Evaluating the influence of mixture composition on the kinetics of salt damage in wall paintings using time lapse video imaging with direct data annotation

This paper presents an examination of the timescale of phase transition behaviour of a series of salts known to cause damage to wall paintings and other cultural property. The rate of deliquescence and crystallisation of single salts (nitromagnesite and halite) under different RH regimes, and the extent to which this was affected when mixed with other salts (niter, nitratite and gypsum), was investigated. The study was conducted using simple conventional techniques (mass measurements over time) and also using an innovative new method: timelapse video imaging with online data annotation. The results demonstrate the synergy gained from combining video imaging with environmental data in reference to time in the study of salt phase changes: where it revealed new information concerning the kinetics of deliquescence and crystallisation. The implications of these results for the implementation of environmental control measures within historic buildings are discussed.

Age of Detrital Zircons from Sandstones of the Mesozoic Flysch Formation in the South Anyui Suture Zone (Western Chukotka)

The South Anyui fold zone (western Chukotka) is considered a suture zone related to closure of the South Anyui oceanic basin and collision of Eurasia with the Chukotka–Arctic Alaska microcontinent in the Early Cretaceous. The existence of a compensatory sedimentation basin (foredeep) during folding in the terminal Jurassic–initial Cretaceous remains debatable. This work presents first data on age estimates of detrital zircons from Upper Mesozoic terrigenous sequences of the South Anyui suture zone obtained by the fission-track method. The distal flysch of presumably Late Jurassic age and the proximal flysch of probably Late Triassic age were sampled in the Uyamkanda River basin. The fission-track dating showed that sandstones from the flysch sections contain detrital zircons of two different-age populations. Young zircon populations from sandstones of distal turbidites in the upper course of the Uyamkanda River (two samples) are 149 ± 10.2 and 155.4 ± 9.0 Ma old (Late Jurassic), whereas those from coarse-grained proximal turbidites sampled in the lower course of the Uyamkanda River (one sample) is 131.1 ± 7.5 Ma old (Early Cretaceous). The data obtained indicate that the Late Mesozoic folding in the South Anyui suture zone was accompanied by the formation of a marginal sedimentary basin. Sediments accumulated in this basin compose tectonic nappes that constitute a fold–thrust structure with the northern vergence.     

Geothermal potential evaluation and development prioritization based on geochemistry of geothermal waters from Kangding area,western Sichuan,China

Kangding geothermal area is located in the western Sichuan, belonging to southeastern margin of Tibetan Plateau. Similar to world-renowned south Tibetan and western Yunnan geothermal belt, western Sichuan has intensive surface thermal manifestations including boiling and hot springs. The emerging temperature of thermal waters ranges from 47 to 79 °C with total dissolved solids lying between 899 and 2550 mg/L. δ²H–δ¹⁸O isotopes indicate a meteoric source for the thermal waters and a significant positive oxygen-18 shift in the southern region. It is suggested that southern thermal waters experienced stronger water–rock interaction and are closer to thermodynamic equilibrium, which is also proved by the water type classification. The reservoir temperature calculated by empirical and theoretical chemical thermometry is 180–225 °C for the north and 225–310 °C for the south. Evidences of hydrogeochemistry, stable isotopes, geothermometry and radiocarbon dating indicate that southern region of Kangding area shows greater geothermal potential than the northern region. In addition, based on the hydrogeochemical modeling of mineral saturation, underlying problem of scaling is likely to occur in the study area. According to the results of reservoir temperature, south Kangding sub-district has greater potential in geothermal power generation and development than northern Kangding. Therefore, further exploration and drilling work should give priority to the south Kangding area.     

Primitive island arc and oceanic lavas from the hunter ridge-hunter fracture zone. Evidence from glass,olivine and spinel compositions

Summary At its southernmost end, the main spreading centre of the North Fiji Basin is propagating into arc crust of the poorly-known Hunter Ridge. We define nine magmatic groups from major element glass chemistry and olivine and spinel compositions in samples dredged from twenty six sites in this area by the R/V Academician A. Nesmeyanov in 1990. These include groups of boninites, island arc tholeiites (IAT), mid-ocean ridge basalts (MORB), enriched mid-ocean ridge basalts (E-MORB), olivine porphyritic andesites and basaltic andesite and Na-rhyolites. Primitive lavas containing highly forsteritic olivine phenocrysts are common in all the groups, except for the rhyolites.We report over 100 glass analyses for dredged rocks from this region, and about 300 olivine-spinel pairs for representatives of all the magmatic groups identified, except the Na-rhyolites.The MORB in this region are probably produced at the propagating spreading centre in the southern part of the North Fiji Basin. Juxtaposition of shallow, hot MORB-source diapirs supplying the MORB in this area, and the sub-arc damp, refractory upper mantle beneath the Hunter Ridge, provides suitable petrogenetic conditions to produce a range of magma types, from island arc tholeiites through to high-Ca boninites. The latter were recovered in eleven dredges.The E-MORB lavas recovered from the extreme southern margin of the North Fiji Basin are shown to be essentially identical to those dredged from adjacent older South Fiji Basin crust. It is hypothesized that the former were either scraped off the South Fiji Basin crust during an episode of oblique subduction that may have generated the Hunter Ridge during the last 5 Myr, or alternatively, that slices of the South Fiji Basin crust were trapped and incorporated into the North Fiji Basin as the subduction zones fronting the Vanuatu arc stepped or propagated southward.

