Petro Gram: An excel-based petrology program for modeling of magmatic processes

Petro Gram is an Excel?based magmatic petrology program that generates numerical and graphical models.Petro Gram can model the magmatic processes such as melting,crystallization,assimilation and magma mixing based on the trace element and isotopic data.The program can produce both inverse and forward geochemical models for melting processes(e.g.forward model for batch,fractional and dynamic melting,and inverse model for batch and dynamic melting).However,the program uses a forward modeling approach for magma differentiation processes such as crystallization(EC:Equilibruim Crystallization,FC:Fractional Crystallization,IFC:Imperfect Fractional Crystallization and In-situ Crystallization),assimilation(AFC:Assimilation Fractional Crystallization,Decoupled FC-A:Decoupled Fractional Crystallization and Assimillation,A-IFC:Assimilation and Imperfect Fractional Crystallization)and magma mixing.One of the most important advantages of the program is that the melt composition obtained from any partial melting model can be used as a starting composition of the crystallization,assimilation and magma mixing.In addition,Petro Gram is able to carry out the classification,tectonic setting,multi-element(spider)and isotope correlation diagrams,and basic calculations including Mg^#,Eu/Eu^*,εSrandεNdwidely used in magmatic petrology.     

Crushing and embedment of proppant packs under cyclic loading:An insigh to enhanced unconventional oil/gas recovery

Crushing and embedment are two critical downhole proppant degradation mechanisms that lead to a significant drop in production outputs in unconventional oil/gas stimulation projects.These persistent production drops due to the non-linear responses of proppants under reservoir conditions put the future utilization of such advanced stimulation techniques in unconventional energy extraction in doubt.The aim of this study is to address these issues by conducting a comprehensive experimental approach.According to the results,whatever the type of proppant,all proppant packs tend to undergo significant plastic deformation under the first loading cycle.Moreover,the utilization of ceramic proppants(which retain proppant pack porosity up to 75％),larger proppant sizes(which retain proppant pack porosity up to 15.2％)and higher proppant concentrations(which retain proppant pack porosity up to 29.5％)in the fracturing stimulations with higher in-situ stresses are recommended to de-escalate the critical consequences of crushing associated issues.Similarly,the selection of resin-coated proppants over ceramic and sand proppants may benefit in terms of obtaining reduced proppant embedment.In addition,selection of smaller proppant sizes and higher proppant concentrations are suggested for stimulation projects at depth with sedimentary formations and lower in-situ stresses where proppant embedment pre-dominates.Furthermore,correlation between proppant embedment with repetitive loading cycles was studied.Importantly,microstructural analysis of the proppant-embedded siltstone rock samples revealed that the initiation of secondary induced fractures.Finally,the findings of this study can greatly contribute to accurately select optimum proppant properties(proppant type,size and concentration)depending on the oil/gas reservoir char-acteristics to minimize proppant crushing and embedment effects.     

Biostratigraphy,Depositional and Diagenetic Processes in Carbonate Rocks from Southern Lebanon: Impact on Porosity and Permeability

Carbonate rocks contain prolific hydrocarbon reserves all over the world, particularly in the Middle East. For exploration and production strategies, it is essential to understand carbonate reservoirs in terms of their internal characteristics, depositional environment, relative age, diagenetic processes and impact on petrophysical properties. This study has been performed on exposed Cretaceous, Paleocene and Miocene marine carbonate sedimentary sequences in two localities (Maghdoucheh and Qennarit) near the city of Sidon (Southern Lebanon). It represents the first comprehensive study that takes into consideration the carbonate reservoir facies, diagenetic history and reservoir quality in the area. Rocks at Maghdoucheh are mainly dominated by limestone beds showing sedimentary structures and erosive bases alternating with microfossil-rich silty marls, related to a shallowing upward sequence in a restricted marine platform environment. Shells of benthic foraminifera and mollusks dominate the fossil assemblage extracted from the studied rocks. The microfossil and nannofossil assemblage detected in the Maghdoucheh sections indicates a middle Miocene age. Rocks at Qennarit are composed of mudstone/wackestone limestone beds rich in planktonic foraminifera and nannofossils related to open marine conditions. Based on the nannofossil content, rocks from Qennarit 1 and 2 are Paleocene and Cretaceous in age, respectively. Four main types of microfacies have been identified, i.e. (1) microbioclastic peloidal calcisiltite, (2) pelagic lime mudstone and wackestone with planktonic microfossils, (3) grainstone/packstone with abundant foraminifera and (4) fenestral bindstones, mudstones and packstones with porostromate microstructures. The porosity-permeability (poro-perm) analysis of representative samples reveals moderate to good porosity but very low permeability. This is mainly due to the presence of large moldic pores that are isolated in nature. The diagenetic features are dominated by micritization and dissolution (both fabric selective and non-fabric selective). Among all diagenetic features, dissolution in both localities contributes to porosity enhancement, while micritization, cementation, compaction and the filled fractures have negative impacts on permeability; hence the overall reservoir quality.     

