Vertical column abundances of HCN deduced from ground-based infrared solar spectra: Long-term trend and variability

A set of high-resolution IR solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, from 84/06 to 93/06, and at the National Solar Observatory McMath-Pierce solar telescope facility on Kitt Peak, Arizona, U.S.A. from 78/05 to 92/07 have been analyzed to determine the vertical column abundances of hydrogen cyanide, HCN, above the two stations. The analysis was based on least-squares curve fitting of calculated spectra to the observations encompassing the P4 and the P8 lines of HCN respectively located at 3299.5273 and 3287.2483 cm^–1. The results obtained for the two stations indicate that no significant long-term trend affects either of the two databases; however, this analysis reveals variable increases during springtime of up to a factor of 2 in the HCN total column above the Jungfraujoch and even up to 3 above Kitt Peak. The calculated mean vertical column abundances, excluding the spring observations, are equal to (2.55±0.30)×10¹⁵ molec./cm² (S.D.) and (2.75±0.30)×10¹⁵ molec./cm² respectively above the Jungfraujoch and the Kitt Peak observatories. Based on a realistic volume mixing ratio profile, these columns translate into mean volume mixing ratios equal to 190×10^–12 ppv at the respective altitudes of the stations.     

Airborne radar and in-situ observations of a shallow stratus with drizzle

Observations were made of a shallow stratus of upslope origin using an aircraft equipped with insitu probes and with a vertically-pointing radar of 3-mm wavelength. A cloud layer of 300 m thickness was found below the inversion; an additional layer of 100 m thickness was located within the inversion. The coldest temperature within the cloud was -2°C and the cloud contained no ice particles. Drizzle drops up to 180 Am were present in both cloud layers.The observations reveal precipitation and air motion structures of approximately 1 km horizontal dimensions. The origin of this organization appears to be weak convection. In addition, mixing played an important role in forming the cloud droplet and drizzle drop size distributions.     

A new interpretation of terraces in the Taranto Gulf: the role of extensional faulting

The Taranto Gulf of southern Italy provides an excellent case where it is possible to document the importance of normal faults in displacing terraced deposits. The study area is located at the front of the southern Apennines, that is a fold-and-thrust belt developed following the closure of the Mesozoic Tethys Ocean, and the deformation of the Adriatic passive margin during Tertiary and Quaternary times. The outer, eastern parts of the belt were structured in Quaternary, i.e. up to Middle Pleistocene times.The front of the chain is partially sealed by Pliocene–Pleistocene foredeep deposits, which represent the infill of the Bradanic Trough. The upper portion of the middle Pleistocene succession consists of marine sands and conglomerates that in the previous literature have been arranged in several orders of terraces. Analysis of aerial photographs and geomorphological mapping has shown the occurrence of prominent geomorphic lineaments, which appear to control the local drainage pattern. Some of these structures coincide with the map trace of normal faults that produce vertical offsets of the marine terrace surfaces in the order of ca. 10 m each. Many of the fault escarpments reduce their elevation and terminate laterally. In other cases fault escarpments are laterally continuous and can be traced for up to 3–4 km. Scarp height is between 2 and 10 m. Their mean trend ranges from NNE–SSW to ENE–WSW and defines an arcuate pattern that mimics the present coastline.An accurate geomorphological, sedimentological and stratigraphic analysis has been carried out in a selected area of the Bradanic Trough (Pisticci transect) to investigate in detail the relationships between normal faults and the development of the terraces. This analysis allowed us to recognise five facies associations related to the upper and lower beachface and to the neritic clays which represent the substratum of the terraces. More importantly, we observed that all the terraced deposits in the Pisticci transect could be referred to a single sedimentary body displaced by faults. The terraced deposits are related to an event of beach progradation, of Middle Pleistocene age, which has been documented in other areas of the Italian peninsula. These results outline an intimate relationship between the arcuate trend of the recognised fault set and the present coastline pattern. The development of the normal faults can be related to large-scale gravitational processes developed after the general tilting towards the SE of the Bradanic Trough.     

Possibilities to detect trends in spectral UV irradiance

Summary It is investigated how long-term UV trends can be assessed by analysing the longest time series of measured spectral UV irradiance in Europe, which have been started in the early 1990s in Thessaloniki, Greece and Sodankylä, Finland. It can be concluded that both time series do not yet show an unambiguous yearly trend in UV irradiance. The regression lines show no uniform behaviour and vary irregularly in strength and from one solar zenith angle to the next if all sky conditions are analysed. It is emphasised that these findings do not disagree with previous studies, that significant changes in UV irradiance have been observed over Europe especially in spring.Our study introduces a new method to estimate the required time series length for trend detection using the measured time series in combination with model calculations. At Sodankylä, a reduction of the total ozone column of –5.7% per decade has been observed from 1979 to 1998. A positive UV trend due to such conditions may be detected after 12 years at the earliest. For Thessalonki, a decrease in total ozone of –4.5% per decade has been observed. A corresponding increase of UV irradiance should be detectable after 15 years. It should be noted that a constant ozone trend over the whole period had to be assumed for this analysis.Since 1990 there has been a considerable variability of total ozone, but no steady decrease could be observed. Consequently, no general UV increase could be expected due to ozone changes. Even if there was a constant ozone trend over that period it is shown that even the longest European time series of UV irradiance are still too short to show distinct trends. However, this does not imply that no changes have occurred, it only shows that the large natural variability of UV irradiance has so far hindered the identification of unambiguous trends. The only way to find significant and consistent UV trends is the continuation of high-quality long-term measurements of spectral UV irradiance.