Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil

Effect of chemical fertilizers (urea, NH₄Cl, Ca(NO₃)₂, KCl and KH₂PO₄) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure, it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil. Applying urea (CO(NH₂)₂) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH₄Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH₂)₂ raised the soil pH from 4.51 to 4.96, whereas NH₄Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH₂PO₄ reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual (RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH₄Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH₂PO₄ decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil.     

东营市东营区努力开创土地开发整理工作新局面

东营区是黄河三角洲中心城市一东营市的中心区,我国第二大油田一胜利油田所在地.近年来,东营区随着城市化进程的加快,建设用地不断增多,保持耕地总量动态平衡压力很大.为确保全区耕地总量动态平衡,东营区创新机制,规范管理,积极探索增加耕地的有效途径,取得了显著成效.1999年以来,全区非农业建设占用耕地551.6 hm2,而同期增加有效耕地3 660.22 hm2,实现了耕地总量的动态平衡.     

淮河流域大气环流型在冬季气温预测中的应用

应用Lamb-Jenkinson大气环流分型方法,根据由1970—2012年NCEP/NCAR逐日海平面气压场计算得到的环流指数,对淮河流域的环流进行分型。分析了冬季主要环流型和气温的分布特征及两者的联系,并以环流指数和主要环流型为预测因子,结合经验正交函数分解(EOF)方法和逐步回归方法,建立了淮河流域冬季气温距平的预测模型。结果表明,淮河流域冬季的主要环流型是东北风型、东风型、反气旋环流型以及东北风、东风配合下的反气旋性环流型,划分的环流型符合实际情况,这些环流型具有显著的年际和年代际变化特征。通过对预测模型进行后报试验和独立预报试验,表明该模型具有一定的预报技巧。     

乍得Doseo盆地烃源岩评价与油源分析

中非裂谷系Doseo盆地是中石油海外重点勘探区块之一,目前油气勘探程度极低.本文基于Ximenia-1井和Kapok-1井131件岩屑和8件原油样品的系统有机地球化学分析,明确了研究区烃源岩生烃潜力和油气来源.由于受中非构造剪切带活动的影响,在Doseo盆地下白垩统Doba组、Kedeni组和Mangara组发育了半深湖—深湖相的优质烃源岩,其累计厚度可达500 m,烃源岩有机质丰度高(TOC＞3％),有机质类型好(Ⅱ1～Ⅰ型),但有机质成熟度整体偏低(钻遇烃源岩R.介于0.4％～0.8％之间),仅局部达到生排烃高峰阶段.分子标志化合物对比分析表明:原油成熟度普遍高于钻遇烃源岩成熟度,现有油气发现主要源自凹陷中Kedeni组下部或Mangara组上部成熟优质烃源岩,Doba组烃源岩未成熟,油气贡献有限.该研究成果有助于指导下一步油气勘探,助推油气规模储量发现.     

登陆孟加拉湾风暴结构个例分析与数值模拟

采用NCEP-NCAR再分析资料,分析了2006年4月29日登陆缅甸并造成云南省强降水过程的孟加拉湾风暴结构。并且利用美周新一代中尺度WRF（weather Researchand Forecast）模式对2006年4月28～30日云南强降水过程进行了数值模拟研究。结果表明：孟加拉湾风暴登陆前后结构具有明显变化,从基本对称结构演变为非对称结构,WRF模式较好地模拟出盂加拉湾风暴登陆前后环流场特征和风暴移动路径以及造成云南强降水雨带的分布特征。     

WRF模式三维变分中背景误差协方差估计

利用WRF模式2008年5-10月逐日预报结果,通过NMC方法进行背景误差协方差(B)估计.给出其结构特征,进行单点数值试验,并利用不同B进行1个月的数值模拟试验,检验模拟降水效果.结果表明:通过单点数值试验验证估算的B结构合理.不同的B,资料同化过程差别较大,应用重新统计的B,同化效率更高,目标函数收敛更稳定.模式模...     

海盐气溶胶和硫酸盐气溶胶在云微物理过程中的作用

利用大气气溶胶和云分档模式研究海盐气溶胶和硫酸盐气溶胶在云微物理过程中的作用, 计算结果表明:云中液态水含量随高度的分布并不随海盐、硫酸盐的数目以及云团上升速度的变化而变化; 随着云滴数目的增加, 云滴的有效半径会减小; 硫酸盐对云滴数目影响起主导作用, 海盐在水汽相对充足情况下增加了云滴数目, 在水汽相对不足的情况下减少了云滴数目; 硫酸盐粒子浓度特别强的情况下 (人类活动污染比较严重时), 如果水汽相对不足, 云滴数目会明显小于硫酸盐粒子浓度; 而海盐粒子的存在, 加剧了水汽的供应不足, 从而可以在很大程度上进一步降低云滴数目。也就是说, 在有些情况下, 如果不考虑海盐气溶胶的作用, 硫酸盐气溶胶对云特性的影响会被过高估计。     

农田尺度土壤水分的监测

根据田间试验实测资料分析了田间土壤水分的空间变化特征和时间动态变化,探索了监测农田水分变化时如何确定其合理的取样数目,讨论了农田尺度的土壤水分应如何监测,为节水灌溉,提高田间用水管理水平提供科学依据。