The effects of climate and landscape position on chemical denudation and mineral transformation in the Santa Catalina mountain critical zone observatory

Understanding the interactions of climate, physical erosion, chemical weathering and pedogenic processes is essential when considering the evolution of critical zone systems. Interactions among these components are particularly important to predicting how semiarid landscapes will respond to forecasted changes in precipitation and temperature under future climate change. The primary goal of this study was to understand how climate and landscape structure interact to control chemical denudation and mineral transformation across a range of semiarid ecosystems in southern Arizona. The research was conducted along the steep environmental gradient encompassed by the Santa Catalina Mountains Critical Zone Observatory (SCM-CZO). The gradient is dominated by granitic parent materials and spans significant range in both mean annual temperature (>10 °C) and precipitation (>50 cm a^?1), with concomitant shift in vegetation communities from desert scrub to mixed conifer forest. Regolith profiles were sampled from divergent and convergent landscape positions in five different ecosystems to quantify how climate-landscape position interactions control regolith development. Regolith development was quantified as depth to paralithic contact and degree of chemical weathering and mineral transformation using a combination of quantitative and semi-quantitative X-ray diffraction (XRD) analyses of bulk soils and specific particle size classes. Depth to paralithic contact was found to increase systematically with elevation for divergent positions at approximately 28 cm per 1000 m elevation, but varied inconsistently for convergent positions. The relative differences in depth between convergent and divergent landscape positions was greatest at the low and high elevation sites and is hypothesized to be a product of changes in physical erosion rates across the gradient. Quartz/Plagioclase (Q/P) ratios were used as a general proxy for bulk regolith chemical denudation. Q/P was generally higher in divergent landscape positions compared to the adjacent convergent hollows. Convergent landscape positions appear to be collecting solute-rich soil–waters from divergent positions thereby inhibiting chemical denudation. Clay mineral assemblage of the low elevation sites was dominated by smectite and partially dehydrated halloysite whereas vermiculite and kaolinite were predominant in the high elevation sites. The increased depth to paralithic contact, chemical denudation and mineral transformation are likely functions of greater water availability and increased primary productivity. Landscape position within a given ecosystem exerts strong control on chemical denudation as a result of the redistribution of water and solutes across the landscape surface. The combined data from this research demonstrates a strong interactive control of climate, landscape position and erosion on the development of soil and regolith.     

Faecal indicator bacteria in New Zealand freshwater fish: a pilot study

Recent studies have suggested that poikilothermic animals, such as fish, may represent a previously overlooked source of the faecal indicator bacteria (FIB) used for the assessment of water quality. However, quantitative studies of FIB in poikilotherms are scarce. We investigated the presence of FIB in the faeces of five freshwater fish species. E. coli and enterococci were detected in 71 and 76% of faecal samples, respectively. Concentrations were highly variable, with maximum concentrations (2.1?×?10⁴ E. coli and 1.3?×?10⁶ enterococci per gram of faecal material) up to four orders of magnitude higher than present in the water column. FIB were not detected in faecal samples from marine fish. Our findings suggest that FIB ingested from the environment may be capable of replication within the fish gut, making fish a potential source and transport mechanism for FIB in New Zealand freshwaters. This may have implications for water quality monitoring.     

Long-Term Observations of Isotope Ratio Accuracy and Reproducibility Using Quadrupole ICP-MS

High precision isotope ratio and trace element determination can be achieved with modern quadrupole ICP-MS provided that short and long-term instrument performance is accurately monitored. Here we present results for the isotope ratios ⁶Li/⁷Li, ¹⁴⁷Sm/¹⁴⁹Sm, ¹⁶⁰Dy/¹⁶¹Dy, ²⁰⁷Pb/²⁰⁶Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁶Pb/²⁰⁴Pb and ²³⁵U/²³⁸U with which we determined long-term isotope ratio stability of relevance to both trace element and isotope determination. With respect to trace element determination, we first present long-term observations regarding oxide formation rates of Ba and Nd on light REE and heavy REE, as well as Zr on Ag. These showed good correlations and could be used to correct effectively the interference. The efficacy of this correction was demonstrated with analyses of the rock reference material BHVO-2 at both low and high oxide formation rates. Next, we studied the long-term reproducibility of a Dy isotope ratio that was measured to correct for the isobaric interference on Gd. It was found that, regardless of tuning condition, the ratio reproduced very well (0.58% RSD, 1s) and that the estimate of the Gd concentration did not suffer from the large correction (> 10%) caused by the Dy isobar. Long-term reproducibilities of Li, Sm and U isotope ratios, required for accurate mass bias correction when isotopically enriched internal standards of these elements are employed, were measured in the rock reference materials AGV-2 and JA-3 over a time period of up to 3 years. As expected, the Li isotope ratio showed the largest variability (RSD = 7%), but the other two ratios had relative external reproducibilities of only 1.01% (1s, U) and 0.67% (Sm). The mass bias-induced scatter in measurements for Sm and U was so small that the internal standard correction was effective, even for samples with high concentrations of these elements. With regard to Pb-isotope ratio determination, we also present long-term reproducibility for NIST SRM 982, run as an unknown and two accuracy tests for Pb separated from granitoids and from meteorites. It is demonstrated that the obtained ratios, including those involving ²⁰⁴Pb, are accurate relative to MC-ICP-MS determinations and of comparable precision to conventional TIMS analysis. The excellent agreement between all data sets shows the potential of modern quadrupole ICP-MS instrumentation for Pb-isotope determination, particularly for samples with very low Pb content.     

