δ13C signature of early graphite and subsequently formed microdiamond from the Saxonian Erzgebirge,Germany

Microdiamond and graphite occur in quartzofeldspathic rocks (saidenbachites) of the central Erzgebirge in Saxony. Zircon from such rocks contains not only relatively high but also variable amounts of early formed graphite and later crystallized diamond, however no carbonate. Six purified zircon concentrates were analysed by mass spectrometry for δ₁₃C(PDB) values which were between −24 and −33‰. The carbon inclusions resulted in C contents of the concentrates as high as 0.5 wt%. It is hypothesized that the observed δ₁₃C signature results from organic material in the sedimentary protoliths of the saidenbachites probably deposited not earlier than Mid‐Devonian. This material was transformed to graphite during early metamorphism and subsequently to diamond after an anatectic event at great depths (>150 km). During these processes, the δ₁₃C signature of the carbon did not (significantly) change.     

Relative contributions of sublimation and volcanoes to Io's atmosphere inferred from its plasma interaction during solar eclipse

We present a model that describes Io's delayed electrodynamic response to a temporal change in Io's atmosphere. Our model incorporates the relevant physical processes involved in Io's atmosphere-ionosphere-magnetosphere electrodynamic interaction to predict the far-ultraviolet (FUV) radiation as Io enters Jupiter's shadow and re-emerges into sunlight. The predicted FUV brightnesses are highly nonlinear as the strength of the electrodynamic interaction depends on the ratios of ionospheric conductances to the torus Alfvén conductance, but the former are functions of electrodynamics and the atmospheric density, which decays rapidly upon entering eclipse. Key factors governing the time evolution are the column density due to sublimation and the column density due to volcanoes, which maintain the background atmosphere during eclipse. The plasma interaction does not react instantaneously, but lags to a temporarily changing atmosphere. We find three qualitatively different scenarios with two of them including a post-eclipse brightening. The brightness ratio of in-sunlight/in-eclipse coupled with the existence of a sub-jovian equatorial spot constrains the volcanic column density to several times 10¹⁸ m⁻², based on the currently available observations. Thus in sunlight, the sublimation driven part of Io's atmosphere dominates the volcanically driven contribution by roughly a factor of 10 or more.     

Oxidation of CO on surface hematite in high CO2 atmospheres

We propose a mechanism for the oxidation of gaseous CO into CO₂ occurring on the surface mineral hematite (Fe₂O₃(s)) in hot, CO₂-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of tropospheric CO₂ on Venus and could at least partly address the CO₂ stability problem in Venus’ stratosphere, since our results suggest that atmospheric CO₂ is produced from CO oxidation via surface hematite at a rate of 0.4 petagrammes (Pg) CO₂ per (Earth) year on Venus which is about 45% of the mass loss of CO₂ via photolysis in the Venusian stratosphere. We also investigated CO oxidation via the hematite mechanism for a range of planetary scenarios and found that modern Earth and Mars are probably too cold for the mechanism to be important because the rate-limiting step, involving CO(g) reacting onto the hematite surface, proceeds much slower at lower temperatures. The mechanism may feature on extrasolar planets such as Gliese 581c or CoRoT-7b assuming they can maintain solid surface hematite which, e.g. starts to melt above about 1200 K. The mechanism may also be important for hot Hadean-type environments and for the emerging class of hot Super-Earths with planetary surface temperatures between about 600 and 900 K.     

