Effect of alkaline solutions on bentonite properties

The influence of alkaline aqueous solutions on the properties of bentonite was investigated to evaluate the performance of bentonitic engineered barriers when contacted with alkaline groundwater. Batch and hydraulic conductivity tests were conducted on Na-bentonite using six different alkaline aqueous solutions. For the batch tests, almost no change in the montmorillonite fraction of the bentonite was observed after reacting with alkaline solutions (pH = 8.4–13.1), regardless of the solution type. On the other hand, aluminosilicate minerals (e.g., albite) were dissolved and secondary minerals (e.g., anorthite) were formed in alkaline NaOH solutions (pH > 13). The cation (Ca or Na) concentration primarily affected the swelling properties of bentonite rather than the pH of the solution, which was comparable to the results of the hydraulic conductivity tests. For the Ca solutions, the hydraulic conductivity of the bentonite specimen to the 0.02 mol/L Ca(OH)₂ solution (6.5 × 10^?9 cm/s) was approximately an order of magnitude lower than that of the bentonite specimen to the 0.02 mol/L Ca(OH)₂ + 1 mol/L CaCl₂ solution (5.0 × 10^?8 cm/s), whereas the hydraulic conductivity to the 0.02 mol/L Ca(OH)₂ + 1 mol/L CaCl₂ solution (pH = 11.3) (5.0 × 10^?8 cm/s) was slightly higher than that to the 1 mol/L CaCl₂ solution (pH_i = 8.4) (4.4 × 10^?8 cm/s). For the NaOH solutions with pH > 13, the hydraulic conductivity of the bentonite specimen decreased with increasing Na concentration, suggesting that the effect of Na concentration was more dominant than that of permeant pH.     

Mechanism and kinetics of hydrothermal replacement of magnetite by hematite

The replacement of magnetite by hematite was studied through a series of experiments under mild hydrothermal conditions(140 -220℃, vapour saturated pressures) to quantify the kinetics of the transformation and the relative effects of redox and non-redox processes on the transformation. The results indicate that oxygen is not an essential factor in the replacement reaction of magnetite by hematite, but the addition of excess oxidant does trigger the oxidation reaction, and increases the kinetics of the transformation. However, even under high O_2(aq) environments, some of the replacement still occurred via Fe²⁺ leaching from magnetite. The kinetics of the replacement reaction depends upon temperature and solution parameters such as pH and the concentrations of ligands, all of which are factors that control the solubility of magnetite and affect the transport of Fe²⁺ (and the oxidant) to and from the reaction front. Reaction rates are fast at ~200℃, and in nature transport properties of Fe and,in the case of the redox-controlled replacement, the oxidant will be the rate-limiting control on the reaction progress. Using an Avrami treatment of the kinetic data and the Arrhenius equation, the activation energy for the transformation under non-redox conditions was calculated to be 26 ± 6 kJ mol^-1.This value is in agreement with the reported activation energy for the dissolution of magnetite, which is the rate-limiting process for the transformation under non-redox conditions.     

Concentrations of cadmium,copper, lead and zinc in surface waters of the Northwest Atlantic Ocean — A comparison of Go-flo and teflon water samplers

The concentrations of cadmium, copper, lead and zinc were measured at two locations in surface waters of the western North Atlantic. Samples were collected upstream of the research vessel in 1-1 teflon bottles, and in a 30-1 teflon-coated Go-flo bottle. Surface mixed-layer samples were also collected at each location by ship cast using this same Go-flo sampler. A comparison of the three sampling modes shows that all the samples taken with the Go-flo sampler possessed much higher concentrations of zinc (7–10-fold) and lead (2–3-fold) than those collected directly in teflon bottles. No apparent differences were noted at each station in the concentrations of either copper or cadmium among the samples collected by the three different procedures. The measured values for copper and cadmium in these waters are in good agreement with recent reports for the western North Atlantic.     

Iaga Paleomagnetic Databases with access

Since the release of the Global Paleomagnetic Database (GPMDB) in 1991, there have been successive updates every two years, with the current version being 3.1. The authors have now constructed a set of four databases that have been sponsored by the International Association of Geomagnetism and Aeronomy (IAGA). These include the GPMDB together with the Paleointensity Database (PALIN), the Polarity Transitions Database (TRANS) and the Secular Variation Database (SECVR). Each of these databases is now released to operate under Microsoft Access V2.0 and are specifically designed so as to operate independently of each other. The design and operation of these databases with Access is described in this second supplement to the Global Paleomagnetic Databases.     