Stacking for the frequencies and Qs of 0S0 and 1S0

Summary. Using nine IDA records for the Indonesian earthquake of 1977 August 19, we have formed an optimal linear combination of the records and have measured the frequency and Q of ₀ S ₀ and ₁ S ₀. The frequency was measured using the moment ratio method. The attenuation was measured by the minimum width method and by the time-lapse method. The frequency and attenuation were measured simultaneously by varying them to obtain a best fit to the data. A 2000-hr stack, the sum of nine individual records, for ₀ S ₀ gave a frequency of 0.814664 mHz±4 ppm. The values for the Q of ₀ S ₀ for the three different methods of measurement were 5600,5833 and 5700, respectively. The error in the estimates of Q ^-1 is about 5 per cent for the minimum power method. For ₁ S ₀ a 300-hr stack yielded a frequency of 1.63151 mHz±30 ppm. The values of Q for this mode were 1960, 1800 and 1850, respectively, with an error in Q ^-1 of about 12 per cent for the minimum power method.     

Cloud Forest Conservation in the Central Highlands of Guatemala Hinges on Soil Conservation and Intensifying Food Production

Soil erosion threatens long-term soil fertility and food production in Q’eqchi’ communities native to the Sierra Yalijux and Sierra Sacranix mountain ranges in the central highlands of Guatemala. Environmental factors such as steep topography, erodible soils, and intense precipitation events, combined with land subdivision and reduced fallow periods as a consequence of population growth, contribute to severe erosion and strain soil resources. The preservation of the region's cloud forests hinges on enhancing production of staple crops through agricultural intensification while maintaining soil fertility through implementation of soil conservation measures.     

Holocene history of lacustrine and marsh sediments in a dune-blocked drainage, Southwestern Nebraska Sand Hills, U.S.A.

As many as 2500 interdune lakes lie within the Nebraska Sand Hills, a 50000 km stabilized sand sea. The few published data on cores from these lakes indicate they are typically underlain by less than two m of Holocene lacustrine sediments. However, three lakes in the southwestern Sand Hills, Swan, Blue, and Crescent, contain anomalously thick marsh (peat) and lacustrine (gyttja) sediments. Swan Lake basin contains as much as 8 m of peat, which was deposited between about 9000 and 3300 years ago. This peat is conformably overlain by as much as 10.5 m of gyttja. The sediment record in Blue lake, which is 3 km downgradient from Swan lake, dates back to only about 6000 years ago. Less than two m of peat, which was deposited from 6000 to 5000 years ago, is overlain by 12 m of gyttja deposited in the last 4300 years. Crescent Lake basin, one km downgradient from Blue Lake, has a similar sediment history except for a lack of known peat deposits. Recently, a 8-km long segment of a paleovalley was documented running beneath the three lakes and connecting to the head of Blue Creek Valley. Blockage of this paleovalley by dune sand during two arid intervals, one shortly before 10500 yr BP and one in the mid-Holocene, has resulted in a 25 m rise in the regional water table. This made possible the deposition of organic-rich sediment in all three lakes. Although these lakes, especially Swan, would seem ideal places to look for a nearly complete record of Holocene climatic fluctuations, the paleoclimatic record is confounded by the effect dune dams have on the water table. In Swan Lake, the abrupt conversion from marsh to lacustrine deposition 3300 years ago does not simply record the change to a wetter regional climate; it reflects the complex local hydrologic changes surrounding the emplacement and sealing of dune dams, as well as regional climate.     