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Primitive Inselbogen- und ozeanische Laven von Hunter Rücken und der Hunter BruchZone: die Bedeutung der Zusammensetzung von Glas, Olivin und Spinell

Zusammenfassung Das spreading centre des Nord-Fidschi-Beckens setzt sich an seinem südlichsten Ende in die Inselbogen-Kruste des noch wenig bekannten Hunter-Rückens fort.Wir definieren 9 magmatische Gruppen auf der Basis der Hauptelement-Zusammensetzung von Gläsern und der Zusammensetzung von Olivin und Spinell in Proben die das Forschungsschiff R/V Akademiker A. Nesmeyanov von 26 Stellen im Jahr 1990 aufgesammelt hat. Zu diesen gehören Gruppen von Boniniten, Inselbogentholeiiten (IAT), Basalten zentralozeanischer Rücken (MORB), angereicherte zentralozeanische Rücken (E-MORB), Olivin-porphyritische Andesite und basaltische Andesite, sowie Na-Rhyolite. Primitive Laven mit Olivinkristallen, die reich an Forsterit-Komponenten sind, kommen in allen diesen Gruppen, mit Ausnahme der Rhyolite, vor.Wir legen über 100 Glas-Analysen von Gesteinen aus diesem Gebiet vor und über 300 Olivin-Spinell-Paare für Vertreter aller der hier identifizierten magmatischen Gruppen, mit Ausnahme der Natriumrhyolite.Die MORB in diesem Gebiet sind wahrscheinlich an dem aktiven Spreading Center im Südteil des Nord-Fidschi-Beckens entstanden. Das nebeneinander Vorkommen von seichten heißen MORB-Quellen Diapiren, die MORB in diesem Gebiet erzeugen, und der Sub-Inselbogen, wasserhaltige, refraktäre obere Mantel unter dem Hunter Rücken führen zu geeigneten petrogenetischen Bedingungen für die Entstehung einer Vielfalt von Magmatypen, von Inselbogentholeiiten bis zu sehr Kalziumreichen Boniniten. Die letzteren wurden in 11 Dredge-Proben gefunden.Die E-MORS Laven, die aus dem extremen Südteil des Nord-Fidschi-Beckens entnommen wurden, sind im wesentlichen mit jenen identisch, die aus der benachbarten älteren Kruste des Süd-Fidschi-Beckens stammen. Es wird vermutet, daß die letzteren entweder aus dem Süd-Fidschi-Becken während einer Episode obliger Subduktion, die in den letzten 5 Millionen Jahren zur Entstehung des Hunter Ridge geführt hat, abgeschert wurden, oder auch daß Teile der Kruste des Süd-Fidschi-Beckens in das Nord-Fidschi-Becken inkorporiert wurden als Subduktionszonen gegenüber dem Vanuato-Bogen sich nach Süden fortbewegten.

     

Air-sea interaction over the tropical Indian Ocean during several contrasting monsoon seasons

Monthly mean anomaly fields of various parameters like sea surface temperature, air temperature, wind stress, effective radiation at the surface, heat gain over the ocean and the total heat loss between a good and bad monsoon composite and the evaporation rates over the Arabian Sea and southern hemisphere have been studied over the tropical Indian Ocean. The mean rates of evaporation on a seasonal scale over the Arabian Sea during a good and bad monsoon composites were equal (about 2·48 × 10¹⁰ tons/day). The evaporation rates over the southern hemisphere were greater during all the months. The mean evaporation rates over the southern hemisphere on a seasonal scale for the good and bad monsoon composites were 4·4 × 10¹⁰ and 4·6 × 10¹⁰ tons/day respectively. The maximum evaporation rates over the southern hemisphere were observed in August. The anomalies of wind stress, effective radiation at the surface and the heat gain over the ocean also exhibit large variations in August, as compared to other monsoon months.     

