Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

我国热带亚热带部分地区花岗岩和片麻岩中黑云母风化研究

综合应用Ｘ射线衍射、扫描电镜、透射电镜及偏光显微镜等技术手段研究了我国热带、亚热带部分地区花岗岩和片麻岩中黑云母的风化现象。结果表明，化学风化产物主要有黑云母／蛭石不规则间层矿物、水黑云母、蛭石、０．７ｎｍ埃洛石及铁的氢氧化物（氧化物）等。影响黑云母风化及次生产物形成的主要因素包括黑云母的晶体结构和化学成分、气候、风化壳母岩的矿物成分等。     

吉林珲春东北部中生代侵入岩——一个中性—酸性双峰式岩系的演化和形成环境

地质调查和年代学资料表明,研究区内早燕山期侵入岩为一套中性—酸性双峰式岩系。通过岩石学、矿物学和地球化学方面的研究,对该岩系的成分演化特征、形成的构造环境进行了较细致的论述,得出该岩系是一个具不连续演化特点的钙碱性岩系,形成于破坏性板块边缘的张性环境,相当于Ⅰ型花岗岩系,属于环太平洋岩浆作用的内容。     

Yangtze Delta floods and droughts of the last millennium: Abrupt changes and long term memory

Summary Climate variability and flood events in the Yangtze Delta, which is a low-lying terrain prone to flood hazards, storm tides and typhoons, are studied in terms of a trend and detrended fluctuation analysis of historical records. The data used in this paper were extracted from historical records such as local annuals and chronologies from 1000–1950 and supplemented by instrumental observations since 1950. The historical data includes frequencies of floods, droughts and maritime events on a decadal basis. Flood magnitudes increase during the transition from the medieval warm interval into the early Little Ice Age. Fluctuating climate changes of the Little Ice Age, which are characterised by arid climate events, are followed by wet and cold climate conditions with frequent flood hazards. For trend analysis, the Mann-Kendall test is applied to determine the changing trends of flood and drought frequency. Flood frequency during 1000–1950 shows a negative trend before 1600 A.D. and a positive trend thereafter; drought frequency increases after 1300. The detrended fluctuation analysis of the flood and drought frequencies reveals power law scaling up to centuries; this is related to long-term memory and is similar to the river Nile floods.     

SVD方法在气象场诊断分析中的普适性

本文首次从理论上推导证明两个气象场的奇异值分解（ＳＶＤ）在气象场时空分布耦合信号的诊断分析中具有普适性。结果表明，两个场的ＳＶＤ求解准则不同于典型相关分析（ＣＣＡ），且ＣＣＡ模型可视为ＳＶＤ之特例，尤其当各个场经ＰＣＡ滤波后，其ＣＣＡ完全与ＳＶＤ等价。ＳＶＤ分析的结果不但可完全代替ＣＣＡ，且计算更简便，所得耦合信号的物理解释更清晰，特别适合于大尺度气象场的遥相关型研究。     

TVGA图形适配器对多卜勒风速的显示

着重介绍单多卜勒雷达圆锥体扫描获得的风速，回波强度资料在显示之前的数据处理方法，以及用ＴＶＧＡ图形适配器的高分辨显示模式（８００×６００，２５６色）显示多卜勒风场的技术。     

啤麦穗粒结构的分阶段气候评价和预报方法研究

通过对十多年来啤麦穗粒结构与气象条件的关系的计算分析,得出了啤麦不同生育阶段影响穗粒结构的主要气象要素,并建立起其间的线性关系模式,为对啤麦产量构成要素进行分阶段的气候评价和预报提供了新的方法。     

重庆城区浓雾的基本特征

统计分析沙坪坝1951～2002年间发生的浓雾事件，结合2001年12月重庆市雾的外场试验资料，探索重庆市主城区浓雾的基本特征。重庆主城区浓雾随年代演变有减缓趋势；主城区浓雾是自然雾与烟尘等的混合物，河谷及城市效应使雾更浓；城市中出现浓雾的大气边界层特征是在近地面层有逆温及增湿降温现象；高浓度气溶胶的净辐射效应阻碍白天混合层发展，使大气边界层趋于稳定，它是重庆连续几天有雾的原因之一；浓雾具有一定的湿沉降作用，能有限地清洁空气；有浓雾的天气条件下，建议降低污染物的排放总量，以避免严重大气污染事件发生。