Trachytic Rock and Associated Fenitization in the Bayan Obo Ore Deposit, Inner Mongolia, China: Evidence for Magmatic-Hydrothermal Mineralization Related to a Carbonatitic Complex

Trachytic rock and its altered rock-fenite-in the Bayan Obo ore district, Inner Mongolia, China, were referred to as slate or feldspar rock before, and identified by the authors for the first time (in 1992). In the paper the mineral assemblages, structures and textures and petrochemical compositions of the rocks, as well as the electron microprobe analysis of feldspars in the rocks are described. The Sm-Nd isochron age of the trachytic rock is 1096±56 Ma, with INd=0.51100+4 (2σ) and εNd(t)= -4.4±0.7. Alterations of the trachytic rock, including microclinization, riebeckitization, aegirinization and biotitization, and accompanied rare element and REE mineralizations are discussed. Based on the occurrence of the trachytic rock and associated fenitization it is deduced that the Bayan Obo Fe-Nb-REE ore deposit is genetically related to magmatic-hydrothermal activity of an alkali carbonatite complex.     

张广才岭新华屯岩体的形成时代与成因研究

全岩－矿物的锶同位素研究结果表明,出露在张广才岭花岗岩带上的新华屯岩体属中侏罗世晚期的产物,其同位素年龄为１６０～１６５Ｍａ,表明该晶洞花岗岩体不属于印支期。地球化学研究结果显示,该岩体属于长英质“Ｉ”分异型,并在岩体就位和岩浆结晶过程中存在少量地壳物质的混染,但控制岩体成分变化的主要因素仍是矿物的结晶分异作用。年轻的钕同位素模式年龄表明该区存在新元古—显生宙的地壳增生。     

硼同位素分馏的实验理论认识和矿床地球化学研究进展

硼是一种中等挥发性元素,具有¹¹B和¹⁰B两个稳定同位素。两个同位素间高达10%的相对质量差使其在地质过程中引起高达-70‰至+75‰的硼同位素变化。硼在自然界主要与氧键合形成三配位(BO₃)和四配位(BO₄)结构,因而¹¹B和¹⁰B间同位素分馏主要受控于三配体(BO₃)和四面体(BO₄)间配分。本文综述了低温和高温地质过程的硼同位素分馏的理论和实验研究进展。在溶液中B(OH)₃和${B(OH)^{-}_{4}}$间硼同位素分馏受pH和热力学p-T条件控制,实验和理论表征获得常温常压条件下的B(OH)₃和$B(OH)^{-}_{4}$间同位素分馏系数(α_3-4)变化范围为1.019 4至1.033 3。低温条件下矿物(如碳酸盐、黏土矿物(蒙脱石和伊利石)、针铁矿、水锰矿、硼酸盐)与溶液间硼同位素分馏行为除了受p-T-pH影响外,矿物表面吸附引起的分馏效应十分显著。在中高温过程(蒙脱石伊利石化、富硼电气石和白云母矿物与热液流体,以及硅酸盐熔体与流体)中硼同位素分馏行为受到硼配位构型、化学成分以及物理化学条件的控制。随着硼同位素分馏机理研究的深入以及越来越完善的地质储库硼同位素端员特征表征,硼同位素地球化学指标可以灵敏示踪成矿物质来源、探究成矿作用与成因模式和重建成矿过程物理化学条件。目前矿床硼同位素地球化学研究的难点在于实现不同赋存相(如流体、矿物和熔体)中硼配位键合结构和硼同位素组成的精细化表征。     

岩溶地区人类活动的水文效应研究现状及展望

在全球气候变化背景下,加之岩溶生态系统的脆弱性及敏感性,地表水与地下水交换迅速,岩溶水动力系统对人类活动及其造成的生态环境变化反馈敏感。岩溶地区人类活动导致的植被退化、石漠化等环境问题已对岩溶地区的水文水循环过程造成了严重影响,水资源问题已成为岩溶地区发展的重要限制因素。本文在对岩溶生态系统及水文环境特性分析的基础上,从土地利用变化的水文效应,人类活动对降水—径流的影响、岩溶水资源的开发利用、岩溶地下水污染及水文模型在岩溶地区的应用等方面,概述了岩溶地区人类活动水文效应的相关研究现状与不足,总结了未来岩溶地区人类活动水文效应的5个研究趋势,并探讨了研究中的重点及难点问题。     

浙西南八都群变火山岩系及变晶糜棱岩的同位素年龄及其构造意义

浙西南八都群变火山岩系的Ｓｍ－Ｎｄ全岩等时线参考年龄为２０１４±４３Ｍａ。其中变质玄武岩具有扁平的ＲＥＥ模型。这说明在早元古，华夏古陆张裂并发生一次陆壳增生事件。对该区与具有逆掩断层性质的Ｍ１大型韧性剪切带有关的含石榴石变晶糜棱岩给出１５１８±１６Ｍａ和１００１±１４Ｍａ的Ｓｍ－Ｎｄ和Ｒｂ－Ｓｒ石榴石十全岩等时线年龄。前者指示原含石榴石变质岩的变质时代；后者指示的是糜棱岩化时代。它们可能分别与中元古时华夏古陆的再次张裂，及晚元古时龙泉群沉积盆地闭合有关。     

