Diffusion of divalent cations in garnet: multi-couple experiments

We demonstrate the possibility of studying several diffusion couples in a single run, i.e. under almost similar P–T–t– conditions, allowing direct comparison of the diffusion rates in different diffusion couples. Thus the duration of experimental study and the risk of failure of expensive experimental equipment can be decreased considerably. The diffusion experiments were carried out in piston-cylinder apparatus. Gem-quality garnets of almandine, spessartine and grossular compositions together with inclusion-rich eclogitic garnets were embedded in a powder of natural pyrope and annealed together under dry conditions at P = 1.9–3.2 GPa and T = 1,070–1,400°C. Diffusion profiles were measured by electron microprobe and fitted numerically on the basis of multicomponent diffusion theory. The datasets derived from different diffusion couples yields parameters of the Arrhenius equation for Ca, Mg and Fe in natural eclogitic garnets and Mg, Mn and Fe in gem-quality garnets. We have also studied the effect of grain-boundary diffusion in the sintered pyrope matrix on interdiffusion on the basis of 2D modeling. Under conditions analogous to those of our experimental runs, we show that observed irregularities in some measured diffusion profiles (not applied for the diffusion modeling) can be directly related to the superposition of local grain-boundary diffusion on dominant volume diffusion.     

Preparing Geographers for Interdisciplinary Research: Graduate Training at the Interface of the Natural and Social Sciences

Recent debates about the state of geography raise valuable questions about how the discipline can and should change in response to shifting institutional realities. Focusing on the breadth and interdisciplinarity of geography, these discussions often overlook the role of pedagogy—particularly graduate training—in adapting the discipline to new institutional landscapes. Drawing on experiences as current and recent geography doctoral students, we identify institutional seedlings of opportunity that can be cultivated toward a spectrum of alternative doctoral training models. These alternatives offer significant opportunities to better prepare early-career geographers for success and to solidify geography's position as a leader in interdisciplinary research.     

Excitation of ion waves by charged dust beams in ionospheric aerosol release experiments

Ion waves excited by charged dust beams streaming across or along the geomagnetic field in the ionosphere may be generated by plasma instabilities during aerosol release experiments. The injection speed of the dust and gas is comparable to or larger than the ion thermal speed in the background plasma. The dust grains can get charged by plasma collection from the ambient ionosphere, and can thus act as a charged beam that excites instabilities in the background plasma. The theory is applied to relatively early time scales of the order of in the dust-gas cloud expansion, with wave frequencies that are larger than the ion gyrofrequency, and collisions with neutrals are included.     

Chesapeake Bay Plume Morphology and the Effects on Nutrient Dynamics and Primary Productivity in the Coastal Zone

To determine the effects of the Chesapeake Bay outflow plume on the coastal ocean, nutrient concentrations and climatology were evaluated in conjunction with nitrogen (N) and carbon (C) uptake rates during a 3-year field study. Sixteen cruises included all seasons and captured high- and low-flow freshwater input scenarios. Event-scale disturbances in freshwater flow and wind speed and direction strongly influenced the location and type of plume present and thus the biological uptake of N and C. As expected, volumetric primary productivity rates did not always correlate with chlorophyll a concentrations, suggesting that high freshwater flow does not translate into high productivity in the coastal zone; rather, high productivity was observed during periods where recycling processes may have dominated. Results suggest that timing of meteorological events, with respect to upwelling or downwelling favorable conditions, plays a crucial role in determining the impact of the estuarine plume on the coastal ocean.     

Meteorological factors affecting the speed of movement and related impacts of extratropical cyclones along the U.S. east coast

The speeds of historical cool-season extratropical cyclones along the U.S. east coast, hereafter East Coast Winter Storms (ECWS), occurring during the period from 1951 to 2006 were computed. Average storm speed was 13.8 ms⁻¹ with stronger storms generally moving faster than weaker storms and faster storms forming during the midwinter months (December–March). There was no clear trend in ECWS speed during the time period, although considerable season-to-season variability was present. The monthly and seasonal variations in storm speed could not be attributed to the El Ni?o-Southern Oscillation or North Atlantic Oscillation (NAO) alone. However, the speed of ECWS was considerably slower when both El Ni?o and the negative phase of NAO occurred simultaneously. Characteristic patterns in the upper levels of the atmosphere, specifically 300 hPa zonal winds and 500 hPa geopotential heights, were present during periods when ECWS speeds were among the slowest (and separately fastest). For slow storm speed, these patterns also prevailed during months in which El Ni?o and negative NAO phase occurred. These patterns were also present during months with extended runs of high oceanic storm surge. This provides a qualitative link between the atmospheric conditions associated with slow storms and potentially high coastal storm surge impacts. Among the prime consequences of ECWS speed are extended periods of high storm surge, mainly due to slow-moving storms. The sustained high tidal levels often lead to substantial damage caused by coastal flooding, overwash, and beach erosion.     

