Diffusion and solubility of hydrogen and water in periclase

Cylinders of synthetic periclase single crystals were annealed at 0.15–0.5 GPa and 900–1200 °C under water-saturated conditions for 45 min to 72 h. Infrared spectra measured on the quenched products show bands at 3,297 and 3,312 cm^?1 indicating V _OH ^? centers (OH-defect stretching vibrations in a half-compensated cation vacancy) in the MgO structure as a result of proton diffusion into the crystal. For completely equilibrated specimens, the OH-defect concentration, expressed as H₂O equivalent, was calculated to 3.5 wt ppm H₂O at 1,200 °C and 0.5 GPa based on the calibration method of Libowitzky and Rossmann (Am Min 82:1111–1115, 1997). This value was confirmed via Raman spectroscopy, which shows OH-defect-related bands at identical wavenumbers and yields an H₂O equivalent concentration of about 9 wt ppm using the quantification scheme of Thomas et al. (Am Min 93:1550–1557, 2008), revised by Mrosko et al. (Am Mineral 96:1748–1759, 2011). Results of both independent methods give an overall OH-defect concentration range of 3.5–9 (+4.5/?2.6) ppm H₂O. Proton diffusion follows an Arrhenius law with an activation energy E _a = 280 ± 64 kJ mol^?1 and the logarithm of the pre-exponential factor logD_o (m² s^?1) = ?2.4 ± 1.9. IR spectra taken close to the rims of MgO crystals that were exposed to water-saturated conditions at 1,200 °C and 0.5 GPa for 24 h show an additional band at 3,697 cm^?1, which is related to brucite precipitates. This may be explained by diffusion of molecular water into the periclase, and its reaction with the host crystal during quenching. Diffusion of molecular water may be described by logD_H2O (m² s^?1) = ?14.1 ± 0.4 (2σ) at 1,200 °C and 0.5 GPa, which is ~ 2 orders of magnitude slower than proton diffusion at identical P-T conditions.     

HydrIS: An open source GIS decision support system for groundwater management (Morocco)

A regional groundwater management system has been elaborated, integrating Relational Database Management System (RDBMS) and various web services. It consists of web geospatial application so-called HydrIS (Hydrogeological Information System) based on Open Source components and technologies, leading to a feasible and low-cost solution. Therefore, HydrIS permits delivery of data from a number of heterogeneous sources to standards supported by the Open Geospatial Consortium (OGC). The protocols used for exchanging data are also derived from OGC standards, i.e., WMS (Web Mapping Service), WFS (Web Feature Service), and WCS (Web Coverage Service). Finally, a geoportal was developed, which consists of client-applications that communicate with different Web Services (WMS, WCS, and WFS) through http-requests.     

Chemical pathway analysis of the Martian atmosphere: CO2-formation pathways

The chemical composition of a planetary atmosphere plays an important role for atmospheric structure, stability, and evolution. Potentially complex interactions between chemical species do not often allow for an easy understanding of the underlying chemical mechanisms governing the atmospheric composition. In particular, trace species can affect the abundance of major species by acting in catalytic cycles. On Mars, such cycles even control the abundance of its main atmospheric constituent CO₂. The identification of catalytic cycles (or more generally chemical pathways) by hand is quite demanding. Hence, the application of computer algorithms is beneficial in order to analyze complex chemical reaction networks. Here, we have performed the first automated quantified chemical pathways analysis of the Martian atmosphere with respect to CO₂-production in a given reaction system. For this, we applied the Pathway Analysis Program (PAP) to output data from the Caltech/JPL photochemical Mars model. All dominant chemical pathways directly related to the global CO₂-production have been quantified as a function of height up to 86 km. We quantitatively show that CO₂-production is dominated by chemical pathways involving HO_x and O_x. In addition, we find that NO_x in combination with HO_x and O_x exhibits a non-negligible contribution to CO₂-production, especially in Mars’ lower atmosphere. This study reveals that only a small number of chemical pathways contribute significantly to the atmospheric abundance of CO₂ on Mars; their contributions to CO₂-production vary considerably with altitude. This analysis also endorses the importance of transport processes in governing CO₂-stability in the Martian atmosphere. Lastly, we identify a previously unknown chemical pathway involving HO_x, O_x, and HO₂-photodissociation, contributing 8% towards global CO₂-production by chemical pathways using recommended up-to-date values for reaction rate coefficients.     