Results from a Multi-disciplinary Sedimentary Pilot Study of Tectonic Lake Iznik (NW Turkey) – Geochemistry and Paleolimnology of the Recent Past

A limnogeological reconnaissance study was carried out on Lake Iznik, located in the southeast of the Marmara region of Turkey, involving a seismic survey and collection of short sediment cores. This lake is located on the middle branch of the North Anatolian Fault Zone (NAFZ), a transform plate boundary between the Eurasian and Anatolian Plates. It is, therefore, tectonically active and offers an opportunity to investigate the interplay of sedimentary and seismo-tectonic processes, as well as climate change and human impact in the region. Short cores of the three sub-basins, maximum length of 35.5 cm, recovered non-laminated, blackish clays and silts with varying amounts of biogenic and minerogenic (allochthonous, autochthonous) material, which documented almost the last 80 years of deposition and environmental history. High sedimentation rates in the deeper core sections are accompanied by changes in land use (conversion of woodland to farmland) in the northern areas of Lake Iznik, which caused the deposition of more weathered material (high K/Na ratios) and higher contents of Mn in the lake. A tendency towards eutrophic conditions within the last 20 years is indicated by high nutrient content (N, TOC, P), decreasing C/N-ratios, and characteristic diatom and cladoceran associations. Also increased pollution is revealed by higher Pb, Cu, and Zn contents and increased supply of human and animal faeces (high coprostanol content) during the last two decades. But simultaneous lower sedimentation rates towards the core tops complicate the reconstruction of recent and past eutrophication and pollution states of Lake Iznik. This requires an extension of the pilot study and deeper sediment cores, to recover non-anthropogenic influenced sediment levels.     

Accumulation in Svalbard glaciers deduced from ice cores with nuclear tests and Chernobyl reference layers

Mean net annual balance and the related spatio-temporal variations have been determined on the basis of well-dated artificial layers in shallow ice cores (Chernobyl, 1986, and atmospheric thermonuclear tests, mainly in 1961-62 in Novaya Zemlya). Seventy ice cores from 13 Svalbard glaciers have been analysed. On each glacier, in its accumulation area and at the highest elevation, one ice core was recovered down to about 40 m and sampled for radioactivity measurements to determine the 1986 and 1962-63 layer (1954 was the initial date of the nuclear tests). For each glacier, at least five complementary ice cores from the accumulation area were analysed to determine the Chernobyl reference layer. Six ice cores exhibit both the Chernobyl and nuclear tests layers and are of special interest in this study.
This work provides new data on the deposition rates of natural and artificial radioisotopes. Using ice cores samples from the Arctic glaciers, even with superimposed ice accumulation, it is possible to distinguish between the Chernobyl and the nuclear tests fallouts. This work also shows that the mean annual net balance did not significantly change for at least five ice core locations in the Svalbard glaciers for the two periods extending from 1963 to 1986 to the recent date of drilling.     

Mineral-scale Sr-isotope constraints on magma evolution and chamber dynamics in the Rum layered intrusion,Scotland

Sr isotopic zoning within single plagioclase crystals from rocks from Unit 9 of the Rum layered intrusion is used to infer events during crystal growth in a magma undergoing contamination. The ⁸⁷Sr/⁸⁶Sr diversity among minerals and between cores and rims of plagioclase crystals increases as the boundary between unit 9 and the overlying Unit 10 peridotite is approached. Models of near-solidus interaction of the cumulate with a fluid or melt, or large scale textural re-equilibration, cannot easily account for the systematic differences in ⁸⁷Sr/⁸⁶Sr between small crystals and the rims of larger crystals.We propose a simple interpretation in which crystal growth is concentrated along the cool margins of the reservoir. Crystals are subsequently advected to a site of accumulation at the base of the reservoir, probably by episodic plume-like dense downwellings allowing mixing of isotopically zoned and unzoned crystals.If the core-rim isotope variations are inherited from primary magmatic growth, then the small distances over which they are now preserved (1–2 mm) place constraints on the minimum cooling rate of the intrusion. Although the length scale of diffusive equilibration is influenced by a number of poorly-constrained variables (starting temperature, feldspar composition, temperature-time path) cooling was clearly very rapid with cooling to effective closure (~1,000 °C) within a few thousand years.Editorial responsibility: I. Parsons     

Borehole diffusive flux apparatus for characterizing diffusive mass-transfer in subsurface systems

The concept of the Borehole Diffusive Flux Apparatus (BDFA) is presented herein. The BDFA is an innovative apparatus designed to provide continuous direct access to an undisturbed column of sediment that can be monitored at multiple discrete vertical intervals to provide high-resolution characterization of local-scale mass transfer and attenuation. The conceptual basis and technical design of the device are presented, along with an example of borehole design and installation at a field site. Mathematical simulations are used to illustrate its application for two scenarios. The results of these simulations indicate that test periods of several weeks to a few months should be sufficient to obtain robust results. The device has the potential to improve our ability to characterize critical mass-transfer and attenuation processes and to quantify the associated rates. This information is key to the evaluation of remediation alternatives, for enhancing the accuracy of mathematical models, and to support more effective long-term management of large groundwater contaminant plumes present at many sites.