A Review on Marine N2 Fixation: Mechanism,Evolution of Methodologies,Rates, and Future Concerns

Ocean Science Journal - Investigations on marine N2 fixation have gained momentum since 1960s with eventual establishments of relevant methodologies to identify species involved and quantify the...     

Holocene and Eemian climatic optima in the Korean Peninsula based on textural and carbon isotopic records from the stalagmite of the Daeya Cave,South Korea

Textural and stable isotopic records from the absolute-dated stalagmite of the Daeya Cave (DY-1) provide new insights into the climatic evolution of the Korean Peninsula during the Holocene and Eemian climatic optima. The stalagmite yielded ages of 8572 ± 227 to 5907 ± 158 and 1,23,456 ± 535 to 1,19,837 ± 1089 years, which coincide with the Holocene and Eemian climatic optima, respectively. The stalagmite’s δ¹³C record closely resembles previously reported Chinese speleothem δ¹⁸O data. Thus it can be suggested that textural and geochemical results of the DY-1 reflect East Asian monsoon intensity, which is forced by summer insolation patterns in the northern hemisphere. Lighter carbon isotopic compositions, well-developed fibrous calcite crystals, and their relatively faster growth rate in the stalagmite sample are interpreted to reflect the warmest and wettest climate conditions of the Holocene and Eemian interglacials. Both climatic optima took place when insolation was decreasing from its maximum level, temperature in Greenland was highest, and sea level approached its maximum level. These climatic optima also coincide with decreasing Antarctic temperatures. Compared the DY-1 data to other proxies, it is suggested that the Holocene and Eemian climatic optima developed through a balance among boreal insolation, monsoon intensity, and sea level (also continental ice volume), which are the main climatic forcing factors in the northern hemisphere. These trends also follow the bi-polar seesaw mechanism as previously described.     

Test of the vibrational modelling for the λ-type transitions: Application to the α-β quartz transition

Vibrational modelling is at the present time the only known way to predict the heat capacities of the Earth's mantle minerals at high-pressure and high-temperature. To test the validity of this method for λ-type transitions, we have applied it to the α-β quartz transition (T ₀=846±1 K). Raman spectra of quartz were recorded up to 900 K. Measured frequency shifts of the α-quartz Raman modes were then used in conjunction with available high-pressure Raman data to calculate intrinsic mode anharmonicity, through the parameter a _i=(?Lnv_i/?T)_v. Vibrational modelling of the heat capacity at constant volume, Cv, and at constant pressure, Cp, including anharmonic corrections deduced from the a _i parameters, are compared to experimental data. Taking into account the soft-mode associated to the α-β quartz transition, the model reproduces the excess of Cp related to the transition. Then, this study confirms that detecting a soft-mode from vibrational data allows one to predict λ-type transitions. However, when modelling the thermodynamic properties, the contribution of a soft-mode cannot be established from spectroscopic data. Therefore, one needs first to determine this contribution in order to predict the heat capacities of Earth's mantle minerals displaying λ-type transitions. In α-quartz, this contribution has been determined as 0.007% of the total number of the optic modes in the model of the density of states.     

Identification of regions enriched or depleted in radioelements through nondistributional analysis of aerial radiometric data

Throughout the aerial radiometric reconnaissance survey portion of the U.S. Department of Energy's National Uranium Resource Evaluation (NURE) program, the identification of outliers (anomalies) was an important approach to locating regions with radio-element concentrations that are either higher or lower than expected. The method introduced herein to locate such regions involves three steps: selection of a high (or low) threshold for the variate of interest; use of the sample percentile to identify all points of interest; and movement of a window over the selected data to locate significant clusters of observations. These steps, applied to aerial radiometric ²¹⁴Bi (equivalent uranium) data collected over the Copper Mountain area in Wyoming, resulted in the identification of areas enriched in that variate.     

Thermal alteration experiments on organic matter in recent marine sediment—II. Isoprenoids

Several isoprenoid compounds were isolated from a heat-treated marine sediment in the southern California continental shelf (from Tanner Basin) which were not present in the original sediment. Among the compounds identified were: phytol, dihydrophytol, C₁₈-isoprenoid ketone, phytanic and pristanic acids, C₁₉- and C₂₀-monoolefins, and the alkanes 2,6,10-trimethylpentadecane, pristane and phytane. The significance and possible routes leading to these compounds is discussed.     

Thermal alteration experiments on organic matter in recent marine sediment—III. Aliphatic and steroidal alcohols

Recent sediments from Tanner Basin (off southern California) and Bandaras Bay (in Gulf of California) have been analyzed for normal, isoprenoid and steroidal alcohols using chromatographic (column, GLC, TLC), and spectroscopic (u.v., i.r., MS) methods, prior to and after heat-treatment (from 65 to 150°C). Normal saturated alcohols (C₁₄-C₂₄) and monounsaturated alcohols (C₂₂-C₂₄) were identified, as well as the isoprenoid alcohols, phytol and dihydrophytol.Two series of sterols (Δ⁵ and Δ⁷) were found in Tanner Basin, and Δ⁵-sterols and triterpenes, in Bandaras Bay sediment. Sterols from both sediments contained the corresponding stanols.     

Currents and sediment transport in the Mississippi Canyon and effects of Hurricane Georges

The temporal variability in currents, temperature, and particulate matter concentration were measured in the Mississippi Canyon axis where the thalweg was 300 m deep from May–July and August–November 1998 using current meters, thermographs, a light-scattering sensor, and sediment traps. Canyon sediments were sampled by coring and observed using an ROV video camera. Currents in the upper Mississippi Canyon generally oscillated up/down canyon with diurnal periodicity and were bottom-intensified. Mean current speed at 3.5 mab was approximately 8 cm s^?1 during both deployments, reaching maximum speeds of over 50 cm s^?1 under normal conditions. Based on current velocities, critical bed shear stress for resuspension of canyon-floor sediments was exceeded about 30% of the time during both deployments. In late September, Hurricane Georges passed 150 km NE of the study site, significantly intensifying current velocities, bed shear stress, resuspension, trap fluxes and temperature fluctuations. As the hurricane passed, maximum current speed reached 68 cm^?s and temperature decreased ～7 °C in less than two hours. Critical bed shear stress for sediment resuspension was exceeded approximately 50% of the time during the five days of hurricane influence. Further evidence for sediment resuspension was the five-fold (and perhaps 70–130 fold) increase in trap fluxes and compositional similarities between canyon surface sediment and material collected by traps.