沉积物孔隙毛细管压力与甲烷水合物饱和度关系研究

To better understand the relationship between the pore capillary pressure and hydrate saturation in sediments, a new method was proposed. First, the phase equilibria of methane hydrate in fine-grained silica sands were measured. As to the equilibrium data, the pore capillary pressure and saturation of methane hydrate were calculated. The results showed that the phase equilibria of methane hydrates in fine-grained silica sands changed due to the depressed activity of pore water caused by the surface group and negatively charged characteristic of silica particles as well as the capillary pressure in small pores together. The capillary pressure increased with the increase of methane hydrate saturation due to the decrease of the available pore space. However, the capillary-saturation relationship could not yet be described quantitatively because of the stochastic habit of hydrate growth.     

黄海中南部近岸海域春季鱼类浮游生物群落空间格局研究

根据2015年春季在黄海中南部近岸海域进行的鱼类浮游生物大型浮游生物网水平拖网数据,采用生态多样性指数和多元统计分析等方法,研究了该海域鱼类浮游生物的种类组成和群落空间格局及其与环境因子的关系。结果表明,本次调查共采集到鱼类浮游生物35种,其中鱼卵21种,仔稚鱼23种。鱼类浮游生物隶属于8目18科34属,优势种为鳀（Engraulis japonicus）、鲬（Platycephalus indicus）、鱼衔属（Callionymus spp.）和小黄鱼（Pseudosciaena polyactis）。其中,鳀和鱼衔属主要分布于海州湾渔场海域,鲬主要分布于吕泗渔场海域,小黄鱼多分布于吕泗渔场北部海域。生态类型包括半咸水型、沿岸型和近海型种类。聚类分析表明,鱼类浮游生物群落可划分为以鱼衔属、鳀为优势种的站位组A（主要分布于海州湾海域）、以小黄鱼、黄鲫（Setipinna taty）等为优势种的站位组B（主要位于江苏沿岸海域）和以鲬为优势种的站位组C（主要位于江苏沿岸-近海海域）,以站位组B的群落物种多样性指数和均匀度指数最高。各站位组的鱼类浮游生物的生态类型和适温类型组成不同,这与其所处的海域生境有关。典范对应分析（CCA）表明,影响春季黄海中南部鱼类浮游生物群落空间结构的主要环境因子为水深和表层温度。同时也受洋流、底质类型等多种因素的综合影响。研究结果初步揭示了黄海中南部近岸海域鱼类浮游生物群落的空间格局,可为今后科学制定该海域水产种质资源保护区、资源量化管理等资源养护管理措施提供科学依据与技术支撑。     

Optical properties and surface energy flux of spring fast ice in the Arctic

Over the past decades, sea ice in the polar regions has been significantly affecting local and even hemispheric climate through a positive ice albedo feedback mechanism. The role of fast ice, as opposed to drift ice, has not been well-studied due to its relatively small coverage over the earth. In this paper, the optical properties and surface energy balance of land fast ice in spring are studied using in situ observations in Barrow, Alaska. The results show that the albedo of the fast ice varied between 0.57 and 0.85 while the transmittance increased from 1.3×10?3 to 4.1×10?3 during the observation period. Snowfall and air temperature affected the albedo and absorbance of sea ice, but the transmittance had no obvious relationship with precipitation or snow cover. Net solar shortwave radiation contributes to the surface energy balance with a positive 99.2% of the incident flux, with sensible heat flux for the remaining 0.8%. Meanwhile, the ice surface loses energy through the net longwave radiation by 18.7% of the total emission, while the latent heat flux accounts for only 0.1%. Heat conduction is also an important factor in the overall energy budget of sea ice, contributing 81.2% of the energy loss. Results of the radiative transfer model reveal that the spectral transmittance of the fast ice is determined by the thickness of snow and sea ice as well as the amount of inclusions. As major inclusions, the ice biota and particulates have a significant influence on the magnitude and distribution of the spectral transmittance. Based on the radiative transfer model, concentrations of chlorophyll and particulate in the fast ice are estimated at 5.51 mg/m2 and 95.79 g/m2, which are typical values in the spring in Barrow.     

An experimental study on microscopic characteristics of gas-bearing sediments under different gas reservoir pressures

Gas-bearing sediments are widely distributed in five continents all over the world. Most of the gases exist in the soil skeleton in the form of discrete large bubbles. The existence of gas-phase may increase or decrease the strength of the soil skeleton. So far, bubbles’ structural morphology and evolution characteristics in soil skeleton lack research, and the influence of different gas reservoir pressures on bubbles are still unclear. The micro characteristics of bubbles in the same sediment sample were studied using an industrial CT scanning test system to solve these problems. Using the image processing software, the micro variation characteristics of gas-bearing sediments in gas reservoir pressure change are obtained. The results show that the number and volume of bubbles in different equivalent radius ranges will change regularly under different gas reservoir pressure. With the increase of gas reservoir pressure, the number and volume of tiny bubbles decrease. In contrast, the number and volume of large bubbles increase, and the gas content in different positions increases and occupies a dominant position, driving the reduction of pore water and soil skeleton movement.     

