REE fractionation and Ce anomalies in weathered Karoo dolerite

Analyses of samples from a weathering profile on Karoo dolerite allow elements to be divided into three groups depending on their behaviour. Si, K, Na, Mg, Ca, Sr, Ba and V are mobilized and removed from weathered products. Fe, Al. Ti, Zr, Hf, Zn, Cu, Sc, Co and Ni are immobile. REE, Y, and to a lesser extent Cr, are mobile and redistributed within the profile without a net loss of these elements from the profile. Large positive Ce anomalies are developed in oxidized weathered products by preferential leaching of the other REE's. Negative Ce anomalies and REE enrichment is a feature of less altered dolerite.     

秦岭凤太矿田层控铅锌(铜)矿床的主要成矿特征及成矿模式

以较详细的资料论述了秦岭凤太矿田层控铅锌(铜)矿床的主要成矿特征。包括反映成矿地质环境、成矿方式、成矿物质来源和成矿物理化学条件等方面的特征,据上述综合特征提出了海底喷气-沉积成矿模式。     

Information infrastructure for Australia’s Integrated Marine Observing System

Australia’s Integrated Marine Observing System (IMOS, imos.org.au) is research infrastructure to establish an enduring observing program for Australian oceanic waters and shelf seas. The observations cover physical, biological, and chemical variables to address themes of multi-decadal ocean change, climate variability and weather extremes, boundary currents and inter-basin flows, continental shelf processes and ecosystem responses.IMOS observations are collected by national facilities based on various platform types and operated by partner institutions around the country. In this paper we describe the infrastructure and workflows developed to manage and distribute the data to the public. We highlight the existing standards and open-source software we have adopted, and the contributions we have made. To demonstrate the value of this infrastructure we provide some illustrations of use and uptake.All IMOS data are freely and openly available to the public via the Ocean Portal (https://imos.aodn.org.au). All IMOS-developed software is open-source and accessible at https://github.com/aodn.     

Weighted merge context for clustering and quantizing spatial data with self-organizing neural networks

This publication presents a generalization of merge context, named weighted merge context (WMC), which is particularly useful for clustering and quantizing spatial data with self-organizing neural networks. In contrast to merge context, WMC does not depend on a predefined (sequential) ordering of the data; distance is evaluated by recursively taking neighboring observations into account. For this purpose, WMC utilizes a weight matrix that describes the neighborhood relationships between observations. This property distinguishes WMC from existing approaches like contextual neural gas (NG) or the GeoSOM, which force spatially close observations to be represented by similar prototypes, but neglected the similarity of the observations’ neighborhoods. For practical studies, WMC is combined with the NG algorithm to obtain weighted merging NG (WMNG). The properties of WMNG and its usefulness for clustering and quantizing spatial data are investigated on two different case studies which utilize an simulated binary grid and a real-world continuous data set.     

The two basic components of the interstellar neutral hydrogen and its relation with the galactic structure

The two basic components of the neutral hydrogen, cool dense clouds merged in a hotter tenuous medium, are studied using 21 cm absorption data of the Parkes Survey. The mean parameters obtained for the typical clouds next to the galactic plane are τ_p = 1.7, velocity half-width=3.3 km s^?1. Their temperatures areT _sc ≥40 K with a meanT _sc =63±12 K and the obtained hot gas density isn _HH=(0.15±0.05) atom cm^?3. Theoretical analysis following Giovanelli and Brown (1973) reveals that the pressure equilibrium condition (n _HH+2n _e )·T _SH≈n _HC·T _sc is compatible with the quoted values if it is assumed that the cosmic abundances in the interstellar medium are below the adopted normal solar abundance. This lack of heavy elements suggests accretion to grains which is consistent with the observed narrow concentration of the dark matter on the galactic layer (≤100 pc halfwidth). The same pressure condition leads to a mean cool cloud density ofn _HC～30 atom cm^?3 and a hot gas temperature ofT _SH～10 500 K. Comparison with data from Hii regions suggests that the cool clouds are somewhat denser and less extensive than such regions. An explanation for it is the expansion that the Hii regions went through in their origin. Comparison with 21 cm emission data shows that the cloud galactic layer is only about a quarter as thick as the hot gas layer. All the present results suggest that only such clouds can be spatially related with the typical I population associated with the spiral structure.     

A four-component ecosystem model of biological activity in the Arabian Sea

A coupled, physical-biological model is used to study the processes that determine the annual cycle of biological activity in the Arabian Sea. The physical model is a system with a surface mixed layer imbedded in the upper layer, and fluid is allowed to move between layers via entrainment, detrainment and mixing processes. The biological model consists of a set of advective-diffusive equations in each layer that determine the nitrogen concentrations in four compartments: nutrients, phytoplankton, zooplankton and detritus. Coupling is provided by the horizontal-velocity, layer-thickness, entrainment and detrainment fields from the physical solution. Surface forcing fields (such as wind stress and photosynthetically active radiation) are derived from monthly climatological data, and the source of nitrogen for the system is upward diffusion of nutrients from the deep ocean into the lower layer. Our main-run solution compares favorably with observed physical and biological fields; in particular, it is able to simulate all the prominent phytoplankton blooms visible in the CZCS data. Three bloom types develop in response to the physical processes of upwelling, detrainment and entrainment. Upwelling blooms are strong, long-lasting events that continue as long as the upwelling persists. They occur during the Southwest Monsoon off Somalia, Oman and India as a result of coastal alongshore winds, and at the mouth of the Gulf of Aden through Ekman pumping. Detrainment blooms are intense, short-lived events that develop when the mixed layer thins abruptly, thereby quickly increasing the depth-averaged light intensity available for phytoplankton growth. They occur during the fall in the central Arabian Sea, and during the spring throughout most of the basin. In contrast to the other bloom types, entrainment blooms are weak because entrainment steadily thickens the mixed layer, which in turn decreases the depth-averaged light intensity. There is an entrainment bloom in the central Arabian Sea during June in the solution, but it is not apparent in the CZCS data. Bloom dynamics are isolated in a suite of diagnostic calculations and test solutions. Some results from these analyses are the following. Entrainment is the primary nutrient source for the offshore bloom in the central Arabian Sea, but advection and recycling also contribute. The ultimate cause for the decay of the solution's spring (and fall) blooms is nutrient deprivation, but their rapid initial decay results from grazing and self shading. Zooplankton grazing is always an essential process, limiting phytoplankton concentrations during both bloom and oligotrophic periods. Detrital remineralization is also important: in a test solution without remineralization, nutrient levels drop markedly in every layer of the model and all blooms are severely weakened. Senescence, however, has little effect: in a test solution without senescence, its lack is almost completely compensated for by increased grazing. Finally, the model's detrainment blooms are too brief and intense in comparison to the CZCS data; this difference cannot be removed by altering biological parameters, which suggests that phytoplankton growth in the model is more sensitive to mixed-layer thickness than it is in the real ocean.     