Partial melting due to breakdown of an epidote‐group mineral during exhumation of ultrahigh‐pressure eclogite: An example from the North‐East Greenland Caledonides

In the North‐East Greenland Caledonides, P–T conditions and textures are consistent with partial melting of ultrahigh‐pressure (UHP) eclogite during exhumation. The eclogite contains a peak assemblage of garnet, omphacite, kyanite, coesite, rutile, and clinozoisite; in addition, phengite is inferred to have been present at peak conditions. An isochemical phase equilibrium diagram, along with garnet isopleths, constrains peak P–T conditions to be subsolidus at 3.4 GPa and 940°C. Zr‐in‐rutile thermometry on inclusions in garnet yields values of ~820°C at 3.4 GPa. In the eclogite, plagioclase may exhibit cuspate textures against surrounding omphacite and has low dihedral angles in plagioclase–clinopyroxene–garnet aggregates, features that are consistent with former melt–solid–solid boundaries and crystallized melt pockets. Graphic intergrowths of plagioclase and amphibole are present in the matrix. Small euhedral neoblasts of garnet against plagioclase are interpreted as formed from a peritectic reaction during partial melting. Polymineralic inclusions of albite+K‐feldspar and clinopyroxene+quartz±kyanite±plagioclase in large anhedral garnet display plagioclase cusps pointing into the host, which are interpreted as crystallized melt pockets. These textures, along with the mineral composition, suggest partial melting of the eclogite by reactions involving phengite and, to a large extent, an epidote‐group mineral. Calculated and experimentally determined phase relations from the literature reveal that partial melting occurred on the exhumation path, at pressures below the coesite to quartz transition. A calculated P–T phase diagram for a former melt‐bearing domain shows that the formation of the peritectic garnet rim occurred at 1.4 GPa and 900°C, with an assemblage of clinopyroxene, amphibole, and plagioclase equilibrated at 1.3 GPa and 720°C. Isochemical phase equilibrium modelling of a symplectite of clinopyroxene, plagioclase, and amphibole after omphacite, combined with the mineral composition, yields a P–T range at 1.0–1. 6 GPa, 680–1,000°C. The assemblage of amphibole and plagioclase is estimated to reach equilibrium at 717–732°C, calculated by amphibole–plagioclase thermometry for the former melt‐bearing domain and symplectite respectively. The results of this study demonstrate that partial melt formed in the UHP eclogite through breakdown of an epidote‐group mineral with minor involvement of phengite during exhumation from peak pressure; melt was subsequently crystallized on the cooling path.     

High‐P tectono‐metamorphic evolution of mylonites from the Variscan basement of the Northern Apennines,Italy

Strain localization within shear zones may partially erase the rock fabric and the metamorphic assemblage(s) that had developed before the mylonitic event. In poly‐deformed basements, the loss of information on pre‐kinematic phases of mylonites hinders large‐scale correlations based on tectono‐metamorphic data. In this study, devoted to a relict unit of Variscan basement reworked within the nappe stack of the Northern Apennines (Italy), we investigate the possibility to reconstruct a complete pressure (P)–temperature (T)–deformation (D) path of mylonitic micaschist and amphibolite by integrating microstructural analysis, mineral chemistry and thermodynamic modelling. The micaschist is characterized by a mylonitic fabric with fine‐grained K‐white mica and chlorite enveloping mica‐fishes, quartz, and garnet pseudomorphs. Potassic white mica shows Mg‐rich cores and Mg‐poor rims. The amphibolite contains green amphibole+plagioclase+garnet+quartz+ilmenite defining S₁ with a superposed mylonitic fabric localized in decimetre‐ to centimetre‐scale shear zones. Garnet is surrounded by an amphibole+plagioclase corona. Phase diagram calculations provide P–T constraints that are linked to the reconstructed metamorphic‐deformational stages. For the first time an early high‐P stage at >11 kbar and 510°C was constrained, followed by a temperature peak at 550–590°C and 9–10 kbar and a retrograde stage (<475°C, <7 kbar), during which ductile shear zones developed. The inferred clockwise P–T–D path was most likely related to crustal thickening by continent‐continent collision during the Variscan orogeny. A comparison of this P–T–D path with those of other Variscan basement occurrences in the Northern Apennines revealed significant differences. Conversely, a correlation between the tectono‐metamorphic evolution of the Variscan basement at Cerreto pass, NE Sardinia and Ligurian Alps was established.     