Influence of an americium solid phase on americium concentrations in solutions

Americium-241 concentrations in solutions contacting contaminated sediments for up to 2 yr were measured as a function of pH. Steady-state concentrations were reached within a few days. The solubility-limited Am concentration was found to decrease approximately 10-fold with one unit increase in pH. The log equilibrium constant for the solubility of Am_(soil) solid $\text{[Am}{}_{\mathrm{(soil)}}\text{+ H}{}^{\mathrm{+}}\text{? Am}{}_{\mathrm{(aq\; complex)}}{}^{\mathrm{+}}\text{]}$ was found to be ?4.12. The predictions based upon thermodynamic data suggest that Am_{(aq complex)}⁺ is likely to be Am(OH)₂⁺. Although the chemical formula of Am_(soil) was not determined, it does not appear to be Am(OH)₃(a).Published data on sorption coefficients of Am by different rocks, soils, and minerals were critically evaluated. Final Am solution concentrations calculated from the sorption coefficients of a variety of earth materials with several solutions agreed well with the concentrations predicted from the solubility of Am_(soil) solid, indicating that the sorption coefficient data are controlled by Am precipitation.     

Changing depositional environment revealed from sediment components,west of “Swatch of No Ground”, northern Bay of Bengal

The sediment cores of 20 cm length collected from 31 to 83 m range of water depth from the inner shelf of Bay of Bengal west of “Swatch of No Ground” were analyzed for grain size, organic carbon, total nitrogen, calcium carbonate and clay mineralogy. Grain size analysis revealed that the sediment size decreases from west to east within the study area indicating a possible direction of transport towards east parallel to the coast. The grain size also decreases with increasing water depth, i.e. north to south, indicating sediment contribution to the area of study from Hooghly and other local rivers. In the cores studied, illite was the dominant clay mineral which seems to be a product of glacial weathering under arid conditions with its source being the Himalayan region. The organic carbon content was low in the sediments and was attributed to low plankton production or intense oxidation processes. Low calcium carbonate percentage also supports the view of a low productivity in this region. Organic carbon increases gradually from west to east indicating its association with finer sediments and also indicates transport due to currents which drift the organic carbon away before it settles down within the sediments. Higher values relatively closer to the coast in the eastern side indicate additional contribution from Sunderban mangroves. The C/N ratio obtained indicates mixed source of terrestrial and marine for the organic matter in the sediments. Sedimentation rates available for deltaic plains and shelves off Bangladesh when adopted for the present area revealed that a 20 cm long sediment column was deposited in around 10 years. In most of the cores studied, a change in the trend of sediment components and organic carbon was observed at around 10 cm where grain size increases and organic carbon decreases towards the surface inferring that during the last 5 years, possible floods during NE monsoon or due to melting of ice in Himalaya are responsible for releasing additional water and material which brought a change in hydrodynamic conditions. The surface depletion of organic carbon indicates its dilution by the addition of coarser materials.     

Salt-bearing fumarole deposits in the summit crater of Oldoinyo Lengai, Northern Tanzania: interactions between natrocarbonatite lava and meteoric water

Oldoinyo Lengai in the Northern Tanzania rift is the only active nephelinite–carbonatite stratovolcano. We report the discovery of thermonatrite, aphthitalite, halite and sylvite fumarole deposits on recent natrocarbonatite lava flows erupted in the summit crater during the wet season. These salt deposits occur as delicate, concave fringes or tubes that line the cooling cracks in the lava flows and consist of intergrowths of euhedral crystals. The presence of a dark altered zone, depleted in halides and alkalies, adjacent to cooling cracks and observations of steam fumaroles emanating from the fractures suggest that the salts are formed by sublimation from saturated vapours generated by the extrusion of lavas over meteoric water. The crystallisation sequence recorded in the salts suggests that mixing between meteoric steam and magmatic CO₂ and H₂S occurs at high temperatures resulting in the sublimation of carbonates and sulphates. At lower temperatures the vapours are dominated by meteoric steam and sublimate halides. The high solubility of the fumarole salts within meteoric water and their formation only during the wet season implies that these are ephemeral deposits that are unlikely to be preserved in the geological record.     

On the assessment of maximum earthquakes in the alps and adjacent areas

Strong tectonic earthquakes within the crust always occur on already existing faults, and they have the property of a shear rupture. Such earthquakes with surface-wave magnitudes M < 7 obviously have a geometric similarity. Because of this similarity and the validity of the Gutenberg and Richter's energy—magnitude relation, the expression M = 2 log₁₀ L + const., with L = focal length, is valid.The expression L_maxL^* for the maximum focal length, is also valid if L^* is the length of the rectilinear extent of the seismic line on which the maximum earthquake occurs. The bounds of L^* may be given by sharp bends and/or by traversing deep faults. Thus the maximum imaginable earthquake on a seismic line with the length L^* has the magnitude M_max = 2 log₁₀ L^* + const.For the investigated region — the Alps and adjacent areas — from the data of recent and historical strong earthquakes, it follows that M_max = 2 log₁₀ L^* + 1.7, if L^* is measured in kilometres. These limiting values lie in the centre-field of the magnitude range for maximum earthquakes, published by Shebalin in 1970. By the aid of this equation it is also possible to assess the upper limiting value of the accompanying maximum scale intensity.