长石矿物的三维热释光谱图研究

通过最新研制的三维热释光光谱测量仪器，对长石热释光光谱的分析，,可以寻找其各个波段热释光信号的响应灵敏度差异。测试结果表明，长石矿物不同波长段的热释光量随辐照剂量的增加，呈现不同的增长特性；同时，长石热释光谱图显示出热释光信号光谱的红光／红外光波段的能量释放比相应蓝／紫光波段的能量的释放，提前大约10℃产生，但是各自能量释放的峰值几乎发生在同一温度处。样品发出的热释光中红光部分的峰峰值与紫光部分的峰峰值相比较，有明显的差别，三维谱图显示出该样品分布在从绿光波段直到红光／远红外光波段（500－850nm）的热释光量，明显比分布在紫光波段附近的相应热释光量要大的多。     

黑龙江多宝山花岗闪长岩的锆石SHRIMP U-Pb年龄及其地质意义

采用锆石SHRIMP U-Pb测年方法对多宝山花岗闪长岩进行定年,结果为479.5±4.6 Ma,据多宝山、铜山铜(钼)矿床中辉钼矿的Re-Os同位素等时线年龄(506±14 Ma),结合区域地质资料,认为多宝山花岗闪长岩侵位年龄为前奥陶纪,被多宝山花岗闪长岩岩体侵位的矿区地层时代、多宝山铜矿成矿主期、与成矿有关的多宝山北西向控矿、容矿构造应属于前奥陶纪,且多宝山花岗闪长岩形成于火山岛弧或活动的陆缘构造环境,岩浆来源以幔源物质为主,同熔了部份壳源物质.     

Highly fractionated I-type granites in NE China (I): geochronology and petrogenesis

Northeastern (NE) China is the easternmost part of the Central Asian Orogenic Belt (CAOB), which is celebrated for its accretionary tectonics and the world's most important juvenile crust production in the Phanerozoic era. Abundant granitoids occur in the Great Xing'an, Lesser Xing'an and Zhangguangcai Ranges in NE China. This paper presents partial results of a series of studies on the granitoids from this region, aiming to understand their role in the building of new continental crust in eastern Asia. Three composite granite plutons (Xinhuatun, Lamashan and Yiershi) were chosen for geochemical and isotopic study in order to determine their emplacement ages and petrogenesis. Petrographically, they range from granodiorite (minor), monzogranite, syenogranite to alkali-feldspar granite. Quartz and perthitic feldspar are principal phases, accompanied by minor amounts of plagioclase, biotite (<5%) and other accessory minerals. In addition, many contain abundant miarolitic cavities which suggest that they were emplaced at shallow levels with extensive fractional crystallization. Geochemically, the granites are silica-rich, peraluminous and have high contents of alkalis. They invariably show enrichment in light rare earth elements (LREE) and significant negative Eu anomalies. All the granitic rocks demonstrate the characteristic negative anomalies in Ba, Nb, Sr, P, Eu, and Ti, and a positive anomaly in Pb in the spidergram.

The emplacement of the Xinhuatun pluton took place at 184±4 Ma as revealed by zircon SHRIMP U–Pb data. This is also supported by the slightly younger Rb–Sr whole-rock (WR) isochron age of 173±3 Ma. A whole-rock (WR) Rb–Sr isochron age of 154±3 Ma was obtained for the Lamashan pluton, which is interpreted as close to the time of emplacement. The Yiershi pluton was intruded at about 140 Ma as evidenced by a zircon U–Pb age of 137±2 Ma and WR Rb–Sr isochron age of 143±5 Ma. Biotite-WR Rb–Sr isochrons and ⁴⁰Ar/³⁹Ar ages of feldspars allow us to estimate the cooling rate of each pluton.

Geochemical data suggest that the rocks are highly fractionated I-type granites. Fractionation of biotite and feldspars was the principal process of magmatic differentiation and responsible for major element variation. Rb, Sr and Ba concentrations were controlled by feldspar separation, whereas REE elements were fractionated by accessory minerals, such as apatite, allanite and monazite.     

吉黑东部中生代两种机制的碰撞构造

吉林、黑龙江东部地区中生代存在两种机制的碰撞构造，即由南北陆块碰撞（华北古板块与张广才—佳木斯地块）所形成的近东西走向的构造（古洞河—富尔河碰撞带）和东部地体向陆缘增生挤压所产生的南北走向的褶皱—推覆构造。前者由早期构造杂岩带及叠加于其上的印支期韧性剪切带和推覆构造所代表，后者是在印支期的褶皱和糜棱岩化带之上发育的推覆构造。两种碰撞构造的主要发育时期为晚中生代（Ｊ＿３—Ｋ）。     

元素碳碳同位素在古环境研究中的应用

元素碳几乎完全来源于植被的燃烧,长期广泛地分布于大气、土壤、沉积物、岩石、水体和冰体等自然界载体中,记录了大量的古环境信息。利用元素碳碳同位素(δ13CEC)指标来反映古气候、古植被信息是将元素碳应用到古环境研究的一个重要方面,本文通过总结国内外学者利用δ13CEC指标进行古环境研究的现状,总结出对于"直接利用δ13CEC指标进行古环境恢复"这一关键问题还存在不同认识。燃烧前后物质的碳同位素是否发生变化是利用δ13CEC进行古环境研究时需要考虑的一个重要问题,国内外学者近20年来对C3、C4植物开展了大量燃烧实验,主要结论是C3植物燃烧前后物质的碳同位素变化(Δδ13C)较小,在±1‰以内,而C4植物变化范围较大,在0‰～-9‰之间;此外,文中还讨论了元素碳外源输入等可能影响δ13CEC指标的因素。建议在利用δ13CEC指标进行古环境重建之前,有必要对δ13CEC进行详细的基础研究工作,进一步研究表土δ13CEC与地表植被相关性以及元素碳外源输入等问题。