Oldest Asian Record of Snapping Shrimps (Malacostraca: Alpheidae) from the Kutch Basin, Western India and Associated Biota: Biostratigraphic, Paleoenvironmental and Paleoecological Significance

The oldest Asian record of alpheid shrimps, assigned to genus Alpheus, based on snapping claw fingertips from the Miocene Khari Nadi Formation in the Kutch Basin, western India reported herein, extends the fossil record of the family Alpheidae from Asia by ~22 million years. An early Miocene (Aquitanian) age is estimated based on the associated assemblage of calcareous nannofossils, Sphenolithus disbelemnos, Cyclicargolithus floridanus, and Reticulofenestra haqii. The co-occurring microbiota includes bony fish otolith remains, identified as “genus Gobiidarum”, isolated teeth of Dasyatis rays, Sphyrna sharks, and teleosts, ctenoid and placoid scales, ostracods, belonging to the genera Paractinocythereis, Alocopocythere, Ruggieria? Aglaiocypris, Bairdoppilata, and echinoid spines. Taken together, the microfossil assemblage and data from chemical analyses using Energy Dispersive Spectroscopy, X-Ray Diffraction and Wavelength Dispersive X-Ray Fluorescence of host and associated lithologies suggests prevalence of a shallow (neritic) to coastal marine (intertidal) depositional paleoenvironment.     

基于CMIP5模拟预估21世纪珠江三角洲地区由于海平面上升而导致的淹没区面积

Projections of potential submerged area due to sea level rise are helpful for improving understanding of the influence of ongoing global warming on coastal areas. The Ensemble Empirical Mode Decomposition method is used to adaptively decompose the sea level time series in order to extract the secular trend component. Then the linear relationship between the global mean sea level(GMSL) change and the Zhujiang(Pearl) River Delta(PRD)sea level change is calculated: an increase of 1.0 m in the GMSL corresponds to a 1.3 m(uncertainty interval from1.25 to 1.46 m) increase in the PRD. Based on this relationship and the GMSL rise projected by the Coupled Model Intercomparison Project Phase 5 under three greenhouse gas emission scenarios(representative concentration pathways, or RCPs, from low to high emission scenarios RCP2.6, RCP4.5, and RCP8.5), the PRD sea level is calculated and projected for the period 2006–2100. By around the year 2050, the PRD sea level will rise 0.29(0.21 to 0.40) m under RCP2.6, 0.31(0.22 to 0.42) m under RCP4.5, and 0.34(0.25 to 0.46) m under RCP8.5, respectively.By 2100, it will rise 0.59(0.36 to 0.88) m, 0.71(0.47 to 1.02) m, and 1.0(0.68 to 1.41) m, respectively. In addition,considering the extreme value of relative sea level due to land subsidence(i.e., 0.20 m) and that obtained from intermonthly variability(i.e., 0.33 m), the PRD sea level will rise 1.94 m by the year 2100 under the RCP8.5scenario with the upper uncertainty level(i.e., 1.41 m). Accordingly, the potential submerged area is 8.57×103 km2 for the PRD, about 1.3 times its present area.     

