High-resolution historical records from Pettaquamscutt River basin sediments: 1. Pb and varve chronologies validate record of Cs released by the Chernobyl accident

Cesium-137 derived from the explosion of the Chernobyl reactor in 1986 was preserved in anoxic sediments from a coastal environment in southern Rhode Island. Although the radioactive plume was detected in surface air samples at several locations in the United States, this is the first known record of a Chernobyl ¹³⁷Cs peak in sediments from North America. The inventory of Chernobyl ¹³⁷Cs that was preserved in the Pettaquamscutt River is small compared to European counterparts and should only be detectable for the next 15-20 yr. However, the presence of two ¹³⁷Cs peaks (1963 and 1987) identifies a well-dated segment of the sediment column that could be exploited in understanding the decomposition and preservation of terrestrial and aquatic organic matter. Different methods for calculating the ²¹⁰Pb chronology were also evaluated in this study and checked against independent varve counting. The end result is a detailed chronology of a site well suited for reconstruction of historical records of environmental change.     

The American whale oil industry: A look back to the future of the American petroleum industry?

The American whaling industry rose from humble beginnings off Long island to become an international giant. In its peak year, 1846, 735 ships and 70,000 people served the industry. As whale stocks and reserves decreased, whalers were forced to go farther and farther from their New England home ports. Voyages became longer, and risks on required return-on-investment became higher. The easy money of Atlantic and Pacific whaling was no more: the only remaining profitable ventures were to Arctic and Antarctic waters. Many ships returned empty, if at all. in 1871, most of the Arctic whaling fleet was crushed by early winter ice and lost. This calamity, in conjunction with the long-term diminishing whale stocks, the diversion of investment capital to more profitable ventures, and the discovery, development, and refinement of abundant petroleum crude oil, struck the death blow to the American whaling industry. By 1890, only 200 whaling vessels were at work, and by 1971, no American commercial whaling ship sailed the world's oceans.It is apparent that no single event caused the final, rapid decline. However, a single calamity, in an already stressed industry, that was self-insured and commercially interlinked, precipitated the end. Today's American petroleum industry, although adopting some principles of the American whaling industry, also has embraced other activities such as work process reengineering and customer alliances, which may preempt, or postpone, a similar catastrophic demise.     

Electronic structures of sulfide minerals — Theory and experiment

The sulfide minerals exhibit a rich diversity in sturctural chemistry and in electrical, magnetic and other physical properties. Models based on molecular orbital theory and incorporating some elements of band theory can be developed to describe the diverse valence electron behavior in these minerals. Qualitative models can be proposed on the basis of observed properties, and the models can be tested and refined using experimental data from X-ray emission and X-ray photoelectron spectroscopy and quantum mechanical calculations performed on cluster units which form the basic building blocks of the crystals. This approach to chemical bonding in sulfide minerals is illustrated for binary non-transition metal sulfides (ZnS, CdS, HgS, PbS), binary transition metal sulfides (FeS₂, CoS₂, NiS₂, CuS₂ ZnS₂) and more complex sulfides (CuFeS₂, Cu₂S, Ag₂S, CuS, Co₃S₄, CuCo₂S₄, Fe₃S₄). The relationship between qualitative and quantitative theories is reviewed with reference to the pyrite-marcasite-arsenopyrite-loellingite series of minerals. Application of the models to understanding structure-determining principles, relative stabilities, solid solution limits and properties such as color, reflectance and hardness are discussed.     

Petrography and geochemistry of clastic sedimentary rocks as evidences for provenance of the Lower Cambrian Lalun Formation, Posht-e-badam block, Central Iran

