Kinetics of Disproportionation of Inorganic Polysulfides in Undersaturated Aqueous Solutions at Environmentally Relevant Conditions

The rate of the reversible homogeneous disproportionation of polysulfides was studied by following the optical absorbance of polysulfide solutions in a continuous plug flow reactor equipped with an on-line photometric detector. In order to avoid heterogeneous slow reactions involving sulfur colloids or precipitate, the reaction was initiated by an abrupt pH change from an undersaturated solution containing predominantly tetrasulfide species to a pH where pentasulfide is the dominant species. The disproportionation was found to follow first order reversible reaction dynamics. At environmentally relevant conditions the characteristic time of the disproportionation reaction is of the order of 10 s. This characteristic time implies that necessary conditions for speciation of the different polysulfide species by chromatography or another separation and subsequent quantification scheme should be of the order of 1 s.     

Stationary spatially modulated fourier transform spectro-radiometer

Journal of the Indian Society of Remote Sensing - A stationary, compact, spatially modulated Fourier Transform spectro-radiometer based on triangular, common path Sagnac interferometer has been...     

A new approach to verify the model core with idealized experiments

Summary ?A newly developed ocean general circulation model has been tested and verified with some idealized experiments. Generally two types of idealized experiments have been done here. First types are called as “symmetric experiments” and second types are called as “transport experiments”. The first types of experiment help to correct the model core and any deficiency from boundary conditions. The second types of experiment are the type of validation experiment. In both the experiments there are no continents, so in the first type of experiments where symmetric forcings are provided one can expect that model should maintain the symmetric nature. In the second type of experiments one can expect that model should respond correctly to the wind forcings, if no wind curl is present in the wind forcing there will be no circulation in the extratropics and if there is no wind the equator there will be no circulation. The model reproduces the possible envisaged results of these experiments and gives the confidence for performing the realistic integration. Received February 20, 2002; accepted July 7, 2002 Published online: February 20, 2003     

Vulnerability Assessment of the Maize and Sorghum Crops to Climate Change in Botswana

This study examines the sensitivity of maize and sorghum crops to global warming in Botswana, a country with arid climatic conditions and shortfalls in locally produced grain. The vulnerability of the maize and sorghum crops to climate change were studied using crop simulation models while climate change scenarios were generated from Global Circulation Models. Simulated yields indicated that rain-fed crop production under the observed climate was a small fraction of what could be produced under optimal conditions. The gap was attributed to both physical (especially lack of rain) and socio-economic constraints. Using the southern African core climate change scenario, simulated yields declined by 36% in the case of maize and 31% for sorghum in the sand veldt region. Yield reductions from thehard veldt region were in the order of 10% for both maize and sorghum. The growing season became shorter, the average reduction in days in the sand veldt region being 5 and 8 days for maize and sorghum respectively, and correspondingly, 3 and 4 days over the hard veldt region. The food security option currently followed in Botswana was found to be a good adaptive strategy under a changed climate.     

Reactive Nitrogen Compounds at Spitsbergen in the Norwegian Arctic

Simultaneousindependent measurements of NO_y and NO_x(NO_x= NO + NO₂) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NO_xmixing ratio was 27 pptv and did not show any cyclethrough the period. The NO_y mixing ratio showeda maximum in late March, while the difference betweenNO_y and PAN decreased during spring. This is anindication of the dominance of PAN in the NO_ybudget in the Arctic, but possible changes in theefficiency of the NO_y converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h^-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1.     

Calculations of horizontal mixing rates using222Rn and the controls on hypoxia in western Long Island Sound, 1991

Late summer hypoxia (<3 ppm oxygen) in western Long Island Sound (WLIS) is a persistent environmental and management issue whose controlling processes are poorly understood. Measured rates of sediment and water-column oxygen consumption in the bottom water suggest that a condition of no oxygen should be attained on the time scale of 13–30 d. Observations, however, indicate the onset of hypoxia is of the order 150 d. Therefore, horizontal and/or vertical transport of oxygen into the area of hypoxia must play an important role. Hypoxia decreases benthic activity and the sediment flux of²²²Rn. The resulting horizontal gradient in bottom water²²²Rn was measured and used to estimate the effective horizontal transport rate (>5–50 m² s^?1), which is considerably slower than previous estimates. Scale analysis of the hypoxia process indicates that horizontal transport rates alone can explain the slow progression of hypoxia in XLIS but that vertical processes may also be capable of delaying the onset of hypoxia especially under conditions of weak stratification or weak intermediate layer oxygen consumption. This scale analysis indicates a delicately balanced process that is sensitive to both climatologically-driven variability in the rates of horizontal and vertical transport as well as the biologically-driven rates of oxygen consumption. An improved ability to predict and/or control hypoxia must be based on a better understanding of temporal and spacial variations in circulation, mixing, and stratification as well as the biological processes in the water column and the sediments.