Nitrogen uptake and primary productivity rates in the Mid-Atlantic Bight (MAB)

Nutrient concentrations, primary productivity, and nitrogen uptake rates were measured in coastal waters of the Mid-Atlantic Bight over a two-year period that included measurements from all four seasons. In order to assess carbon productivity and nitrogen demand within the context of the physical environment, the region was divided into three distinct hydrographic regimes: the Chesapeake and Delaware Bay outflow plumes (PL), the southern Mid-Atlantic shelf influenced by the Gulf Stream (SS), and the mid-shelf area to the north of the Chesapeake Bay mouth (MS). Annual areal rates of total nitrogen (N) uptake were similar across all regions (10.9 ± 2.1 mol N m⁻² y⁻¹). However, annual areal rates of net primary productivity were higher in the outflow plume region (43 mol C m⁻² y⁻¹), than along the Mid-Atlantic shelf and in areas influenced by the Gulf Stream (41 and 34 mol C m⁻² y⁻¹, respectively). Rates of net primary productivity were not well correlated with Chl a concentrations and were uncoupled with net N uptake rates. Seasonally averaged annual areal rates of net primary productivity for the Mid-Atlantic Bight measured in this study were higher than those calculated in previous decades and provide important validation information for biogeochemical models and satellite remote sensing algorithms developed for the region.     

Modest diatom responses to regional warming on the southeast Tibetan Plateau during the last two centuries

A general mean annual temperature increase accompanied with substantial glacial retreat has been noted on the Tibetan Plateau during the last two centuries but most significantly since the mid 1950s. These climate trends are particularly apparent on the southeastern Tibetan Plateau. However, the Tibetan Plateau (due to its heterogeneous mountain landscape) has very complex and spatially differing temperature and precipitations patterns. As a result, intensive palaeolimnological investigations are necessary to decipher these climatic patterns and to understand ecological responses to recent environmental change. Here we present palaeolimnological results from a ²¹⁰Pb/¹³⁷Cs-dated sediment core spanning approximately the last 200 years from a remote high-mountain lake (LC6 Lake, working name) on the southeastern Tibetan Plateau. Sediment profiles of diatoms, organic variables (TOC, C:N) and grain size were investigated. The ²¹⁰Pb record suggests a period of rapid sedimentation, which might be linked to major tectonic events in the region ca. 1950. Furthermore, unusually high ²¹⁰Pb supply rates over the last 50 years suggest that the lake has possibly been subjected to increasing precipitation rates, sediment focussing and/or increased spring thaw. The majority of diatom taxa encountered in the core are typical of slightly acidic to circumneutral, oligotrophic, electrolyte-poor lakes. Diatom species assemblages were rich, and dominated by Cyclotella sp., Achnanthes sp., Aulacoseira sp. and fragilarioid taxa. Diatom compositional change was minimal over the 200-year period (DCCA = 0.85 SD, p = 0.59); only a slightly more diverse but unstable diatom assemblage was recorded during the past 50 years. The results indicate that large-scale environmental changes recorded in the twentieth century (i.e. increased precipitation and temperatures) are likely having an affect on the LC6 Lake, but so far these impacts are more apparent on the lake geochemistry than on the diatom flora. Local and/or regional peculiarities, such as increasing precipitation and cloud cover, or localized climatic phenomena, such as negative climate feedbacks, might have offset the effects of increasing mean surface temperatures.     

Petrography,mineral chemistry,and crystallization history of olivine‐phyric shergottite NWA 6234: A new melt composition

