赣南地区寒武纪高滩组碎屑锆石U-Pb年龄和Hf同位素特征及地质意义

寒武纪高滩组广泛分布于赣南武功山-雩山地区,主体为一套浅变质砂岩夹板岩的复理石建造。为分析其物源,并对源区地壳生长和构造演化提供约束,本文对采自高滩组的变长石石英杂砂岩进行了LA-ICP-MS碎屑锆石U-Pb年代学和Hf同位素研究。锆石U-Pb年龄数据显示2 500 Ma、1 100~900 Ma和900~700 Ma 3个主要年龄峰值。2 500 Ma的年龄峰值代表了新太古代末期—古元古代的古陆核生长事件。1 100~900 Ma和900~700 Ma两个峰最显著,表明Rodinia超大陆聚合裂解在华南地区的响应,为该区寒武纪地层提供了主要物源。此外,3 003 Ma锆石年龄的捕获说明,华夏地块可能存在太古宙地壳基底。Hf同位素数据表明,源区锆石结晶多为古老地壳组分部分熔融产生的岩浆。结合锆石年龄数据分析认为,华南地区存在强烈的新元古代岩浆活动,该时期岩浆活动主要是古老地壳物质的再循环。     

临涣矿区界沟煤矿工程地质条件研究

根据主采煤层顶底板岩体岩性类型及结构面发育程度对其稳定性进行了评价：72煤层顶板以中等稳定一不稳定类型为主,82煤层顶板以中等稳定类型为主,10煤层顶板以中等稳定一稳定类型为主。在大量统计见煤点硬质岩百分含量（k值）的基础上,结合顶板岩石的单轴抗压强度,对各主采煤层顶底板工程地质类型进行了划分：72煤层以一、二类顶板为主,82、10煤层均以五类顶板为主。综合评价该矿工程地质条件为中等即Ⅲ类二型。根据研究成果,指出该矿在采掘过程中可能出现的工程地质问题,并依此提出了治理建议。     

湖南香花岭复式碱长花岗岩体侵入期次关系的识别

香花岭碱长花岗岩为一复式岩体。不同期次侵入体之间的接触关系、白色和绿色含铍条纹岩以及磁铁矿条纹岩与不同期次侵入体之间的对应关系、通天庙、塘官铺、太平和新风不同矿化组合与不同期次侵入体之间的成因联系以及遥感图像中的环形构造特点和差异明显的Rb-Sr同位素等时年龄表明该岩体是两期四次碱长花岗质岩浆侵入作用的产物,燕山早期的三次岩浆侵入与本区矿化关系密切;而燕山晚期的一次岩浆侵入与矿化无关。上述认识可对矿区的某些地质问题作出合理的解释。     

用自组织人工神经网络分类,识别矿物

作者运用三维Ｔ．Ｋｏｈｏｎｅｎ自组织人工神经网络对我国沉积碳酸盐型锰矿中菱锰矿进行分类、识别。所选研究实例中，识别成功率达１００％．结果表明，该网络性能良好，可望成为矿物识别的有效手段。     

Magnetic susceptibility of ultrahigh pressure eclogite: The role of retrogression

Retrograde metamorphism played the dominant role in changing the low-field rock magnetic properties and density of 198 specimens of variably retrograded eclogites from the main borehole of the Chinese Continental Scientific Drilling Project (CCSD) and from surface outcrops in the Donghai area in the southern part of the Sulu UHP belt, China. Bulk magnetic susceptibility (κ) of unretrogressed UHP eclogite is controlled by whole-rock chemical composition and ranges from 397 to 2312 μSI with principal magnetic susceptibility carrying minerals paramagnetic garnet, omphacite, rutile and phengite. Partially retrograded eclogites show large variations in magnetic susceptibility between 804 and 24,277 μSI, with high mean magnetic susceptibility values of 4372 ± 4149 μSI caused by appreciable amounts of Fe-Ti oxide minerals such as magnetite, ilmenite and/or titanohematite produced by retrograde metamorphic reactions. Completely retrograded eclogites have lower susceptibilities of 1094 ± 600 μSI and amphibolite facies mineral assemblages lacking high magnetic susceptibility minerals. Jelínek's corrected anisotropy (P_j) of eclogites ranges from 1.001 to 1.540, and shows a positive correlation with low-field magnetic susceptibility (κ). Arithmetic mean bulk density (ρ) shows a steady decrease from 3.54 ± 0.11 g/cm³ (fresh eclogite) to 2.98 ± 0.06 g/cm³ (completely retrograded eclogite). Retrograde metamorphic changes in mineral composition during exhumation appear to be the major factor causing variations in low field magnetic susceptibility and anisotropy. Retrograde processes must be taken into account when interpreting magnetic surveys and geophysical well logs in UHP metamorphic terranes, and petrophysical properties such as density and low-field magnetic susceptibility could provide a means for semi-quantifying the degree of retrogression of eclogite during exhumation.     

