Small angle neutron scattering by opals

Micro- and non-crystalline opals, chalcedony and flint show diffuse small angle neutron scattering (SANS). Precious opals give rise to two additional intensity maxima at very small scattering angles which are due to Bragg reflections from the closest packed non-crystalline silica spheres. A small angle texture diagram reveals that the closest packing is faulty. Synthetic non-crystalline opals yield much less intense small angle scattering due to lower contrast between silica spheres and interstitial cement or particles; in this case intensity maxima were not observed. The outer part of the scattering curves of opal-CT and microcrystalline quartz deviates from Porod's law. The specific surface of natural non-crystalline opals ranges from 0.006 to 0.018 nm^–1. In microcrystalline opals, the specific surface is about 10 times larger than in non-crystalline opals.     

A chum scale pattern analyzer and stock identification based onscale patterns by discriminant function and power spectrum analysis

An optoelectronic instrument has been developed to analyze the scales and scale patterns of chum salmon. This device, with specially developed software, has been used to study populations of salmon. Fish from two different rivers approximately 200 km apart from each other were grouped with an accuracy of 82% or more. Machine-measured ages coincided with those derived from visual estimation in approximately 80% of the fish sampled. These results suggest the proposed system could be of practical use for measuring and analyzing the scale patterns that allow one to accurately measure both natural and farmed populations of salmon     

Comparison of results from several AOGCMs for global and regional sea-level change 1900–2100

 Sea-level rise is an important aspect of climate change because of its impact on society and ecosystems. Here we present an intercomparison of results from ten coupled atmosphere-ocean general circulation models (AOGCMs) for sea-level changes simulated for the twentieth century and projected to occur during the twenty first century in experiments following scenario IS92a for greenhouse gases and sulphate aerosols. The model results suggest that the rate of sea-level rise due to thermal expansion of sea water has increased during the twentieth century, but the small set of tide gauges with long records might not be adequate to detect this acceleration. The rate of sea-level rise due to thermal expansion continues to increase throughout the twenty first century, and the projected total is consequently larger than in the twentieth century; for 1990–2090 it amounts to 0.20–0.37 m. This wide range results from systematic uncertainty in modelling of climate change and of heat uptake by the ocean. The AOGCMs agree that sea-level rise is expected to be geographically non-uniform, with some regions experiencing as much as twice the global average, and others practically zero, but they do not agree about the geographical pattern. The lack of agreement indicates that we cannot currently have confidence in projections of local sea-level changes, and reveals a need for detailed analysis and intercomparison in order to understand and reduce the disagreements. Received: 1 September 2000 / Accepted: 20 April 2001     

Observational Selection of Comet Discoveries

The distribution of perihelion distances of nearly periodic comets was studied using different assumptions about comet discovery probabilities. It was shown that the concentration of perihelia at small heliocentric distances cannot be explained solely by the influence of visibility conditions.     

The influence of a non‐associated flow rule on the calculation of the factor of safety of soil slopes

This paper presents a method that incorporates a non‐associated flow rule into the limit analysis to investigate the influence of the dilatancy angle on the factor of safety for the slope stability analysis. The proposed method retain's the advantage of the upper bound method, which is simple and has no stress involvement in the calculation of the energy dissipation and the factor of safety. Copyright © 2001 John Wiley & Sons, Ltd.     

Why Mt Etna?

The Etna volcano is located in an apparently anomalous position on the hinge zone of the Apennines subduction and its Na-alkaline geochemistry does not favour a magma source from the deep slab as indicated for the Aeolian K-alkaline magmatism. The steeper dip of the regional foreland monocline at the front of the Apennines in the Ionian Sea than in Sicily, implies a larger rollback of the subduction hinge in the Ionian Sea. Moreover, the lengthening of the Apennines arc needs extension parallel to the arc. Therefore, the larger southeastward subduction rollback of the Ionian lithosphere with respect to the Hyblean plateau in Sicily, should kinematically produce right-lateral transtension and a sort of vertical 'slab window' which might explain (i) the Plio-Pleistocene alkaline magmatism of eastern Sicily (e.g. the Etna volcano) and (ii) the late Pliocene to present right lateral transtensional tectonics and seismicity of eastern Sicily. The area of transfer of different dip and rollback occurs along the inherited Mesozoic passive continental margin between Sicily and the oceanic Ionian Sea, i.e. the Malta escarpment.     

Grain boundary diffusion in enstatite

We have investigated grain boundary diffusion rates in enstatite by heating single crystals of quartz packed in powdered San Carlos olivine (Mg_0.90Fe_0.10)₂SiO₄ at controlled oxygen fugacities in the range 10^?5.7 to 10^?8.7?atm and temperatures from 1350° to 1450?°C for times from 5 to 100?h at 1?atm total pressure. Following the experiments, the thickness of the coherent polycrystalline reaction rim of pyroxene that had formed between the quartz and olivine was measured using backscatter scanning imaging in the electron microprobe. Quantitative microprobe analysis indicated that the composition of this reaction phase is (Mg_0.92Fe_0.08)₂Si₂O₆. The rate of growth of the pyroxene increases with increasing temperature, is independent of the oxygen fugacity, and is consistent with a parabolic rate law, indicating that the growth rate is controlled by ionic diffusion through the pyroxene rim. Microstructural observations and platinum marker experiments suggest that the reaction phase is formed at the olivine-pyroxene interface, and is therefore controlled by the diffusion of silicon and oxygen. The parabolic rate constants determined from the experiments were analyzed in terms of the oxide activity gradient across the rim to yield mean effective diffusivities for the rate-limiting ionic species, assuming bulk transport through the pyroxene layer. These effective diffusivities are faster than the lattice diffusivities for the slowest species (silicon) calculated from creep experiments, but slower than measured lattice diffusivities for oxygen in enstatite. Thus, silicon grain boundary diffusion is most likely to be the rate-limiting process in the growth of the pyroxene rims. Also, as oxygen transport through the pyroxene rims must be faster than silicon transport, diffusion of oxygen along the grain boundaries must be faster than through the lattice. The grain boundary diffusivity for silicon in orthopyroxenite is then given by D¯gbSiδ=(3.3±3.0)×10^?9f0.0O₂e^?400±65/RT?m³s^?1, where the activation energy for diffusion is in kJ/mol, and δ is the grain boundary width in m. Calculated growth rates for enstatite under these conditions are significantly slower than predicted by an extrapolation from similar experiments performed at 1000?°C under high pressure (hydrous) conditions by Yund and Tullis (1992), perhaps due to water-enhancement of diffusion in their experiments.     

Solid bitumens: an assessment of their characteristics, genesis, and role in geological processes

Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ¹³C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in ¹³C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and ¹³C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits.