SHRIMP zircon dating and Nd isotopic systematics of Palaeoproterozoic migmatitic orthogneisses in the Epupa Metamorphic Complex of northwestern Namibia

The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to peraluminous, calc-alkaline granitoids, predominantly with volcanic arc geochemical signatures. The zircon protolith ages for the orthogneisses range from 1861 ± 3 to 1758 ± 3 Ma. Anatexis in the migmatitic Epupa gneisses was dated from a melt patch at 1762 ± 4 Ma, and the anatectic Otjitanda Granite has a zircon age of 1757 ± 4 Ma. Migmatization and anatexis therefore occurred almost immediately after granitoid emplacement and date a widespread high-temperature Palaeoproterozoic event at ∼1760 Ma which has not been recorded elswhere in northern Namibia. The Nd isotopic systematics of all dated samples are surprisingly similar and suggest formation of the protolith from a source region that probably separated from the depleted mantle about 2.4–2.0 Ga ago. A major Archaean component in the source area is unlikely.     

Stable carbon isotope variations in northwest Europe during the last glacial–interglacial transition

Stable carbon isotope data that span part of the last glacial–interglacial transition (ca. 14-9 ka ¹⁴C BP; ca. 15–11 ka cal. BP), and which derive from organ-specific plant macrofossils recovered from two lake sediment profiles in the UK and one in Norway, are compared. The recorded temporal variations show similar trends, which, over a millennial time-scale appear to parallel the main drift in δ¹⁸O as determined for the GRIP ice-core. It is postulated that some smaller scale variations in the δ¹³C profiles may reflect the shorter term oscillations in δ¹⁸O values evident in the GRIP record, although this is less certain. Overall, however, the results suggest that stable carbon isotope measurements based on organ-specific terrestrial plant macrofossils may provide (i) a means for establishing correlations between terrestrial successions and (ii) additional paleoenvironmental information, as the apparent ‘shadowing’ of the GRIP record indicates a common forcing mechanism for both Greenland δ¹⁸O and northwest European δ¹³C variations. From the evidence available we suggest that the recorded δ¹³C variations reflect fluctuations in air temperature and/or changes in water vapour pressure in the atmosphere. © 1997 John Wiley & Sons, Ltd.     

Electron paramagnetic resonance,optical absorption,and magnetic circular dichroism studies of the CO 3 − molecular-ion in irradiated natural beryl

Room temperature X-irradiation of some natural beryls produced several new absorption lines in the electron paramagnetic resonance (EPR) spectrum, a known series of optical absorption lines in the 500–700 nm range, and a shift of the absorption edge to lower energies. Several of the new EPR lines and part of the irradiation-induced shift of the absorption edge disappeared after a few days at room temperature, and were not examined in detail. However, three of the paramagnetic centres responsible for the new EPR lines were stable at room temperature and two of these have previously been identified as atomic hydrogen and the methyl radical, CH₃. These species were stable to ～150 and ～450°C respectively. The third stable species, hitherto unreported, showed a single-line EPR spectrum of axial symmetry, with g∥=2.0051 and g⊥=2.0152. This spectrum was found to be intensity-correlated with the series of optical bands in the 500–700 nm range, after thermal bleaching at 175°C. The EPR and optical spectra are therefore assigned to the same species. It is argued that this species is the CO ₃ ^? molecular ion, located in the widest part of the structural channel and aligned with the plane of the molecule perpendicular to the c axis. The EPR spectrum is consistent with a ² A′₂ ground state of a CO ₃ ^? molecule with trigonal symmetry, and this requires that the optical transition has a ² A′₂ → ² E′ character. Most of the features in the optical spectrum can be assigned to coupling of a totally symmetric mode of frequency ～1020 cm^?1 onto a zero-phonon line at 14,490 cm^?1 and a second weaker line at 16,020 cm^?1. However, both of these two fundamental lines are structured, and the two components show strong temperature-dependent derivative-shaped magnetic circular dichroism (MCD). Furthermore, the overall sign of the MCD for the line at 16,020 cm^?1 is opposite to that at 14,490 cm^?1. The separation (～120 cm^?1) of the two components of the 14,490 cm^?1 line is much larger than that expected from spin-orbit interaction, and the origin of this splitting is not yet understood.     