Petrography and geochemistry (major, trace and rare earth elements) of clastic rocks from the Lower Cambrian Lalun Formation, in the Posht-e-badam block, Central Iran, have been investigated to understand their provenance. Petrographical analysis suggests that the Lalun conglomerates are dominantly with chert clasts derived from a proximal source, probably chert bearing Precambrian Formations. Similarly, purple sandstones are classified as litharenite (chertarenite) and white sandstones as quartzarenite types. The detrital modes of purple and white sandstones indicate that they were derived from recycled orogen (uplifted shoulders of rift) and stable cratonic source. Most major and trace element contents of purple sandstones are generally similar to upper continental crust (UCC) values. However, white sandstones are depleted in major and trace elements (except SiO₂, Zr and Co) relative to UCC, which is mainly due to the presence of quartz and absence of other Al-bearing minerals. Shale samples have considerably lower content in most of the major and trace elements concentration than purple sandstones, which is possibly due to intense weathering and recycling. Modal composition (e.g., quartz, feldspar, lithic fragments) and geochemical indices (Th/Sc, La/Sc, Co/Th, Cr/Th, Cr/V and V/Ni ratios) of sandstones, and shales (La/Sc and La/Cr ratios) indicate that they were derived from felsic source rocks and deposited in a passive continental margin. The chondrite-normalized rare earth element (REE) patterns of the studied samples are characterized by LREE enrichment, negative Eu anomaly and flat HREE similar to an old upper continental crust composed chiefly of felsic components in the source area. The study of paleoweathering conditions based on modal composition, chemical index of alteration (CIA), plagioclase index of alteration (PIA) and A–CN–K (Al₂O₃ − CaO + Na₂O − K₂O) relationships indicate that probably chemical weathering in the source area and recycling processes have been more important in shale and white sandstones relative to purple sandstones. The results of this study suggest that the main source for the Lalun Formation was likely located in uplifted shoulders of a rifted basin (probably a pull-apart basin) in its post-rift stage (Pan-African basement of the Posht-e-badam block).     

A study of the depth of weathering and its relationship to the mechanical properties of near-surface rocks in the Mojave Desert

Weathered granite extends 70 m deep at Hi Vista in the arid central Mojave Desert of southern California. The low strength of this granite is due to the alteration of biotite and chlorite montmorillonite. Deep weathering probably occurs in most granites, although we cannot rule out some anomalous mechanisms at Hi Vista. Geophysical instruments set in these slightly altered rocks are limited by the unstable behavior of the rocks. Thus, tectonic signals from instruments placed in shallow boreholes give vague results. Geophysical measurements of these weathered rocks resemble measurements of granitic rocks near major faults. The rheology of the rocks in which instruments are placed limits the useful sensitivity of the instruments.     

Evolution of cold shock-bounded slabs

The stability and evolution of cold, shock-bounded slabs is studied using numerical hydrodynamic simulations. We confirm the analysis of Vishniac (1994) [ApJ, 428, 186], who showed that such slabs are unstable if they are perturbed by a displacement larger than their width. The growth rate of this nonlinear thin shell instability (NTSI) is found to increase with decreasing wavelength, in qualitative agreement with Vishniac's analysis. The NTSI saturates when the bending angle becomes large and the growth in the width of the slab pinches off the perturbation. After saturation, the slab remains greatly extended with an average density much less than the original slab density, supported primarily by supersonic turbulence within the slab. Linear perturbations are also found to be unstable in that they can lead to turbulent flow within the slab, although this response to linear perturbations is distinct from, and much less violent than the NTSI.Richard McCray     

A system for line profile studies at the 150-foot tower on Mount Wilson

We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s^–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington.     

Newtonian cosmology with a varying gravitational constant

Newtonian cosmology is developed with the assumption that the gravitational constantG diminishes with time. The functional form adopted forG(t), a modification of a suggestion of Dirac, isG=A(k+t) ^–1, wheret is the age of the Universe and a small constantk is inserted to avoid a singularity in the two-body problem. IfR is the scale factor, normalized to unity at an epoch time , the differential equation is then . Here ₀ is the mean density at the epoch time. With the above form forG(t), the solution is reducible to quadratures.The scale factorR either increases indefinitely or has one and only one maximum. LetH ₀ be the present value of Hubble's constant /R and _0c the minimum density for a maximum ofR, i.e., for closure of the Universe. The conditions for a maximum lead to a boundary curve of _0c versusH ₀ and the numbers indicate strongly that thisG-variable Newtonian model corresponds to an open universe. An upward estimate of the age of the Universe from 10¹⁰ yr to five times such a value would still lead to the same conclusion.The present Newtonian cosmology appears to refute the statement, sometimes made, that the Dirac model forG necessarily leads to the conclusion that the age of the Universe is one-third the Hubble time. Appendix B treats this point, explaining that this incorrect conclusion arises from using all the assumptions in Dirac (1938). The present paper uses only Dirac's final result, viz,G(k+t)^–1, superposing it on the differential equation .