Knowledge of Martian igneous and mantle compositions is crucial for understanding Mars' mantle evolution, including early differentiation, mantle convection, and the chemical alteration at the surface. Primitive magmas provide the most direct information about their mantle source regions, but most Martian meteorites either contain cumulate olivine or crystallized from fractionated melts. The new Martian meteorite Northwest Africa (NWA) 6234 is an olivine‐phyric shergottite. Its most magnesian olivine cores (Fo₇₈) are in Mg‐Fe equilibrium with a magma of the bulk rock composition, suggesting that it represents a melt composition. Thermochemical calculations show that NWA 6234 not only represents a melt composition but is a primitive melt derived from an approximately Fo₈₀ mantle. Thus, NWA 6234 is similar to NWA 5789 and Y 980459 in the sense that all three are olivine‐phyric shergottites and represent primitive magma compositions. However, NWA 6234 is of special significance because it represents the first olivine‐phyric shergottite from a primitive ferroan magma. On the basis of Al/Ti ratio of pyroxenes in NWA 6234, the minor components in olivine and merrillite, and phosphorus zoning of olivine, we infer that the rock crystallized completely at pressures consistent with conditions in Mars' upper crust. The textural intergrowths of the two phosphates (merrillite and apatite) indicate that at a very last stage of crystallization, merrillite reacted with an OH‐Cl‐F‐rich melt to form apatite. As this meteorite crystallized completely at depth and never erupted, it is likely that its apatite compositions represent snapshots of the volatile ratios of the source region without being affected by degassing processes, which contain high OH‐F content.     

Ries crater and suevite revisited—Observations and modeling Part I: Observations

We report results of an interdisciplinary project devoted to the 26 km‐diameter Ries crater and to the genesis of suevite. Recent laboratory analyses of “crater suevite” occurring within the central crater basin and of “outer suevite” on top of the continuous ejecta blanket, as well as data accumulated during the past 50 years, are interpreted within the boundary conditions imposed by a comprehensive new effort to model the crater formation and its ejecta deposits by computer code calculations (Artemieva et al. 2013). The properties of suevite are considered on all scales from megascopic to submicroscopic in the context of its geological setting. In a new approach, we reconstruct the minimum/maximum volumes of all allochthonous impact formations (108/116 km³), of suevite (14/22 km³), and the total volume of impact melt (4.9/8.0 km³) produced by the Ries impact event prior to erosion. These volumes are reasonably compatible with corresponding values obtained by numerical modeling. Taking all data on modal composition, texture, chemistry, and shock metamorphism of suevite, and the results of modeling into account, we arrive at a new empirical model implying five main consecutive phases of crater formation and ejecta emplacement. Numerical modeling indicates that only a very small fraction of suevite can be derived from the “primary ejecta plume,” which is possibly represented by the fine‐grained basal layer of outer suevite. The main mass of suevite was deposited from a “secondary plume” induced by an explosive reaction (“fuel‐coolant interaction”) of impact melt with water and volatile‐rich sedimentary rocks within a clast‐laden temporary melt pool. Both melt pool and plume appear to be heterogeneous in space and time. Outer suevite appears to be derived from an early formed, melt‐rich and clast‐poor plume region rich in strongly shocked components (melt ? clasts) and originating from an upper, more marginal zone of the melt pool. Crater suevite is obviously deposited from later formed, clast‐rich and melt‐poor plumes dominated by unshocked and weakly shocked clasts and derived from a deeper, central zone of the melt pool. Genetically, we distinguish between “primary suevite” which includes dike suevite, the lower sublayer of crater suevite, and possibly a basal layer of outer suevite, and “secondary suevite” represented by the massive upper sublayer of crater suevite and the main mass of outer suevite.     

Geochemical studies of the SUBO 18 (Enkingen) drill core and other impact breccias from the Ries crater,Germany

Suevite and melt breccia compositions in the boreholes Enkingen and Polsingen are compared with compositions of suevites from other Ries boreholes and surface locations and discussed in terms of implications for impact breccia genesis. No significant differences in average chemical compositions for the various drill cores or surface samples are noted. Compositions of suevite and melt breccia from southern and northeastern sectors of the Ries crater do not significantly differ. This is in stark contrast to the published variations between within‐crater and out‐of‐crater suevites from northern and southern sectors of the Bosumtwi impact structure, Ghana. Locally occurring alteration overprint on drill cores—especially strong on the carbonate‐impregnated suevite specimens of the Enkingen borehole—does affect the average compositions. Overall, the composition of the analyzed impact breccias from Ries are characterized by very little macroscopically or microscopically recognized sediment‐clast component; the clast populations of suevite and impact melt breccia are dominated consistently by granitic and intermediate granitoid components. The Polsingen breccia is significantly enriched in a dioritic clast component. Overall, chemical compositions are of intermediate composition as well, with dioritic‐granodioritic silica contents, and relatively small contributions from mafic target components. Selected suevite samples from the Enkingen core have elevated Ni, Co, Cr, and Ir contents compared with previously analyzed suevites from the Ries crater, which suggest a small meteoritic component. Platinum‐group element (PGE) concentrations for some of the enriched samples indicate somewhat elevated concentrations and near‐chondritic ratios of the most immobile PGE, consistent with an extraterrestrial contribution of 0.1–0.2% chondrite‐equivalent.