Inter-annual and seasonal variations in hydrological parameters and its implications on chlorophyll a distribution along the southwest coast of Bay of Bengal

Seasonal and inter-annual variability of hydrological parameters and its impact on chlorophyll distribution was studied from January 2009 to December 2011 at four coastal stations along the southwest Bay of Bengal. Statistical analysis(principal component analysis(PCA), two-way analysis of variance(ANOVA) and correlation analysis)showed the significant impact of hydrological parameters on chlorophyll distribution in the study area. The ranges of different parameters recorded were 23.8–33.8°C(SST), 4.00–36.00(salinity), 7.0–9.2(p H), 4.41–8.32 mg/L(dissolved oxygen), 0.04–2.45 μmol/L(nitrite), 0.33–16.10 μmol/L(nitrate), 0.02–2.51 μmol/L(ammonia),0.04–3.32 μmol/L(inorganic phosphate), 10.09–85.28 μmol/L(reactive silicate) and 0.04–13.8 μg/L(chlorophyll).PCA analysis carried out for different seasons found variations in the relationship between physico-chemical parameters and chlorophyll in which nitrate and chlorophyll were positively loaded at PC1(principal component1) during spring inter-monsoon and at PC2(principal component 2) during other seasons. Likewise correlation analysis also showed significant positive relationship between chlorophyll and nutrients especially with nitrate(r=0.734). Distribution of hydrobiological parameters between stations and distances was significantly varying as evidenced from the ANOVA results. The study found that the spatial and temporal distribution of chlorophyll was highly dependent on the availability of nutrients especially, nitrate in the southwest Bay of Bengal coastal waters.     

从构造形成的新旋转假说观点看构造圈的形变规律

本文是为中国地球科学研究者而写的。文中介绍了地球构造圈构造形成的新的旋转假说及其一些成果:构造圈断块性和断裂继承性活动的规律。      

安徽月山岩体的40Ar/39Ar年龄及与其有关的成矿时代估计

安徽月山岩体是长江中下游钢铁成矿带中的一个重要含矿岩体.我们对该岩体的角闪石和黑云母进行了⁴⁰Ar/³⁹Ar年龄测定.角闪石的未扰动年龄谱给出岩体侵位年龄为136Ma.根据黑云母的扰动年龄谱,估计岩体从浸位到矿化（晚期热液作用）的时间间隔不少于9Ma.月山岩体的年龄测定结果以及前人对长江中下游其它含铜岩体的年龄测定结果表明,该区所有铜矿化岩体均形成于136Ma前,且产出于沿江构造单元内.此外,月山岩体的研究还表明,对中酸性岩的年龄测定,封闭温度高的角闪石是较理想的样品,在解释与矿化有关或热液作用发育的岩体的黑云母K-Ar结果时,必须持慎重态度.     

Direct scaling of residual displacements for bilinear and pinching oscillators

The estimation of residual displacements in a structure due to an anticipated earthquake event has increasingly become an important component of performance-based earthquake engineering because controlling these displacements plays an important role in ensuring cost-feasible or cost-effective repairs in a damaged structure after the event. An attempt is made in this study to obtain statistical estimates of constant-ductility residual displacement spectra for bilinear and pinching oscillators wit...     

21世纪的世界石油资源

预测世界石油资源不仅确定了局部区域的能源潜力 ,还有其战略意义。２０世纪最为现实的工作是多次计算了石油的潜在资源 ,而且 ,最新计算的油气资源量通常超过以前的计算 ,并总是因发现以石油、凝析气等不同相态存在的新油田而得到证实。如在２０世纪初 ,П．Уикс确定世界石油资源总量为９５亿ｔ,但到１９５８年已增至２０７０亿ｔ,而到世纪末估计有５４００亿ｔ。在石油资源评价上有如此大的进展与烃类普查方法的完善 ,在油气生成领域内理论工作的成功 ,地球物理和地球化学研究的应用以及在成因基础上对含油气性前景论证的充分有关。…