Managing coastal area resources by stated choice experiments

In many coastal regions, oil spills can be considered as one of the most important and certainly the most noticeable forms of marine pollution. Efficient contingency management responding to oil spills on waters, which aims at minimizing pollution effects on coastal resources, turns out to be critically important. Such a decision making highly depends on the importance attributed to different coastal economic and ecological resources. Economic uses can, in principal, be addressed by standard measures such as value added. However, there is a missing of market in the real world for natural goods. Coastal resources such as waters and beach cannot be directly measured in money terms, which increases the risk of being neglected in a decision making process. This paper evaluates these natural goods of coastal environment in a hypothetical market by employing stated choice experiments. Oil spill management practice in German North Sea is used as an example. Results from a pilot survey show that during a combat process, beach and eider ducks are of key concerns for households. An environmental friendly combat option has to be a minor cost for households. Moreover, households with less children, higher monthly income and a membership of environmental organization are more likely to state that they are willing to pay for combat option to prevent coastal resources from an oil pollution. Despite that choice experiments require knowledge of designing questionnaire and statistical skills to deal with discrete choices and conducting a survey is time consumed, the results have important implications for oil spill contingency management. Overall, such a stated preference method can offer useful information for decision makers to consider coastal resources into a decision making process and can further contribute to finding a cost-effective oil preventive measure, also has a wide application potential in the field of Integrated Coastal Zone Management (ICZM).     

Comparisons of ZnO codoped by group IIIA elements (Al, Ga, In) and N: a first-principle study

The electronic structures and effective masses of the N mono-doped and Al-N, Ga-N, In-N codoped ZnO system have been calculated by a first-principle method, and comparisons among different doping cases are made. According to the results, the impurity states in the codoping cases are more delocalised compared to the N mono-doping case, which means a better conductive behaviour can be obtained by codoping. Besides, compared to the Al-N and Ga-N codoping cases, the hole effective mass of In-N codoped system is much smaller, indicating the p-type conductivity can be more enhanced by In-N codoping.     

Dominant climate factors influencing the Arctic runoff and association between the Arctic runoff and sea ice

By using the Arctic runoff data from R-ArcticNET V4.0 and ArcticRIMS, trends of four major rivers flowing into the Arctic Ocean, whose climate factor plays an important role in determining the variability of the Arctic runoff, are investigated. The results show that for the past 30 years, the trend of the Arctic runoff is seasonally dependent. There is a significant trend in spring and winter and a significant decreasing trend in summer, leading to the reduced seasonal cycle. In spring, surface air temperature is the dominant factor influencing the four rivers. In summer, precipitation is the most important factor for Lena and Mackenzie, while snow cover is the most important factor for Yenisei and Ob. For Mackenzie, atmospheric circulation does play an important role for all the seasons, which is not the case for the Eurasian rivers. The authors further discuss the relationships between the Arctic runoff and sea ice. Significant negative correlation is found at the mouth of the rivers into the Arctic Ocean in spring, while significant positive correlation is observed just at the north of the mouths of the rivers into the Arctic in summer. In addition, each river has different relationship with sea ice in the eastern Greenland Sea.     

折射/谐衍射红外双波段成像光谱仪系统研究

为了获取足够的目标信息,充分利用中波红外和长波红外的光谱信息,建立了谐衍射中、长波红外超光谱成像系统.利用谐衍射元件独特的色散特性,将谐衍射透镜应用于中、长波红外超光谱成像系统中,使系统在中波红外3.7—4.8 μm和长波红外8—12 μm的2个红外大气窗口内获取数百个光谱图像.设计结果表明,中波红外波段,在18对线/mm处光学系统的调制传递函数(MTF)大于0.55;长波红外波段,在13对线/mm处光学系统的MTF大于0.5;光学系统的衍射环绕能,在中波红外波段30 μm半径范围内大于85%,在长波红外     

Last glacial terrestrial vegetation record of leaf wax n-alkanols in the northern South China Sea: Contrast to scenarios from long-chain n-alkanes

Long-chain n-alkanols and n-alkanes in core sediments from the northern South China Sea (SCS) were measured to make a comparison during terrestrial vegetation reconstruction from ~42 ka to ~7 ka. The results showed that terrestrial vegetation record from long-chain n-alkanes matched well with previous studies in nearby cores, showing that more C₄ plants developed during the Last Glacial Maximum (LGM) and C₃ plants dominated in the interglacial period. However, these scenarios were not revealed by terrestrial vegetation reconstruction using long-chain n-alkanols, which showed C₃ plant expansion during the LGM. The discrepancy during the interglacial period could be attributed to the aerobic degradation of functionalized long-chain n-alkanols in the oxygen-rich bottom water, resulting in poor preservation of terrestrial vegetation signals. On the other hand, the different advantages of functionalized n-alkanols and non-functional n-alkanes to record local and distal vegetation signals, respectively, may offer a potential explanation for the contradiction during the LGM when the SCS was characterized by low-oxygen deep water. Nevertheless, large variations on n-alkyl lipid compositions in C₃/C₄ plants could play a part in modulating sedimentary long-chain n-alkanols and n-alkanes toward different vegetation signals, thereby suggesting that caution must be taken in respect to the terrestrial vegetation reconstruction using long-chain n-alkanes and long-chain n-alkanols.