Examining ambient noise using colocated measurements of rotational and translational motion

In the past decade, a number of studies have reported the observation of rotational motion associated with seismic events. We report a first observation of rotational motion in the microseismic ambient noise band. A striking feature of rotational motion measurements is that the information about the seismic phase velocity and source back azimuth is contained in the amplitude ratio of a point measurement of rotation rate and transverse acceleration. We investigate the possibility of applying this method to ambient noise measured with a ring laser and a broadband seismometer at the Wettzell Geodetic Observatory in Germany. Using data in the secondary microseismic band, we recover local phase velocities as well as the back azimuth of the strongest noise source for two different time periods. In order to confirm these findings, we additionally compare the results with classical array processing techniques of the Gr?fenberg array located nearby.     

Strain rotation coupling and its implications on the measurement of rotational ground motions

Spatial derivatives of the seismic wave field are known to be sensitive to various site effects (e.g., cavity effects, topography, and geological inhomogeneities). In this study, the focus is on strain rotation coupling that can cause significant differences between point measurements compared to array-derived rotational motions. The strain rotation coupling constants are estimated based on finite element simulations for inhomogeneous media as well as for the 3D topography around Wettzell, Germany (the location of the G ring laser). Using collocated array and ring laser data, the coupling constants of the ring laser itself are shown to be small. Several examples are shown to illustrate the order of magnitude that strain-induced rotation might have on the seismograms in the near field of volcanoes as well as in the far field and in the low-frequency spectrum (free oscillations).     

Improving the assessment of uncertainty and risk in the spatial prediction of environmental impacts: a new approach for fitting geostatistical model parameters based on dual Kriging in the presence of a trend

Modern methods of geostatistics deliver an essential contribution to Environmental Impact Assessment (EIA). These methods allow for spatial interpolation, forecast and risk assessment of expected impact during and after mining projects by integrating different sources of data and information. Geostatistical estimation and simulation algorithms are designed to provide both, a most likely forecast as well as information about the accuracy of the prediction. The representativeness of these measures depends strongly on the quality of the inferred model parameters, which are mainly defined by the parameters of the variogram or the covariance function. Available data may be sparse, trend affected and of different data type making the inference of representative geostatistical model parameters difficult. This contribution introduces a new method for best fitting of the geostatistical model parameters in the presence of a trend, which utilizes the empirical and theoretical differences between Universal Kriging and trend-predictions. The method extends well known approaches of cross validation in two aspects. Firstly, the model evaluation is not only limited to sample data locations but is performed on any prediction locations of the attribute in the domain. Secondly, it extends the measure used in cross validation, based on a single point replacement by using error curves. These allow defining rings of influence representing errors resulting from separate variogram lags. By analyzing the different variogram lags the fit of the complete covariance can be assessed and the influence of the several model parameters separated. The use of the proposed method in an EIA context is illustrated in a case study related on the prediction of mining-induced ground movements.     

作为生态和环境保护手段的空间规划:联邦德国的经验及对中国的启示

联邦德国生态环境保护走过了一条污染-治理-预防的道路, 即由技术性和应激性转为政策性和预防性的环境保护。生态环境保护政策和措施由环保活动家,大企业,学术界,地方及联邦各级有关部门共同制定,并由一个国家级综合的监测体系监督执行。公众不仅有权力了解结果,而且也将参与政策措施的制订和监督。德国空间规划包含欧盟,联邦,州,区域,城镇和城市建设6个层面。空间规划,特别是生态环境规划已成为预防生态环境破坏的重要措施。然而,联邦德国生态环境规划实施也面临个人交通和小企业污染以及环保成本提高造成企业区位劣势所带来的挑战。这些经验教训对中国的生态环境保护目标,政策措施的完善及生态空间规划的制订和监督落实,环境评价,特别是规划本身的环境评价具有借鉴意义。具体包括4个方面: 1)生态环境保护政策实现从提高环保技术手段向预防污染产生转变; 2)保证生态环境保护政策及实施的有效性; 3)把空间规划作为实现区域经济和社会稳定可持续发展的手段,提高生态和环保目标的地位; 4)在规划的技术层面上关注居住,休闲,交通和自然保护区用地的增长。