Non-woven polypropylene fabric modified with carbon nanotubes and decorated with nanoakaganeite for arsenite removal

Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L^?1, at pH 6.5 and with a sorbent dose of 5 g L^?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g^?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g^?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.     

Groundwater characteristics within loessic deposits: the coastal springs of Los Acantilados,Mar del Plata,Argentina

The urban growth of the southern neighborhoods of Mar del Plata City provoked significant changes in the groundwater balance of the loessic sequences. These regional loessic levels with a significant portion of volcanic ash layers were reported subject to fluoride and nitrate concentrations. Residential houses pump from sands located 70 m depth and withdraw the sewages to depths less than 5 m. These effects cause significant local and seasonal (summer) increments of the water table outcropping via springs at certain unconformities of the coastal cliffs. A mathematical model was applied to analyze the water level lowering at the productive levels, while there is a decrease in the quality of the upper levels subject to waste discharges. Much of this groundwater flow is concentrated in unconformities between different types of sediments. Human activities have affected the aquifer dynamics increasing the groundwater pumping rates and the return velocity of the sewages. This should be considered in the management strategies of coastal hydric resources.     

Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase,orthopyroxene, clinopyroxene,glass geobarometer,and application to Mt. Ruapehu,New Zealand

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).     

Evolution of the space concept in locational theories of intraurban economic activity

The concept of space is fundamental to various theories on the organization of intraurban economic activities. This concept has evolved from the totalitarian perspective of Greek philosophers into the contemporary space–time dichotomy. Through examining the historical concepts of space, the most significant limits of organizational theories regarding economic activity may be identified. Therefore, the aim of this paper is to analyze the evolution of the concept of space in addition to the relationship of this concept with different theories on the organization of intraurban economic activities. New reflections on the concept of space are presented in order to provide insight into future directions and perspectives in the analysis of urban space. Finally, this article explores the contemporary space–time dichotomy as applied to the organization of economic activities in the city and reflects upon space as an active, dynamic, and biased factor in such organization.     

Influence of the sediment delivery ratio index on the analysis of silting and break risk in the Plasencia reservoir (Central System,Spain)

The random forest method was used to generate susceptibility maps for debris flows, rock slides, and active layer detachment slides in the Donjek River area within the Yukon Alaska Highway Corridor, based on an inventory of landslides compiled by the Geological Survey of Canada in collaboration with the Yukon Geological Survey. The aim of this study is to develop data-driven landslide susceptibility models which can provide information on risk assessment to existing and planned infrastructure. The factors contributing to slope failure used in the models include slope angle, slope aspect, plan and profile curvatures, bedrock geology, surficial geology, proximity to faults, permafrost distribution, vegetation distribution, wetness index, and proximity to drainage system. A total of 83 debris flow deposits, 181 active layer detachment slides, and 104 rock slides were compiled in the landslide inventory. The samples representing the landslide free zones were randomly selected. The ratio of landslide/landslide free zones was set to 1:1 and 1:2 to examine the results of different sample ratios on the classification. Two-thirds of the samples for each landslide type were used in the classification, and the remaining 1/3 were used to evaluate the results. In addition to the classification maps, probability maps were also created, which served as the susceptibility maps for debris flows, rock slides, and active layer detachment slides. Success and prediction rate curves created to evaluate the performance of the resulting models indicate a high performance of the random forest in landslide susceptibility modelling.     

Statistical forecast of the marine surge

Natural Hazards - This paper studies different machine learning methods for solving the regression problem of estimating the marine surge value given meteorological data. The marine surge is...     

Three decades of landslide activity in western Nepal: new insights into trends and climate drivers

In recent decades, landslide disasters in the Himalayas, as in other mountain regions, are widely reported to have increased. While some studies have suggested a link to increasing heavy rainfall under a warmer climate, others pointed to anthropogenic influences on slope stability, and increasing exposure of people and assets located in harm’s way. A lack of sufficiently high-resolution regional landslide inventories, both spatially and temporally, has prevented any robust consensus so far. Focusing on Far-Western Nepal, we draw on remote sensing techniques to create a regional inventory of 26,350 single landslide events, of which 8778 date to the period 1992–2018. These events serve as a basis for the analyses of landslide frequency relationships and trends in relation to precipitation and temperature datasets. Results show a strong correlation between the annual number of shallow landslides and the accumulated monsoon precipitation (r = 0.74). Furthermore, warm and dry monsoons followed by especially rainy monsoons produce the highest incidence of shallow landslides (r = 0.77). However, we find strong spatial variability in the strength of these relationships, which is linked to recent demographic development in the region. This highlights the role of anthropogenic drivers, and in particular road cutting and land-use change, in amplifying the seasonal monsoon influence on slope stability. In parallel, the absence of any long-term trends in landslide activity, despite widely reported increase in landslide disasters, points strongly to increasing exposure of people and infrastructure as the main driver of landslide disasters in this region of Nepal. By contrast, no climate change signal is evident from the data.

     

Enzymatic activity in the rhizosphere of Spartina maritima: potential contribution for phytoremediation of metals

Extracellular enzymatic activity (EEA) of five enzymes (peroxidase, phenol oxidase, beta-glucosidase, beta-N-acetylglucosaminidase and acid phosphatase) was analysed in sediments colonised by Spartina maritima in two salt marshes (Rosário and Pancas) of the Tagus estuary (Portugal) with different characteristics such as sediment parameters and metal contaminant levels. Our aim was a better understanding of the influence of the halophyte on microbial activity in the rhizosphere under different site conditions, and its potential consequences for metal cycling and phytoremediation in salt marshes. Acid phosphatase and beta-N-acetylglucosaminidase presented significantly higher EEA in Rosário than in Pancas, whereas the opposite occurred for peroxidase. This was mainly attributed to differences in organic matter between the two sites. A positive correlation between root biomass and EEA of hydrolases (beta-glucosidase, beta-N-acetylglucosaminidase and acid phosphatase) was found, indicating a possible influence of the halophyte in sediment microbial function. This would potentially affect metal cycling in the rhizosphere through microbial reactions.     

The mesoscale variability in the Caribbean Sea. Part I: Simulations and characteristics with an embedded model

The variability in the Caribbean Sea is investigated using high resolution (1/15°) general circulation model experiments. For the first time in this region, simulations were carried out with a 2-way nested configuration of the NEMO primitive equation model. A coarse North Atlantic grid (1/3°) reproduces the main features of the North Atlantic and Equatorial circulation capable of influencing ocean dynamics in the Caribbean Sea. This numerical study highlights strong dynamical differences among basins and modifies the view that dynamics are homogeneous over the whole Caribbean Basin. The Caribbean mean flow is shown to organize in two intense jets flowing westward along the northern and southern boundaries of the Venezuela Basin, which merge in the center of the Colombia Basin. Diagnostics of model outputs show that width, depth and strength of baroclinic eddies increase westward from the Lesser Antilles to the Colombia Basin. The widening and strengthening to the west is consistent with altimetry data and drifter observations. Although influenced by the circulation in the Colombia Basin, the variability in the Cayman Basin (which also presents a westward growth from the Chibcha Channel) is deeper and less energetic than the variability in the Colombia/Venezuela Basins. Main frequency peaks for the mesoscale variability present a westward shift, from roughly 50 days near the Lesser Antilles to 100 days in the Cayman Basin, which is associated with growth and merging of eddies.     

Dynamics of coastline changes in Mexico

Journal of Geographical Sciences - The goal of our work was to locate and quantify changes that occurred in 66% of the Mexican coastline, based on four land cover maps generated by the Mexican...