Calcified roasting-acid leaching process of vanadium from low-grade vanadium-containing stone coal

The low-grade vanadium-containing stone coal used in this experiment was collected from Wuxi Coun- try, Chongqing City, China. The experiment focused on the vanadium recovery from roasted residue through opti- mizing the process conditions of an effective and environmentally-friendly technology, named calcified roast- ing-sulfuric acid leaching technology. By single-factor experiments and orthogonal experiments, the effects of roast- ing temperature, roasting time, sulfuric acid concentration and leaching time on the leaching ratio of vanadium were analyzed. The results showed that the leaching ratio of vanadium reached 85.5% under the proper technological con- ditions of roasting temperature=950℃, roasting time=4 h, 40% concentration of sulfuric acid and leaching time=6 h.     

斜方辉石的反演畴结构对其衍射效应的影响

斜方辉石内部存在着众多的相邻间呈反演关系的(100)晶畴。这些晶畴的存在使斜方辉石的K为奇数的okl衍射之强度明显减弱,且参与衍射的晶畴的数目越多,其减弱的程度也就越大。这一现象在一定程度上掩盖了斜方辉石P2_(1ca)的真实对称性。与X射线衍射相比,利用电子衍射来研究斜方辉石的空间群类型具有明显的优越性。     

利用膨润土与工业废渣制轻质保温材料

本文介绍了利用膨润土、钙质造纸废渣制备轻质保温材料的研究,分析了膨润土在轻质保温材料制备中的作用,优选出制备轻质保温材料的配方和工艺。该材料的导热系数为０ ．１７１ Ｗ／ｍ·Ｋ,抗压强度约为９ ．３７ ｋｇ／ｃｍ２ ,容重为０ ．４９ ｇ／ｃｍ３ 。     

新疆锰矿成矿规律研究

最近新疆西昆仑地区锰矿勘查实现重大突破,伴随大型优质锰矿的发现和勘查,锰已成为新疆区域优势金属矿种之一。通过系统收集资料,总结新疆锰矿成矿类型及区域时空规律。指出寒武纪、二叠纪、石炭纪是新疆锰矿成矿的3个重要时代,西昆仑-昆盖山裂谷带、塔里木陆块北部边缘活动带是新疆锰矿成矿的重要构造单元,以海相沉积型锰矿为主要成矿类型。同时,对比中国南方重要锰矿成矿特征,指出新疆奥尔托喀讷什、穆呼锰矿与广西下雷超大型锰矿在地质构造背景、成矿时代、含矿建造、矿石类型等方面均有相似之处,在成矿空间上具某种“亲缘性”。新疆西昆仑穆呼-玛尔坎苏锰矿带具超大型锰矿成矿潜力。     

Cs and Cl NMR spectroscopy and molecular dynamics modeling of Cs and Cl complexation with natural organic matter

Interaction of dissolved aqueous species with natural organic matter (NOM) is thought to be important in sequestering some species and enhancing the transport of others, but little is known about these interactions on a molecular scale. This paper describes a combined experimental ¹³³Cs and ³⁵Cl nuclear magnetic resonance (NMR) and computational molecular dynamics (MD) modeling study of the interaction of Cs⁺ and Cl⁻ with Suwannee River NOM. The results provide a detailed picture of the molecular-scale structure and dynamics of these interactions. Individual NOM molecules are typically hundreds to thousands of Daltons in weight, and on the molecular scale their interaction with small dissolved species can be investigated in ways similar to those used to study the interaction of dissolved aqueous species with mineral surfaces. As for such surface interactions, understanding both the structural environments and the dynamics over a wide range of frequencies is essential. The NMR results show that Cs⁺ is associated with NOM at pH values from 3.4 ± 0.5 (unbuffered Suwannee River NOM solution) to 9.0 ± 0.5. The extent of interaction increases with decreasing CsCl concentration at constant pH. It also decreases with increasing pH at constant CsCl concentration due to pH-dependent negative structural charge development on the NOM caused by progressive deprotonation of carboxylic and phenolic groups. The presence of NOM has little effect on the ¹³³Cs chemical shifts, demonstrating that its local coordination environment does not change significantly due to interaction with the NOM. Narrow, solution-like line widths indicate rapid exchange of Cs⁺ between the NOM and bulk solution at frequencies of >10² Hz. The MD simulations support these results and show that Cs⁺ is associated with the NOM principally as outer sphere complexes and that this interaction does not reduce the Cs⁺ diffusion coefficient sufficiently to cause NMR line broadening. The ³⁵Cl NMR data and the MD results are consistent in demonstrating that there is no significant complexation between Cl⁻ and NOM in the pH range investigated, consistent with negative structural charge on the NOM.