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231.
Neal T. Skipper Peter A. Lock James O. Titiloye Jan Swenson Zakaria A. Mirza W. Spencer Howells Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196
The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献
232.
233.
234.
A. V. Maslov M. V. Isherskaya Yu. L. Ronkin M. T. Krupenin N. P. Gorbunova T. Ya. Gulyaeva O. P. Lepikhina O. Yu. Popova G. M. Yatluk 《Lithology and Mineral Resources》2006,41(3):250-270
Variation of geochemical modules and indices in mudstones from the Upper Vendian Kairovo and Shkapovo groups of the Shkapovo-Shikhan Basin provides the comprehensive information on changes in maturity of the fine aluminosiliciclastic material delivered in the basin, characterizes the redox environment in bottom water, and makes it possible to reconstruct the rock composition in provenance and its evolution through time. The generally moderate maturity of the fine terrigenous clastic material suggests that a nearly semiarid-semihumid climate dominated in paleodrainage area throughout the Late Vendian. It has been established that reducing environment did not exist in bottom water of the central Shkapovo-Shikhan Basin throughout the Late Vendian. Intermediate rocks prevailed in the paleodrainage area. More silicic rocks could occur only in the early Staropetrovo and late Salikhovo times. Data points of mudstones from the Kairovo and Shkapovo Groups plotted on the Cr-Ni, Co-V, Co/Hf-Ce/Cr, La-Th, and La/Sm-Sc/Th diagrams indicate that both Archean and more mature Paleoproterozoic crustal blocks existed in different proportions in the Late Vendian within source areas. 相似文献
235.
236.
Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola,
the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base
metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity
to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate
their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO
Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with
a KO
Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower
part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements
along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously
described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from
the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively.
The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition
above the cupola in the ore veins of the Schlema and Schneeberg deposits.
Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp.
967–982. 相似文献
237.
V. A. Marinov S. V. Meledina O. S. Dzyuba O. S. Urman O. V. Yazikova V. A. Luchinina A. G. Zamirailova A. N. Fomin 《Stratigraphy and Geological Correlation》2006,14(4):418-432
Paleontological study of Upper Jurassic and Lower Cretaceous sediments recovered by boreholes in the Agan-Vakh and Nadym-Vengapur interfluves clarified environments of their deposition. As is shown, influx of siliciclastic material to central areas of the West Siberian sea basin varied through time. Taxonomic composition and ecological structure of nektonic and benthic fossil assemblages are analyzed and considered in terms of environmental factors such as hydrodynamics, aeration, temperature, and salinity of seawater. 相似文献
238.
239.
Atomistic calculations of structural and elastic properties of serpentine minerals: the case of lizardite 总被引:1,自引:0,他引:1
A.-L. Auzende R. J.-M. Pellenq B. Devouard A. Baronnet O. Grauby 《Physics and Chemistry of Minerals》2006,33(4):266-275
The physical properties of the hydrous phyllosilicate lizardite have been investigated by atomistic simulation using the GULP code based on transferable semi-empirical interatomic potentials. Lizardite behavior was first investigated during structure relaxation at room temperature. The Helmholtz free energy is minimum for an equilibrium structure that is in agreement with experiment. The bulk, shear, and Young modulii for lizardite were calculated along with the Poisson ratio. From the shear and bulk modulii, we also calculated translational and longitudinal acoustic wave velocities that are important quantities for tectonophysics models. As expected, lizardite is stiffer in the a direction parallel to the layers than in the c perpendicular direction; the variation of the unit cell parameters with pressure is in good agreement with experiment. The cohesive energy between two successive layers along c direction was calculated at 0.33 eV (i.e., 0.11 eV per OH bond) in good agreement with recent ab initio calculations. Upon pressure and temperature variations, we evidenced that structural changes are mainly pressure induced; pressure being accommodated by a decrease of the c parameter up to 10 GPa. We also found that the change of slope in the derivative of the c cell parameter with respect to pressure occurring around 2 GPa originates from the bending of the interlayer hydroxyl groups with respect to the layer normal direction. 相似文献
240.
E. O. Groznova M. G. Dobrovol’skaya V. A. Kovalenker K. V. Davydov V. T. Bitarov M. V. Razin 《Geology of Ore Deposits》2006,48(2):108-133
The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ~120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry. 相似文献