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921.
Drop calorimetric measurements of HT-H273 are reported for glassy and liquid albite and potassium tetrasilicate for the temperature interval 600–1500 K. Analysis of these observations as well as data for 13 other stable and supercooled silicate liquids suggests strongly that the isobaric heat capacities of stable and supercooled liquids are equal and thus temperature independent. Available evidence indicates that the isochoric heat capacities of liquid alkali silicates are also temperature independent within present experimental uncertainties. 相似文献
922.
923.
Pierre Schiano Bernard Bourdon Robert Clocchiatti Dominique Massare Maria E. Varela Yan Bottinga 《Earth and Planetary Science Letters》1998,160(3-4):537-550
The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO2 and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO2 and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO2 for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr2O3 and poorer in SiO2, K2O, Na2O, Al2O3 and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO2 >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO2 and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO2 and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated. 相似文献
924.
925.
Jing Wu Jian Yin Yonghong Hao Yan Liu Yonghui Fan Xueli Huo Youcun Liu Tian‐Chyi J. Yeh 《水文研究》2015,29(13):2855-2866
The traditional hydrological time series methods tend to focus on the mean of whichever variable is analysed but neglect its time‐varying variance (i.e. assuming the variance remains constant). The variances of hydrological time series vary with time under anthropogenic influence. There is evidence that extensive well drilling and groundwater pumping can intercept groundwater run‐off and consequently induce spring discharge volatility or variance varying with time (i.e. heteroskedasticity). To investigate the time‐varying variance or heteroskedasticity of spring discharge, this paper presents a seasonal autoregressive integrated moving average with general autoregressive conditional heteroskedasticity (SARIMA‐GARCH) model, whose the SARIMA model is used to estimate the mean of hydrological time series, and the GARCH model estimates its time‐varying variance. The SARIMA‐GARCH model was then applied to the Xin'an Springs Basin, China, where extensive groundwater development has occurred since 1978 (e.g. the average annual groundwater pumping rates were less than 0.20 m3/s in the 1970s, reached 1.20 m3/s at the end of the 1980s, surpassed 2.0 m3/s in the 1990s and exceeded 3.0 m3/s by 2007). To identify whether human activities or natural stressors caused the heteroskedasticity of Xin'an Springs discharge, we segmented the spring discharge sequence into two periods: a predevelopment stage (i.e. 1956–1977) and a developed stage (i.e. 1978–2012), and set up the SARIMA‐GARCH model for the two stages, respectively. By comparing the models, we detected the role of human activities in spring discharge volatility. The results showed that human activities caused the heteroskedasticity of the Xin'an Spring discharge. The predicted Xin'an Springs discharge by the SARIMA‐GARCH model showed that the mean monthly spring discharge is predicted to continue to decline to 0.93 m3/s in 2013, 0.67 m3/s in 2014 and 0.73 m3/s in 2015. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
926.
If the upstream boundary conditions are prescribed based on the incident wave only, the time-dependent numerical models cannot effectively simulate the wave field when the physical or spurious reflected waves become significant. This paper describes carefully an approach to specifying the incident wave boundary conditions combined with a set sponge layer to absorb the reflected waves towards the incident boundary. Incorporated into a time-dependent numerical model, whose governing equations are the Boussinesq-type ones, the effectiveness of the approach is studied in detail. The general boundary conditions, describing the down-wave boundary conditions are also generalized to the case of random waves. The numerical model is in detail examined. The test cases include both the normal one-dimensional incident regular or random waves and the two-dimensional oblique incident regular waves. The calculated results show that the present approach is effective on damping the reflected waves towards the incident wave boundary. 相似文献
927.
YANMin-hua DENGWei CHENPan-qin LIANGLi-qiao 《中国地理科学(英文版)》2004,14(4):320-325
The characteristics of zonal anomaly and change rule of temporal distribution of annual precipitation in the northeastern China are revealed in this paper with EOF (Empirical Orthogonal Function) and REOF (Rotated Empirical Orthogonal Function) methods and results are drawn in the standard relief maps with GIS technology for practical application. Data used in the study were obtained from 208 meteorological stations over the northeastern China from 1961 to 2001. EOF results show that the first 3 loading vectors could give entire spatial anomaly structure of annual precipitation. In the Northeast Plain including the Songneng Plain and the Liaohe Plain, there is a regional compatibility (whether wet or dry) of annual precipitation change and this precipitation pattern has occurred since the late 1980s to the present. There also exist annual precipitation patterns of wet (or dry) in south and dry (or wet) in north and wet (or dry) in east and dry (or wet) in west. REOF results display 8 principal precipitation anomaly areas by the first 8 rotated loading vectors: the west plain, the Liaodong hills, the Sanjiang Plain, the Liaoxi hills,the Changbai Mountains, the Hulun Buir Plateau, the southwest plateau and the Liaodong Peninsula. 相似文献
928.
A New Feature Vector Using Selected Line Spectra for Pulsar Signal Bispectrum Characteristic Analysis and Recognition 总被引:1,自引:0,他引:1
Zhen-Hua Xie Lu-Ping XU Guang-Ren Ni Yan Wang 《中国天文和天体物理学报》2007,7(4):565-571
Average pulse profiles of pulsar signals are analyzed using the bispectrum tech-nique. The result shows that there are nonlinear phase couplings between the two frequency axes of the bispectrum charts, which indicate nonlinear factors in the generation and prop-agation of pulsar signals. Bispectra can be used as feature vectors of pulsar signals because of their being translation invariant. A one-dimension selected line spectrum algorithm for ex-tracting pulsar signal characteristic is proposed. Compared with selected bispectra, the pro-posed selected line spectra have the maximum interclass separability measurements from the point of view of the whole one-dimension feature vector. Recognition experiments on several pulsar signals received at several frequency bands are carried out. The result shows that the selected line spectrum algorithm is suitable for extracting pulsar signal characteristics and has a good classification performance. 相似文献
929.
李艳 《成都信息工程学院学报》2007,22(2):274-277
在G-凸空间内得到了一些新的连续选择定理,并利用连续选择定理证明了非紧G-凸空间内及乘积G-凸空间内的重合点定理.这些定理改进并推广了最近文献中的一些已知结果. 相似文献
930.
淮河源区中更新世黄土堆积的元素地球化学特征及其古气候意义 总被引:1,自引:1,他引:0
利用地球化学元素分析方法,对淮河源区中更新世黄土、古土壤剖面含有的化学元素及多种化学元素指标进行了分析。研究表明:区内中更新世以来的气候变化,主要以湿热气候为主,淋溶及氧化作用较强;表现在气温上HT-1~HT-3的气温较低,HT-4~HT-7的气温高,HT-8的气温又相对较低,其变化趋势表现为中更新世经历了从早期寒冷转湿热转温干,中期凉干转暖湿到晚期温湿转暖湿。 相似文献