A numerical study of mechanical behavior of a cement paste under mechanical loading and chemical leaching

Based on relevant experimental data of a petroleum cement paste under mechanical loading and chemical leaching, an elastic‐plastic model is first proposed by taking into account plastic shearing and pore collapse. The degradation of mechanical properties induced by the chemical leaching is characterized by a chemical damage variable which is defined as the increase of porosity. Both elastic and plastic properties of the cement paste are affected by the chemical damage. The proposed model is calibrated from and applied to describe mechanical responses in triaxial compression tests respectively on sound and fully leached samples. In the second part, a phenomenological chemical model is defined to establish the relationship between porosity change and calcium dissolution process. The dissolution kinetics is governed by a diffusion law taking into account the variation of diffusion coefficient with calcium concentration. The chemical model is coupled with the mechanical model, and both are applied to describe mechanical response of cement paste samples subjected to progressive chemical leaching and compressive stresses. Comparisons between experimental data and numerical results are presented.     

华北克拉通南缘后大陆碰撞背景下的岩石圈演化及金、钼成矿规律探讨

通过对华北克拉通南缘大量的岩浆岩和矿床研究表明,矿床的形成与燕山期岩浆岩具有非常密切的关系,豫西矿集区是华北克拉通南缘岩石圈剧烈演化的结果。岩石圈的这种剧烈演化是在两件重大地质事件的共同作用下进行的:一方面,扬子板块与华北板块在印支期拼合,并发生了广泛的陆-陆碰撞造山活动,此后,克拉通边缘转入了后造山演化阶段;另一方面,燕山晚期的J-K之交,太平洋板块向欧亚板块俯冲,导致地幔大规模活动。中国东部大规模的地壳减薄和壳幔作用,使本来就处于造山后演化阶段的华北陆块南缘发生了广泛的岩浆活动。正因为这两大地质作用叠加效应,区域岩浆演化剧烈而复杂,大批重融花岗岩的地球化学特征往往既显示造山带的特点,又具有大规模壳幔作用的特征。这两大地质作用为豫西矿集区的形成提供了良好的成矿地质背景,大量的研究表明,各种矿床与燕山期岩浆岩在形成时间上高度吻合,空间上密切相关,同位素指标极为相近,显示它们在成因上的密切关系。岩浆一方面作为深部赋矿流体的上升通道,另一方面提供持续的高温环境,保证了元素迁移和成矿作用的进行。因此,华北克拉通南缘后大陆碰撞背景下的壳幔演化、大规模岩浆活动是豫西矿集区形成的决定性因素。     

云南省禄劝县普福滑坡形成条件、发展趋势与防治对策

云南省禄劝县普福滑坡是我国典型灾难性滑坡之一,曾多次发生大规模滑动。本文回顾了普福滑坡的活动历史,分析了其形成条件。通过实地调查,结合由遥感多波段数据与DEM数据融合而成的三维影像图,指出普福滑坡实际上是一个滑坡(崩塌)→泥石流灾害链,且再次发生大规模滑动的可能性很大,影响范围覆盖烂泥沟两岸大面积区域。目前最经济有效的减灾措施包括搬迁避让、群测群防、监测预报、生态恢复和水土保持等。     

山西宁武地区高山湖泊全新世湖相地层划分及干海组的建立

通过山西宁武地区高山湖泊湖相沉积地层的浅井挖掘,在天池湖泊群一带发现了厚度大于6m的以草炭、泥炭、粘土及砂层为主的湖相沉积物。根据实测的干海、天池和琵琶海3条剖面,将分布于高山湖盆区内的湖相地层划分为12层,层序地层显示出以干海为代表的古湖泊由浅湖→滨湖→沼泽的演化趋势。湖相沉积的14C法测年结果为10950～260aBP,ESR法年龄测定结果为(9±3～8±1)ka,这表明高山湖盆内湖相沉积的形成时代为全新世。根据沉积相、岩相组合等特征,结合同位素测年、孢粉分析、微体古生物鉴定等资料,首次建立了山西宁武地区高山湖泊全新世湖相沉积地层序列,并将该套地层命名为干海组。     

粉煤灰改性膨胀土水稳定性试验研究

针对典型中膨胀土及其粉煤灰改性土,进行了击实特性试验,并且在最优含水率、不同压实度状态下,进行了饱水后干密度、压实度变化特征试验,以及不同吸水时间、不同干湿循环次数下的无侧限抗压强度、压缩模量变化规律试验,以此探讨中膨胀土、粉煤灰改性膨胀土的水稳定性特征。试验结果表明：粉煤灰改性土可击实含水率范围较之未改性土宽,这给粉煤灰改性土路堤的施工带来了很大的方便。饱水之后,改性土的干密度和压实度比素土变化小,饱水能力不大,强度变化较小。改性土经过不同吸水时间和干湿循环次数之后,其强度最初发生急剧衰减,但最终趋于稳定。其衰减程度较之未改性土来说,有较大改善,水稳定性良好。     

Infrared spectroscopic and X-ray diffraction characterization of the nature of adsorbed arsenate on ferrihydrite