Thermal alteration experiments on organic matter in recent marine sediment—I. Pigments

Sediment from Tanner Basin, located at the outer continental shelf off southern California, was analyzed for photosynthetic pigments and their derivatives, namely carotenes and chlorins. Samples of the sediment were also exposed to raised temperatures (65°, 100°, 150°C) for various periods of time (1 week, 1 month, 2 months). Analysis of the heat-treated sediment revealed the presence of α-ionene and 2,6-dimethylnaphthalene, thermal-degradation products of β-carotene. Chlorins were converted to nickel porphyrins of both DPEP and etio series. Possible mechanisms and geochemical significance of these transformations are presented.     

Composition isotopique du plomb et du soufre des galènes liées aux formations sédimentaires interprétations géologiques et géophysiques

Stratiform deposits found in mesozoic sedimentary layers, in Marocco and in France, have been analysed to determine lead and sulphur isotopic compositions.For the sulphur, the results indicate a low temperature formation, and are in good agreement with synsedimentary theories. The lead isotopic compositions are anomalous: J type for french galenas, B type for these of Marocco. The authors propose that the lead of these galenas have had a continental origin; the two different histories of the continental areas explain the galena anomalous compositions; two factors are particulary important: the age of the crust formation, and after that, the time of separation of lead from uranium and thorium in the continental crust.     

Paleocurrents and the problem of continental drift

The hypothesis of continental drift is examined on the light of paleocurrent analysis. A peripherical radial transportation pattern was obtained in South America and Africa from marine sandstones deposited during Ordovician to Devonian times. This pattern is suggestive of a former adjacent position between both continents, being the source area located somewhere in eastern Brazil and western Africa (Figs. 8 and 9). The paleocurrents in both continents flowed away from this common area. Evidences of Ordovician and/or Silurian glaciation indicated a radial movement for the ice-sheets, away from the same source area. The Caradocian ice movement in Sahara was to the north, while the ice-flow in the Gape Province was to the south, and in Northeastern Brazil it was possibly to the west.The Carboniferous paleocurrent and ice-movement trends are suggestive of a territorial contiguity between Africa and South America. However, several data must be revised for stratigraphic control.The Permian formations in the Paraná and Karroo basins had independent development without any direct connection as suggested by cross-bedding analysis. The occurrence ofMesosaurus in both basins is a strong argument of their close position at the time of sedimentation.Mesozoic wind laid deposits occur in both continents from Upper Triassic to Lower Cretaceous time. The Triassic eolian sandstones were deposited by westerly paleowinds in middle latitude region at the time of continental contiguity. The Upper Jurassic-Lower Cretaceous eolian sandstones were deposited after the separation between the continents had started. The paleowind pattern includes westerlies, trade-,and return tradewinds. This pattern is suggestive for the presence of the Southern Atlantic Ocean in Upper Jurassic-Lower Cretaceous time.

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Zusammenfassung Die Hypothese der Kontinentaldrift der Südkontinente Afrika und Südamerika wird mit Hilfe der Analyse von PalÄoströmungen untersucht.Marine Sandsteinablagerungen vom Ordoviz bis zum Devon zeigen in Südamerika und auch in Afrika peripher-radiales Transportnetz.Dies weist auf eine früher zusammenhÄngende Position zwischen beiden Kontinenten hin, deren Ursprung in Ost-Brasilien und West-Afrika gelegen haben mu\, da die Strömungsrichtungen in beiden Kontinenten von diesem Gebiet ausgehen (Fig. 8 und 9).Die Vereisung im Ordoviz und/oder Silur zeigt eine sternförmige Bewegungsrichtung des Eises vom gleichen Ursprungsgebiet aus. Die Strömungsrichtung zur Caradoc-Zeit war in der Sahara nach N gerichtet, wÄhrend sich das Eis in der Kap-Provinz nach S und in NE-Brasilien möglicherweise nach W bewegte.Die Strömungsrichtungen und Eisbewegungen im Karbon deuten auf einen territorialen Zusammenhang zwischen Afrika und Südamerika hin, jedoch bedürfen einige Daten einer stratigraphischen überprüfung.Das Perm im Paraná- und Karroo-Becken zeigt eine unabhÄngige Entwicklung ohne direkten Zusammenhang, wie er aus SchrÄgschichtungsmessungen angedeutet wurde. Das Vorkommen vonMesosaurus in beiden Becken ist ein gewichtiges Argument für ihre benachbarte Lage wÄhrend der Sedimentation.Im Mesozoikum finden wir von Obertrias bis Unterkreide in beiden Kontinenten Äolische Ablagerungen. Die der Trias wurden durch westliche Winde in mittleren geographischen Breiten sedimentiert, zu einer Zeit, als die beiden Kontinente noch zusammenhingen. Die Sandsteine des Oberen Juras und der Unteren Kreide wurden abgelagert, nachdem die Trennung der Kontinente begonnen hatte.Das PalÄowindsystem zeigt westliche und Passatwinde. Dieses System spricht bereits für das Vorhandensein des Südatlantiks wÄhrend dem Oberen Jura und der Unteren Kreide.

