构造与部分熔融层特征──INDEPTH项目结果的初步综合

根据中、美两国合作开展的西藏深反射地震结果,提出雅鲁藏布江缝合带（YZS）的"双陆内俯冲"构造模式和缝合带南、北分别存在着不同特征的、规模不一的部分熔融层；提出YZS处断裂向深部延深有限,认为YZS处地壳增厚有4种机制：①地壳规模的大的俯冲增厚；②上部地壳内的俯冲和背冲增厚；③下地壳内的底部垫托增厚和挤压增厚；④深部熔融体的向上挤入而引起的地壳增厚.提出可能存在两条大的伸展性断裂,造成江孜南、北地块间出现了大升降.     

深反射地震揭示喜马拉雅地区地壳上地幔的复杂结构

报告了中、美两国在喜马拉雅山区进行的第一次深反射地震试验的结果．试验剖面南起喜马拉雅山山脊南亚东县的帕里镇，向北穿过喜马拉雅山脊的荡拉，到达康马南的萨马达．剖面长约１００ｋｍ．共中心点（ＣＭＰ）叠加剖面上显示出：１．在地壳中部有一强反射带，向北缓倾斜下去，延长达１００ｋｍ以上．它可能代表了一个活动的逆冲断裂或是一条巨大的拆离带，印度地壳整体或下地壳沿此拆离层俯冲到藏南之下．２．上部地壳的反射很丰富，显示了上地壳存在着大规模的叠瓦状结构．３．下地壳的反射同相轴呈现短而有规律的分布，显示了塑性流变特征．４．在测线南部莫霍反射明显，深度达７２－７５ｋｍ．发现南部有双莫霍层的存在．５．试验中还取得莫霍层下面３２，３８，４８ｓ等双程走时的多条反射，向北倾斜，反射同相轴延续较长，信息丰富，反映了上地幔的成层结构和变形特征．这些结果对印度大陆地壳整体或其下地壳俯冲到藏南特提斯喜马拉雅地壳之下，并导致西藏南端地壳增厚的观点，给予了实质性的支持．     

Modelling of mineral equilibria in ultrahigh-temperature metamorphic rocks from the Anápolis–Itauçu Complex, central Brazil

A new quantitative approach to constraining mineral equilibria in sapphirine‐bearing ultrahigh‐temperature (UHT) granulites through the use of pseudosections and compatibility diagrams is presented, using a recently published thermodynamic model for sapphirine. The approach is illustrated with an example from an UHT locality in the Anápolis–Itauçu Complex, central Brazil, where modelling of mineral equilibria indicates peak metamorphic conditions of about 9 kbar and 1000 °C. The early formed, coarse‐grained assemblage is garnet–orthopyroxene–sillimanite–quartz, which was subsequently modified following peak conditions. The retrograde pressure–temperature (P–T) path of this locality involves decompression across the FeO–MgO–Al₂O₃–SiO₂ (FMAS) univariant reaction orthopyroxene + sillimanite = garnet + sapphirine + quartz, resulting in the growth of sapphirine–quartz, followed by cooling and recrossing of this reaction. The resulting microstructures are modelled using compatibility diagrams, and pseudosections calculated for specific grain boundaries considered as chemical domains. The sequence of microstructures preserved in the rocks constrains a two‐stage isothermal decompression–isobaric cooling path. The stability of cordierite along the retrograde path is examined using a domainal approach and pseudosections for orthopyroxene–quartz and garnet–quartz grain boundaries. This analysis indicates that the presence or absence of cordierite may be explained by local variation in a_H2O. This study has important implications for thermobarometric studies of UHT granulites, mainly through showing that traditional FMAS petrogenetic grids based on experiments alone may overestimate P–T conditions. Such grids are effectively constant a_H2O sections in FMAS‐H₂O (FMASH), for which the corresponding a_H2O is commonly higher than that experienced by UHT granulites. A corollary of this dependence of mineral equilibria on a_H2O is that local variations in a_H2O may explain the formation of cordierite without significant changes in P–T conditions, particularly without marked decompression.     

TUNING EFFECTS,LITHOLOGICAL EFFECTS AND DEPOSITIONAL EFFECTS IN THE SEISMIC RESPONSE OF GAS RESERVOIRS*

Synergism of 3-D seismic data, wavelet processing, colour display and interactive interpretation has been exploited in the study of a Gulf of Mexico gas reservoir. Seismic amplitude has been used as a measure of the proportion of a sand/shale reservoir capable of producing gas. This has led to the mapping of net producible thickness of gas sand. The tuning phenomena resulting from geometric effects alone were studied in detail, and tuning curves of various levels of sophistication were used as the basis for amplitude editing. Statistical tuning curves were derived by interactive cross-plotting and deterministic curves by wavelet extraction. Multiple wavelet side lobes cause multiple maxima in the tuning curve. Depositional effects and intrareservoir communication have also been studied by interactive cross-plotting.     

Pyroxenes from the Late Stages of Fractionation of the Skaergaard Intrusion, East Greenland

The pyroxenes of the upper zone of the Skaergaard layered seriesconsist of an iron-rich series of brown and green clinopyroxenes.Five new analyses are presented, together with a revised trendline which includes the full range of clinopyroxenes believedrepresentative of the Skaergaard fractionation sequence. Therange for the augite-ferroaugite-ferrohedenbergite series isfrom Ca_42?4 Mg_47?9 Fe_9?7 to Ca_42?5 Mg_0?4 Fe_57?1, the most ferriferousvariety coexisting with a pure fayalite. A re-study of the compositionsand textures of certain green ferrohedenbergites supports thebelief that they are the product of sub-solidus inversion offerriferous ß-wollaston?tes, which crystallized asa temporary phase between the periods when brown ferrohedenbergitescrystallized directly from the magma. A consideration of thecompositional and textural relationships between green and brownpyroxenes, and the significance of the mosaic inversion texture,have led to an interpretation of the crystallization and inversionsequence for these minerals. Four new analyses of ferrohedenbergitesfrom the downward-crystallized upper border group rocks provideevidence for a trend which differs slightly from that for thelayered series ferrohedenbergites.