Paleoclimate reconstruction using carbonate clumped isotope thermometry

Carbonate clumped isotope thermometry is a relatively new paleotemperature proxy based on measurements of the degree of ordering of ¹³C and ¹⁸O into bonds with each other (making the ¹³C¹⁸O¹⁶O₂^?2 ion group) in lattices of carbonate minerals. This technique has several unusual properties that complement existing methods of paleoclimate reconstruction. Most importantly, it is based on a homogeneous isotope exchange equilibrium and thus constrains temperature independent of the isotopic composition of waters from which carbonates grew. This method also appears to be generally insensitive to ‘vital effects’ that compromise many other paleothermometers based on the chemical properties of biominerals or organic matter, at least for those organisms that have been subjected to systematic study to-date (corals and foraminifera); however, discrepancies among some calibrations, particularly at low temperatures, may point toward the existence of vital effects in mollusks and other organisms. This review discusses the principles and calibrations of the technique, its uses in combination with conventional stable isotope measurements to constrain the δ¹⁸O of past waters, preservation of paleotemperatures in ancient materials, as well as current problems in our understanding of calibrations and interlaboratory data comparisons.     

Analytical solutions for advective–dispersive solute transport in double‐layered finite porous media

Analytical solutions for advection and dispersion of a conservative solute in a one‐dimensional double‐layered finite porous media are presented. The solutions are applicable to five scenarios that have various combinations of fixed concentration, fixed flux and zero concentration gradient conditions at the inlet and outlet boundaries that provide a wide number of options. Arbitrary initial solute concentration distributions throughout the media can be considered via explicit formulations or numerical integration. The analytical solutions presented have been verified against numerical solutions from a finite‐element‐based approach and an existing closed‐form solution for double‐layered media with an excellent correlation being found in both cases. A practical application pertaining to advective transport induced by consolidation of underlying sediment layers on contaminant movement within a capped contaminated sediment system is presented. Comparison of the calculated concentrations and fluxes with alternative approaches clearly illustrates the need to consider advection processes. Consideration of the different features of contaminant transport due to varying pore‐water velocity fields in primary consolidation and secondary consolidation stages is achieved via the use of non‐uniform initial concentration distributions within the proposed analytical solutions. Copyright © 2010 John Wiley & Sons, Ltd.     

Application of topo-edaphic factors and remotely sensed vegetation indices to enhance biomass estimation in a heterogeneous landscape in the Eastern Arc Mountains of Tanzania

Estimating tropical biomass is critical for establishment of conservation inventories and landscape monitoring. However, monitoring biomass in a complex and dynamic environment using traditional methods is challenging. Recently, biomass estimates based on remotely sensed data and ecological variables have shown great potential. The present study explored the utility of remotely sensed data and topo-edaphic factors to improve biomass estimation in the Eastern Arc Mountains of Tanzania. Twenty-nine vegetation indices were calculated from RapidEye data, while topo-edaphic factors were taken from field measurements. Results showed that using topo-edaphic variables or vegetation indices, biomass could be predicted with an R² of 0.4. A combination of topo-edaphic variables and vegetation indices improved the prediction accuracy to an R² of 0.6. Results further showed a decrease in biomass estimates from 1162 ton ha^?1 in 1980 to 285.38 ton ha^?1 in 2012. This study demonstrates the value of combining remotely sensed data with topo-edaphic variables in biomass estimation.     

Engineering geomorphological characterisation of the Vajont Slide,Italy, and a new interpretation of the chronology and evolution of the landslide

Although the 1963 Vajont Slide in Italy has been extensively studied for over 50 years, its regional geological and geomorphological context has been neglected. In this paper, we use field observations and remote sensing data to elucidate the interaction between endogenic and exogenic processes that brought the north slope of Monte Toc to failure. We present the first detailed pre- and post-failure engineering geomorphology maps of the slide area. The maps delineate two main landslide blocks, several sub-blocks, compressional and extensional zones, and secondary failures in the deposit. The maps provide new insights into the kinematics, dynamics and evolution of the slide. Finally, we discuss the origin of Vajont Gorge and a prehistoric failure that occurred at the same location as the 1963 slide. We propose, as part of a newly developed multi-stage landscape evolution sequence, that the prehistoric failure was a deep-seated gravitational slope deformation (sackung) that initiated during deglaciation and continued to slowly move until the catastrophic failure in 1963. We argue that the gorge was created by these deep-seated slow movements.     

Hydrogeology of a montane headwater groundwater system downgradient of a coal-mine waste rock dump: Elk Valley,British Columbia,Canada

Steelmaking-coal waste rock placed in mountain catchments in the Elk Valley, British Columbia, Canada, drain constituents of interest (CIs) to surface water downgradient of the waste rock dumps. The role of groundwater in transporting CIs in the headwaters of mountain catchments is not well understood. This study characterizes the physical hydrogeology of a portion of a 10-km² headwater catchment (West Line Creek) downgradient of a 2.7-km² waste rock dump placed over a natural headwater valley-bottom groundwater system. The study site was instrumented with 13 monitoring wells. Drill core samples were collected to determine subsurface lithology and geotechnical properties. The groundwater system was characterized using field testing and water-level monitoring. The valley-bottom sediments were composed of unconsolidated glacial and meltwater successions (<64 m thick) deposited as a series of cut and fill structures overlying shale bedrock. An unconfined basal alluvial aquifer located above fractured bedrock was identified as the primary conduit for groundwater flow toward Line Creek (650 m from the toe of the dump). Discharge through the basal alluvial aquifer was estimated using the geometric mean hydraulic conductivity (±1 standard deviation). These calculations suggest groundwater discharge could account for approximately 15% (ranging from 2 to 60%) of the total water discharged from the watershed. The residence time from the base of the waste rock dump to Line Creek was estimated at <3 years. The groundwater system was defined as a snowmelt (i.e., nival) regime dominated by direct recharge (percolation of precipitation) across the catchment.     

Evaluating Tidal Wetland Restoration Performance Using National Estuarine Research Reserve System Reference Sites and the Restoration Performance Index (RPI)

Evaluations of tidal wetland restoration efforts suffer from a lack of appropriate reference sites and standardized methods among projects. To help address these issues, the National Estuarine Research Reserve System (NERRS) and the NOAA Restoration Center engaged in a partnership to monitor ecological responses and evaluate 17 tidal wetland restoration projects associated with five reserves. The goals of this study were to (1) determine the level of restoration achieved at each project using the restoration performance index (RPI), which compares change in parameters over time between reference and restoration sites, (2) compare hydrologic and excavation restoration projects using the RPI, (3) identify key indicator parameters for assessing restoration effectiveness, and (4) evaluate the value of the NERRS as reference sites for local restoration projects. We found that the RPI, modified for this study, was an effective tool for evaluating relative differences in restoration performance; most projects achieved an intermediate level of restoration from 2008 to 2010, and two sites became very similar to their paired reference sites, indicating that the restoration efforts were highly effective. There were no differences in RPI scores between hydrologic and excavation restoration project types. Two abiotic parameters (marsh platform elevation and groundwater level) were significantly correlated with vegetation community structure and thus can potentially influence restoration performance. Our results highlight the value of the NERRS as reference sites for assessing tidal wetland restoration projects and provide improved guidance for scientists and restoration practitioners by highlighting the RPI as a trajectory analysis tool and identifying key monitoring parameters.