Simultaneous use of geochemical and geophysical methods to characterise abandoned landfills

. Groundwater sampling and geophysical methods determined a serious contamination problem associated with refilled exploitation sites at the Cal Dimoni area, Llobregat delta, Barcelona, Spain. To characterise this process, hydrogeochemical analyses were performed and showed the following modifications to groundwater chemical composition: increasing pH values, changing redox conditions, significant increases in total organic carbon (TOC) and certain trace elements, and high groundwater conductivity values. Major ion content accumulations were found under the refilled area. In contrast, elements involved in the oxidation–reduction processes, such as iron, manganese and nitrates, clearly diminished. Electromagnetic prospecting methods were also performed and delineated the contamination plume extent. These methods also showed separate sources of contamination, one clearly related to the groundwater–refilled zone leachate interaction, another as a consequence of the manure–accumulation surface site. Geochemical and geophysical methods have shown similar results for locating groundwater contamination sources, and for determining leachate generation mechanisms and flow paths.     

Variabilité isotopique des précipitations sahéliennes à différentes échelles de temps à Niamey (Niger) entre 1992 et 1999 : implication climatiqueIsotopic variability of Sahelian rainfall at different time steps in Niamey (Niger, 1992–1999): climatic implications

The isotopic content of rainfall was measured in Niamey (Niger) over a period of eight years (1992–1999). Seasonal distribution of rainy events depends on the monsoon movement over the region. At the beginning and at the end of the rainy season, low rainfall, high temperatures and low relative humidity favour isotopic enrichment. In the middle of the rainy season, heavy rainfall, low temperatures and relative humidity close to saturation lead to isotopically depleted contents because of the mass effect; moreover, in the case of low rainfall, marked vertical convective development favours high altitude condensation. How far the Intertropical Front moves north, determines the quality of the rainy season and influences the isotopic contents. Thus the isotopic contents of rainfall are good climatic indicators. To cite this article: J.-D. Taupin et al., C. R. Geoscience 334 (2002) 43–50     

Moment Tensor Inversion of Regional Phases: Application to a Mine Collapse

—?The aim of our study consists of analyzing potentially non-double-couple seismic events recorded at regional distances. In order to define the nature of the seismic source, a moment tensor inversion is carried out as this method is general enough not to initially constrain the source mechanism. In this paper we present an application to a seismic event induced by a mine collapse which occurred near the town of Halle in Germany. Because of its induced nature, many parameters such as the location and geometry of this seismic source are known. This information allows us to test the influence of inadequate propagation modeling on the moment tensor obtained from the inversion. Green's functions have been computed with the reflectivity method in a flat layered medium, using the European model EurID (Du et? al., 1998; Dufumier et al., 1997). From the inversion of P-wave seismograms recorded by the German Regional Seismic Network will, we obtained a source time function which can be decomposed into two subevents. The first one has a large isotropic part and a deviatoric mechanism with near vertical nodal planes. No volume change is observed for the second subevent, but a deviatoric component opposite of the first one. The addition of S-waves does not change the results of the inversion which are stable. Surface waves were not used because of their poor dispersion curves. Based on the moment tensor obtained from these inversions, the physical process at the source is compatible with a large cavity collapse.     

河北平原水系密度与隐伏活动构造的关系

以1926年出版的比例尺为1：5万的顺直地形图作为基础图件，用地理信息系统技术对河北平原作水系密度计量分析，揭示隐伏在第四纪巨厚的沉积物之下活动构造的信息，研究结果证实水系线密度统计图与使用其它地球科学方法获得的成果，例如基底活动断块图，地貌类型图和第四纪厚度图都有很好的对应，特别与布格重力图对应更好，研究结果发现水系密度图与布格重力异常图在总体一致性较好的前提下，多处反向异常区均为近代强震发生的区域，提出这种地表水系密度统计研究的成果不仅可以揭示深部隐伏的活动构造，而且具有较明确的时间含义。     

Upper Oligocene-Lower Miocene shallowing-upwardlacustrine sequences controlled by periodic and non-periodic processes(Ebro Basin, northeastern Spain)

The lacustrine facies from two sections (Candasnos and Fraga) ofthe Oligocene-Miocene Torrente de Cinca lithostratigraphic Unit in thecentral part of the Ebro Basin (Spain) have been analysed to determine theinfluence of orbital parameters in lacustrine sedimentation. The unit ispredominantly composed of limestones and marls, and represents a shallowlacustrine freshwater system. The sedimentological features of the faciesstudied demonstrate that the lower part of the Candasnos section representsoffshore lacustrine subenvironments whereas the upper part, and the whole ofthe Fraga section, characterise marginal lacustrine areas. Series of stratalthickness variations of limestone, marl, and limestone/marl couplets fromboth sections have been analysed using spectral analysis. This shows thatinformation corresponding to periodic cycles only appears in the offshorefacies, that is to say, in the lower part of Candasnos section, and disappearsin the marginal facies where non-periodic cycles exist. Furthermore, thespectral analysis of the offshore facies highlights the existence of a peak inthe power spectrum with a period of around 7 (6.8 to 7.8) that can berecognised in the field as shallowing-upward lacustrine sequences.Magnetostratigraphic data from the Candasnos section allow us to establish atime span of 2,808 years for the limestone/marl couplet from the lower partof this section, and between 19,000 and 22,000 years for the periodic cycleidentified, thus representing the climatic precession cycle. Shallowingsequences from marginal areas do not correspond with any periodiccycle.     

Tectonique transpressive en terre Adélie au Paléoprotérozoı̈que (Est Antarctique)Palaeoproterozoic transpression in Terre Adélie (East Antarctica)

The Palaeoproterozoic units of Terre Adélie show two types of structural domains associated with HT–LP metamorphic conditions: domes and NS–N340° striking vertical shear zones. Shear zones reflect dextral transpressive motions. Domes reflect sub-vertical shortening and principal stretching subparallel to shear zones. They could partly result from longitudinal flow coeval with transpression. Deformations are comparable to those described along the eastern and western boundaries of the Archean Gawler Craton (South-East Australia), which underlines the continuity between these two areas before opening of the Austral Ocean. To cite this article: A. Pelletier et al., C. R. Geoscience 334 (2002) 505–511.     

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.     

Permeability-porosity Relationships in Rocks Subjected to Various Evolution Processes

— It is well known that there is no “universal” permeability-porosity relationship valid in all porous media. However, the evolution of permeability and porosity in rocks can be constrained provided that the processes changing the pore space are known. In this paper, we review observations of the relationship between permeability and porosity during rock evolution and interpret them in terms of creation/destruction of effectively and non-effectively conducting pore space. We focus on laboratory processes, namely, plastic compaction of aggregates, elastic-brittle deformation of granular rocks, dilatant and thermal microcracking of dense rocks, chemically driven processes, as a way to approach naturally occurring geological processes. In particular, the chemically driven processes and their corresponding evolution permeability-porosity relationships are discussed in relation to sedimentary rocks diagenesis.