Mixing and chemical interdiffusion of trachytic and latitic magma in a subvolcanic complex of the Tertiary Westerwald (Germany)

A special kind of magma mixing is extraordinarily well exposed in the Bittersberg subvolcanic complex in the Tertiary volcanic field of the German Westerwald: A trachytic melt has been penetrated by a latitic dyke which has been dispersed within the host magma as small spherical enclaves (globules). Whole rock analyses of the globules show a change in composition that cannot be explained by a simple mechanical mixing between the endmembers. The most evolved globules have a phonolitic composition. Microprobe measurements in the microlithic matrix of the host rock and the guest indicate a diffusive motion of the alkalis from the host into the globules. On the other hand, an opposite trend can be observed for Ca, Mg, Fe and Ti, which are impoverished in the globules. The trace elements and the middle rare earth elements (MREE) has also been involved in the diffusive exchange. The REE-pattern of the most evolved (phonolitic) globules shows a characteristic trough in the area of the MREE which is almost identical to the REE-pattern of many phonolites. The phonolites and the alkali-rich trachytes of the Westerwald show similar globular textures as the Bittersberg volcanics. Therefore, generation of these rocks involving diffusive element exchange during mixing processes in a magma reservoir situated on a deeper crustal level may be possible.     

Provenance of the Bosnian Flysch

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.     

Correlation of δ<Superscript>18</Superscript>O and initial<Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr ratios in Kirkpatrick basalt on Mt. Falla,transantarctic mountains

Theδ¹⁸O (SMOW) values of the Kirkpatrick Basalt (Jurassic) on Mt. Falla, Queen Alexandra Range, vary between +6.3‰ and +8.6‰ The apparent enrichment of these rocks in¹⁸O excludes the possibility that they were altered by interaction with aqueous solutions of meteoric origin. Theδ¹⁸O values of the flows correlate significantly with the initial⁸⁷Sr/⁸⁶Sr ratios and all major elements. These correlations confirm the hypothesis that the basalt magma was contaminated by rocks of the continental crust through which it was extruded. Estimates of the chemical composition of the basalt magma and the contaminant, based on extrapolations of the new oxygen data, generally confirm earlier estimates based on extrapolations of initial⁸⁷Sr/⁸⁶Sr ratios. The⁸⁷Sr/⁸⁶Sr ratio of the uncontaminated basalt was 0.7093 which indicates that magma may have originated by melting either in old Rb-enriched lithospheric mantle under Antarctica or in the overlying crust, or both.     

‘Box‐Profile’ Ion Implants as Geochemical Reference Materials for Electron Probe Microanalysis and Secondary Ion Mass Spectrometry

Although electron probe microanalysis and secondary ion mass spectrometry are widely used analytical techniques for geochemical and mineralogical applications, metrologically rigorous quantification remains a major challenge for these methods. Secondary ion mass spectrometry (SIMS) in particular is a matrix‐sensitive method, and the use of matrix‐matched reference materials (RMs) is essential to avoid significant analytical bias. A major problem is that the number of available RMs for SIMS is extremely small compared with the needs of analysts. One approach for the production of matrix‐specific RMs is the use of high‐energy ion implantation that introduces a known amount of a selected isotope into a material. We chose the more elaborate way of implanting a so‐called ‘box‐profile’ to generate a quasi‐homogeneous concentration of the implanted isotope in three dimensions, which allows RMs not only to be used for ion beam analysis but also makes them suitable for EPMA. For proof of concept, we used the thoroughly studied mineralogically and chemically ‘simple’ SiO₂ system. We implanted either ⁴⁷Ti or ⁴⁸Ti into synthetic, ultra‐high‐purity silica glass. Several ‘box‐profiles’ with mass fractions between 10 and 1000 μg g^?1 Ti and maximum depths of homogeneous Ti distribution between 200 nm and 3 μm were produced at the Institute of Ion Beam Physics and Materials Research of Helmholtz‐Zentrum Dresden‐Rossendorf. Multiple implantation steps using varying ion energies and ion doses were simulated with Stopping and Range of Ions in Matter (SRIM) software, optimising for the target concentrations, implantation depths and technical limits of the implanter. We characterised several implant test samples having different concentrations and maximum implantation depths by means of SIMS and other analytical techniques. The results show that the implant samples are suitable for use as reference materials for SIMS measurements. The multi‐energy ion implantation technique also appears to be a promising procedure for the production of EPMA‐suitable reference materials.