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Sumário No presente trabalho o problema da deriva continental é examinada do ponto de vista da análise das paleocorrentes. MediÇÕes de estratos cruzados em arenitos marinhos do Ordoviciano ao Devoniano, realizadas na áfrica e na América do Sul indicaram urn padrÃo de transporte periférico-radial. Êste padrÃo é sugestivo de uma justaposiÇÃo pretérita entre ambos continentes. A área fonte estaria localizada na regiÃo oriental da América do Sul e Ocidental da áfrica (figs. 8 e 9). Em ambos continentes as paleocorrentes fluiram a partir desta área comum. EvidÊncias de glaciaÇÃo Ordoviciana e/ou Siluriana indicam um movimento radial das massas de gÊlo a partir da mesma área fonte. No Sahara, o movimento do gÊlo no Caradociano fazia-se para o norte, enquanto que, na Provincia do Cabo era para o Sul, e no Nordeste do Brasil Êle provàvelmente dirigia-se para o oeste.No Carbonifero, as paleocorrentes e tendÊncia do movimento das geleiras sÃo sugestivas de uma contiguidade territorial entre a América do Sul e áfrica. Contudo, várlos dados devem ser revisados para controle estratigráfico.As formaÇÕes Permianas nas bacias do Paraná e do Karroo apresentam desenvolvimento independente. O estudo das paleocorrentes nÃo sugere qualquer ligaÇÃo direta. Entretanto, a ocorrÊncia deMesosaurus em ambas bacias, constitui forte argumenta a favor de maior proximidade entre elas na época de sedimentaÇÃo.Os depósitos eólicos mesozóicos ocorrem em ambos continentes desde o Triássico Superior até o Cretáceo Inferior. Os arenitos eólicos Triássicos foram depositados em regiÃo de latitude média pelos paleoventos de oeste. Nésta época, ambos os continentes encontravam-se unidos. Os arenitos eólicos do Jurássico Superior-Cretáceo Inferior foram depositados após o início da separaÇÃo. O sistema de paleoventos inclui ventos de oeste, aliseos e aliseos de retÔrno. Êste padrÃo de circulaÇÃo aérea é sugestivo da presenÇa do Atlântico sul durante o Jurássico Superior — Cretáceo Inferior.

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Under the auspices of the Conselho Nacional de Pesquisas (Brasil), Geological Survey of South Africa, and Institute Algerien du Pétrole.     

The relationship of auroral absorption to the electron energy distribution of the plasma

An auroral absorption event in the D-region of the atmosphere has been studied by simultaneous measurements of electron temperature, electron density and hyperthermal electrons with a Langmuir probe, and of radio absorption coefficient by 30 MHz riometers. The absorption of the radio waves cannot be explained only by the enhancement of the electron density but requires that the electron collision frequency v be increased above its normal value by the presence of a high energy tail in the electron distribution function. A model is used to determine the characteristics of the hyperthermal electrons in order to evaluate their contribution to the collision frequency and to the absorption coefficient. Good agreement is found between theoretical and experimental values.     

Dynamic analysis of structures using modified Lanczos co‐ordinates

An efficient dynamic analysis method using the modified Lanczos co‐ordinates is presented. The proposed method is obtained by applying the modified Lanczos algorithm using Lanczos vectors that satisfy the stiffness‐orthonormality condition to the conventional Lanczos co‐ordinates method. The modified Lanczos co‐ordinates method is more efficient than the conventional method in the case of structures under multi‐input loads. The effectiveness of the modified Lanczos co‐ordinates method is verified by analysing a numerical example. Copyright © 2003 John Wiley & Sons, Ltd.