Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS）,由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度,在污染物的环境行为研究中得到广泛应用,GC-MS法的定性效果好,但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况,结果显示,即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度,同时保证检测灵敏度,实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法,最终选择中等极性的TG-35MS为第一色谱柱,非极性的（DB-1）为第二色谱柱,将鲜样与无水硫酸钠混合均匀后,以正己烷-丙酮（1：1,V/V）为提取剂进行索氏提取,采用全二维气相色谱-电子捕获检测器进行检测,外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系,相关系数均大于0.995,检出限为0.02~0.17μg/kg。用标准加入法进行回收实验,测得回收率为80.7%~103.5%,测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合,在保证检测灵敏度的同时增加了峰容量,有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式）,本方法检出限显著降低,且操作简单,可为复杂基质样品中的痕量超痕量检测提供参考。     

煤和干酪根纳米结构的研究进展

对煤和干酪根结构的认识得益于技术和方法的不断创新。基于各种方法,先后建立了多个煤和干酪根的结构模型,但至今没有得到普遍认可。原子力显微镜(AFM)可以实时、实空间、原位成像,可以观察单个原子层的局部表面结构,直接观察表面缺陷、表面重构、表面吸附体的形态和位置以及表面扩散等动态过程。在对图像的分析中,AFM超越了传统仪器单纯平面成像的功能,可提供样品表面动态三维图像和用于分析的定量化信息。通过纳米技术,实现了原子级的分辨率的观察,揭示了煤和干酪根聚集态分子和纳米级孔隙的形态、大小、结构及相互间的空间排列特征,显示出在煤和干酪根结构研究中的巨大潜力。纳米技术为煤和干酪根结构的基础研究工作拓展了新的途径,也为非常规油气的勘探开发和煤炭的二次转化研究提供了科学依据。     

化探背景与异常划分中的C型转换法

化学背景与异常在统计学上的差异同时表现在浓度和变差两个方面。在划分背景与异常时,把这两方面信息提取出来并作显化处理,使背景与异常的差别更大,以利划分,这就是Ｃ型转换的基本思想。介绍了Ｃ型转换法的基本原理及其在条件模拟和实际金矿区中的应用。     

胜利油田车镇凹陷沙河街组二、三段沉积相

车镇凹陷古近系沙河街组三段上亚段—二段下亚段是较为典型的深断陷型三级层序。层序的发育主要受控于幕式断陷作用,可进一步划分出低位体系域、湖侵体系域和高位体系域。通过岩心观察、薄片镜下鉴定、粒度分析、古生物及遗迹化石分析,并综合利用测井曲线和地震相特征,认为该时期主要发育有扇三角洲、三角洲、近岸水下扇、湖底扇、滨浅湖滩坝等骨架砂体相,以及滨浅湖、半深湖—深湖等沉积相及其亚相。综合考虑物源特征、沉积环境、沉积体系平面展布以及生、储、盖组合关系,认为有利的沉积相带主要是三角洲、扇三角洲前缘、湖底扇、近岸水下扇的中扇和外扇以及滨浅湖中发育的滩坝和砂坝。     

Investigating soil thermodynamic parameters of the active layer on the northern Qinghai-Tibetan Plateau

The soil thermodynamic parameters, including thermal conductivity, diffusivity and volumetric capacity within the active layer on the northern Tibetan Plateau, were calculated using the measured data of soil temperature gradient, heat flux, and moisture at four stations from October 2003 to September 2004. The results showed that the soil thermodynamic parameters exhibited clear seasonal fluctuation. The thermal conductivity and diffusivity in summer and autumn at Beiluhe, Kexinling, and Tongtianhe were larger than those in winter. The volumetric thermal capacity causes an opposite change; it was larger in autumn and winter than in summer. In spring, the soil thermal conductivity at the Kekexili station was larger than that in summer. Generally, fine-grained soils and lower saturation degrees in the topsoil might be a reason for the lower soil thermal conductivity in winter. For a given soil, soil moisture was the main factor influencing the thermodynamic parameters. The unfrozen water content that existed in frozen soils greatly affected the soil thermal conductivity, whose contribution rate was estimated to be 55 %. The thermodynamic parameters of frozen soils could be expressed as a function of soil temperature, volumetric ice content and soil salinity, while for the unfrozen ground the soil moisture content is the dominant factor for those thermal parameters. As for the soil thermal diffusivity, there exists a critical value of soil moisture content. When the soil moisture content becomes less than a critical value, the soil thermal diffusivity increases as the soil moisture content rises.     

GPS RTK技术及其在管线勘控中的应用

针对GPS RTK技术应用中的工作条件、数据链传输、误差特性及质量控制等问题,结合管线勘控测量的作业特点,提出了提高RTK作业精度若干方法.     

中国深层地热能开采的地质条件评价

深层地热能是指深度大于3 000 m的地热能。我国深层地热能资源丰富,但是开采条件怎么样呢?本文基于地热地质学原理,结合岩石力学等相关学科的理论,提出一种对深层地热能开采条件进行评价的指标体系,对各单一指标采用专家打分的方法赋值,继而采用模糊数学定量计算和评估深层地热能资源开发的难易程度。该方法考虑了深层地热能开发利用中的增强地热系统(EGS)的环境安全问题,即传统的“刚性造储”可能带来的诱发地震等不利于地热能行业健康发展的因素,倡导“柔性造储”和广义EGS理念,强调储层属性和地物理场的整合,针对我国地热能分布与构造活动关系密切、地壳总体上活动性强、地应力高、地震频发等构造型地热特点,是对以往评价方法的补充和拓展。该方法充分利用了专家知识,发挥了模糊数学综合评估作用,给出的量化结果易于对比和使用,可以更好地支持决策。本文基于新的评估方法,利用现有的深部地热研究及勘探成果,评估了中国大陆地区九个区域深层地热能开发的难易程度,评价区包括西藏南北地堑系、云南西部火山型地热区、青海东部共和盆地以及东北、华北等。从本文的结果可以看出,我国深层地热能开采的地质条件复杂,开采难度较大。