Cluster–subcluster mergers and the formation of narrow-angle tailed radio sources

We examine the ROSAT PSPC X-ray properties of a sample of 15 Abell clusters containing 23 narrow-angle tailed (NAT) radio galaxies. We find that clusters with NATs show a significantly higher level of substructure than a similar sample of radio-quiet clusters, indicating that NAT radio sources are preferentially located in dynamically complex systems. Also, the velocity distribution of the NAT galaxies is similar to that of other cluster members; these velocities are inadequate for producing the ram pressure necessary to bend the radio jets. We therefore propose a new model for NAT formation, in which NATs are associated with dynamically complex clusters undergoing merger events. The U -shaped NAT morphology is produced in part by the merger-induced bulk motion of the ICM bending the jets.     

Silicic differentiates of abyssal oceanic magmas: Evidence for late-magmatic vapor transport of potassium

Massive, nearly holocrystalline dolerites from DSDP Hole 417D contain from 0.5 to 1.5% of granophyric patches composed mainly of Na-plagioclase and quartz. These patches are compositionally similar to other crystalline silicic rocks from oceanic spreading centers and differ from rarer abyssal silicic glasses. Crystalline varieties withSiO₂60wt.% generally haveNa/K>10, whereas silicic glasses have Na/K in the range 3–6. While crystal fractionation readily accounts for the Na₂O and K₂O contents of abyssal silicic glasses, both the 417D granophyres and other crystalline abyssal silicic rocks have much lower K₂O than that predicted by any reasonable crystal-liquid fractionation model. We propose that high-temperature vapor phase transport is responsible for removal of potassium during late-stage crystallization of these rocks. This allows for the formation of cogenetic silicic glassy and crystalline rocks with greatly different Na/K ratios. These observations and interpretations lead to a more confident assignment of high Na/K silicic rocks of oceanic and ophiolitic environments to a cogenetic origin with basaltic oceanic crust.     

Se and Te mineralization in albitites and prospects of the metasomatites for Au,Salla-Kuolajarvi belt,Northern Karelia

On the basis of the complex of geological features, the eastern flank of the Salla-Pana-Kuolajarvi belt is a prospect structure for gold mineralization in the U-bearing albitites and related acid and mafic metasomatites. Visible tellurides and selenides, which are typical of gold deposits of the Fe-Co-Au-U group in the adjacent territory of Finland within the Salla-Pana-Kuolajarvi belt, were found in the Ozerny occurrence as a result of studies. Native gold is found in association with tellurides. Molybdenite from the occurrence has a high Re content up to 0.3%.     

On error bounds and initialization in satellite orbit theories

The order of magnitude of the error is investigated for a first-order von Zeipel theory of satellite orbits in an axisymmetric force field, i.e., first-order long period and short-period effects are included along with second order secular rates. The treatment is valid for zero eccentricity and/or inclination. In the case where initial position and velocity vectors are known, the in-track position error over time intervals of order 1/J ₂ is kept at 0(J ₂ ²), like the other position errors and velocity errors, by calibration of the mean motion with the aid of the energy integral. The results are specifically applicable to accuracy comparisons of the Brouwer orbit prediction method with numerical integration. A modified calibration is presented for the general asymmetric force field which includes tesseral harmonics.     

Tides in the Tongan Region of the Pacific Ocean

Tidal levels and currents in the Tongan region of the Pacific were simulated using a two-dimensional frequency-domain finite element model. The eight major diurnal and semidiurnal tidal constituents were modeled successfully, using open boundary conditions taken from a global tidal model based on the Topex/Poseidon satellite altimeter. Comparison of model results with observations from the single tide gauge site in the area were later used to adjust the boundary conditions. The validity of omitting horizontal eddy viscosity from the finite element model was checked by running an equivalent finite difference model. The results show that although the submarine Tongan ridge does not appear to trap tidal energy, there are residual tidal currents and possible recirculations which are capable of influencing biological productivity around Tonga. The model results are reduced to a simple method for predicting tidal heights in outlying areas, based only on the tidal calendar for the capital, Nuku'alofa.     

SUBURBANIZATION IN THE CLEVELAND SMSA, 1950–1970

Suburban growth is a complex process attributable partly to decentralization and partly to deconcentration. Data on source of migrants and population density are used to operationalize these concepts in an empirical study of the Cleveland, Ohio SMSA for the period 1950 to 1970. Statistical analysis of census tract data for the suburban ring reveals a piling up of densities at the inner edge and suggests a complex pattern with respect to sources of the migrants contributing to suburban growth.