Fourier transformed infrared (FTIR) spectroscopy was used to characterize arsenate-ferrihydrite sorption solids synthesized at pH 3-8. The speciation of sorbed arsenate was determined based on the As-O stretching vibration bands located at 650-950 cm⁻¹ and O-H stretching vibration bands at 3000-3500 cm⁻¹. The positions of the As-O and O-H stretching vibration bands changed with pH indicating that the nature of surface arsenate species on ferrihydrite was strongly pH dependent. Sorption density and synthesis media (sulfate vs. nitrate) had no appreciable effect. At acidic pH (3, 4), ferric arsenate surface precipitate formed on ferrihydrite and constituted the predominant surface arsenate species. X-ray diffraction (XRD) analyses of he sorption solids synthesized at elevated temperature (75 °C), pH 3 clearly showed the development of crystalline ferric arsenate (i.e. scorodite). In neutral and alkaline media (pH 7, 8), arsenate sorbed as a bidentate surface complex (in both protonated FeO₂As(O)(OH)⁻ and unprotonated forms). For the sorption systems in slightly acidic media (pH 5, 6), both ferric arsenate and surface complex were probably present on ferrihydrite. It was further determined that the incorporated sulfate in ferrihydrite during synthesis was substituted by arsenate and was more easily exchangeable with increasing pH.     

云南因民铁铜矿区辉长岩类中黑云母-金红石化特征及其指示意义

对云南因民铁铜矿区深部辉长岩类中金红石、黑云母、碳酸盐和绿泥石的矿物地球化学特征进行研究,以探讨赋存于辉长岩类中的铁氧化物铜金型矿(化)体的成岩成矿环境。金红石由岩浆结晶和多期蚀变作用形成,其结晶温度为820~1 082 ℃,多期蚀变温度为444~730 ℃,金红石与黑云母密切共生;黑云母可划分为原生高钛镁质黑云母、热液蚀变镁质黑云母和铁质黑云母,形成温度分别为653~750 ℃、525~619 ℃和551~577 ℃,氧逸度均位于Ni NiO缓冲剂附近,表明黑云母形成于高温强氧化环境,有利于金红石化;铁白云石-菱铁矿化揭示了强还原环境,交代蚀变金红石;绿泥石多由铁镁矿物蚀变形成,形成于中低温(174~243 ℃)、低氧逸度(-4468~-5142)和高硫逸度(-1442~-1976)的强还原环境,有利于金属硫化物形成。本区岩浆结晶演化和黑云母-金红石化蚀变具有高温强氧化地球化学岩相学特征,有利于钛、铁矿化,后期叠加中低温强还原地球化学岩相,为IOCG矿床成矿的有利地球化学岩相学类型。     

辽东兰花岭地区古元古代I型花岗岩类与辽吉A型花岗岩对比研究

辽东半岛是华北克拉通胶-辽-吉古元古代活动带的重要组成部分,古元古代经历了复杂的构造演化过程,并记录了多期岩浆-变质作用,约2.2 Ga的辽吉A型花岗岩和1.89~1.85 Ga的巨斑状花岗岩、正长岩分别标志着辽东古元古代造山作用的开端和结束。最新研究显示,2.20~2.15 Ga的岩浆作用形成了2种不同类型的花岗岩,它们可能具有不同的岩石成因和构造意义。在青城子铅锌矿集区北部采集的兰花岭、白砬子花岗闪长岩和黄泊辉绿岩,锆石U−Pb年龄分别为2177±19 Ma、2129±36 Ma、1876±29 Ma。花岗闪长岩的岩石成因类型、地球化学特征与典型的约2.2 Ga的辽吉A型花岗岩明显不同,属于弱过铝质、低钾钙碱性—碱性岩石,Zr、Hf、Nb、Rb含量较低,K2O/Na2O值、稀土元素总量极低,为典型的I型花岗岩类。根据锆石Lu−Hf同位素分析,εHf (t)值为−5.1~9.0,二阶段Hf模式年龄tDM2为2089~2817 Ma,岩浆源区为约2.5 Ga的太古宙地壳物质和少量软流圈地幔物质。兰花岭地区花岗闪长岩具备岛弧或活动大陆边缘的地球化学亲缘属性,可能形成于弧岩浆俯冲挤压环境;结合形成于伸展环境的A型条痕状花岗岩特征,认为约2.2 Ga辽东地区古元古代活动带呈现总体伸展、局部挤压的构造环境,为洋壳板块向龙岗地块俯冲碰撞过程中或碰撞后的弧后盆地。     

江西省地震工程地质现状与防灾展望——兼谈汶川地震对江西的启示

(1 概况.江西省位于欧亚板块东南部,跨扬子准地台和华南褶皱系两个地块(24°29′～30°04′N,113°34′～118°29′E).其南部地处华南沿海地震带,主要受河源一邵武断裂带与南岭纬向构造带控制;北部地处长江中游地震带,主要受郯城一庐江断裂带和扬州一铜陵断裂带控制,地质构造复杂,新构造及现代构造运动活跃,历史上曾多次发生破坏性地震.