Holocene vegetation and fire dynamics in the supra‐mediterranean belt of the Nebrodi Mountains (Sicily,Italy)

High‐resolution pollen, macrofossil and charcoal data, combined with accelerator mass spectrometry ¹⁴C dating and multivariate analysis, were used to reconstruct Holocene vegetation and fire dynamics at Urio Quattrocchi, a small lake in the supra‐mediterranean belt in the Nebrodi Mountains of Sicily (Italy). The data suggest that after 10 000 cal a BP increasing moisture availability supported closed forests with deciduous (Quercus cerris, Fagus sylvatica and Fraxinus spp.) and evergreen (Quercus ilex) species. Species‐rich closed forest persisted until 6850 cal a BP, when Neolithic activities caused a forest decline and affected plant diversity. Secondary forest with abundant Ilex aquifolium recovered between 6650 and 6000 cal a BP, indicating moist conditions. From 5000 cal a BP, agriculture and pastoralism led to the currently fragmented landscape with sparse deciduous forests (Quercus cerris). The study suggests that evergreen broadleaved species were more important at elevations above 1000 m a.s.l. before ca. 5000 cal a BP than subsequently, which might reflect less human impact or warmer‐than‐today climatic conditions between 10 000 and 5000 cal a BP. Despite land use since Neolithic times, deciduous supra‐mediterranean forests were never completely displaced from the Nebrodi Mountains, because of favourable moist conditions that persisted throughout the Holocene. Reconstructed vegetation dynamics document the absence of any pronounced mid‐ or late‐Holocene ‘aridification’ trend at the site, an issue which is controversially debated in Italy and the Mediterranean region. Copyright © 2012 John Wiley & Sons, Ltd.     

Reproductive resilience of ice‐dependent Antarctic silverfish in a rapidly changing system along the Western Antarctic Peninsula

The Western Antarctic Peninsula (wAP) is globally one of the systems most heavily impacted by climate change, notably steep declines in sea ice extent. In forage species, reproductive resilience to change is particularly important because population fluctuations are rapidly communicated through the system via trophic interactions. The reproductive traits of the ice‐dependent forage species Antarctic silverfish (Pleuragramma antarctica) from different areas along the wAP and at the tip of the Antarctic Peninsula were investigated through macroscopic and histological analyses of gonads, with the aim to assess its reproductive potential and to test for spatial differences in fecundity and spawning season. Fish samples were collected in late summer off Charcot Island, in Marguerite Bay and off Joinville Island; no fish were caught in the central wAP. Samples from Charcot Island and Marguerite Bay consisted of adults in developing gonad stage, whereas those from Joinville consisted almost exclusively of juveniles. Mean GSI was relatively low (2–3%) and similar in both sexes, as specimens were still far from being actively reproducing. Developing females exhibited two discrete, though partially overlapping modes of oocytes of different size, with vitellogenic oocytes measuring 0.5–1.0 mm. Absolute and relative fecundity ranged between 3000 and 12,000 eggs per female and between 80 and 190 eggs·g^?1, with a strong relationship between absolute fecundity and body size. These results were consistent with a single population at Charcot Island and Marguerite Bay and indicated substantial reproductive potential, which may mitigate population isolation and reductions in habitat availability but cannot ultimately offset catastrophic loss of spawning habitat linked to sea‐ice retreat.     

Diatom, Pollen, and Chemical Evidence of Postglacial Climatic Change at Big Lake, South-Central British Columbia, Canada

Postglacial climatic conditions were inferred from cores taken from Big Lake in southern British Columbia. Low concentrations of nonarboreal pollen and pigments near the base of the core suggest that initial conditions were cool. Increases in both aquatic and terrestrial production suggest warmer and moister conditions until 8500 cal yr B.P. Hyposaline diatom assemblages, increases in nonarboreal pollen, and increased concentrations of pigments suggest the onset of arid conditions from 8500 to 7500 cal yr B.P. Slightly less arid conditions are inferred from 7500 until 6660 cal yr B.P. based on the diatoms, small increases and greater variability in biogenic silica and pigments, and higher percentages of arboreal pollen. At 6600 cal yr B.P., changes in diatoms, pigments, biogenic silica, and organic matter suggest that Big Lake became fresh, deep, and eutrophic until 3600 cal yr B.P., when water levels and nutrients decreased slightly. Our paleoclimatic inferences are similar to pollen-based studies until 6600 cal yr B.P. However, unlike these studies, our multiple lines of evidence from Big Lake imply large changes in effective moisture since 6000 cal yr B.P.