Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).     

雄安新区蓟县系雾迷山组岩溶热储特征、主控因素及有利区预测*

雄安新区蓟县系雾迷山组中赋存丰富的地热资源,研究雾迷山组岩溶热储特征及优质储集层发育的主控因素是地热资源勘探的基础。综合运用野外剖面、岩心、薄片、钻井、测井、录井等地质与地球物理资料,对雾迷山组岩溶热储特征和演化过程进行了深入研究,明确了优质储集层形成的控制因素,预测了有利靶区。结果表明,雾迷山组岩溶热储主要岩性为晶粒白云岩、颗粒白云岩、微生物白云岩、硅质白云岩和角砾白云岩等,溶蚀孔洞、裂缝及其组合为主要的储集空间类型。雾迷山组热储平均孔隙度为3.18%,平均渗透率为91.48×10^-3 μm²;其中角砾白云岩物性最好。雾迷山组岩溶热储经历了沉积—准同生期成孔(雾迷山沉积期)、Ⅰ期表生增孔(雾迷山沉积期后至青白口纪前)、Ⅰ期埋藏减孔(青白口纪前至三叠纪)、Ⅱ期表生增孔(三叠纪—古近纪)、Ⅱ期埋藏减孔(新近纪—第四纪)5个阶段,岩性及岩相、成岩作用和构造应力是雾迷山组有利热储形成的主控因素。藻云坪—云坪相、表生岩溶、埋藏溶蚀、准同生岩溶、岩溶高地—斜坡和地层裂缝段比率大于0.4的6项叠合区是研究区最有利的岩溶热储发育区。     

Wave Slamming on An OWSC Wave Energy Converter in Coupled Wave-Current Conditions with Variable-Depth Seabed

China Ocean Engineering - Coastal wave energy resources have enormous exploitation potential due to shorter weather window, closer installation distance and lower maintenance cost. However, impact...     

A method to Estimate Dynamic Responses of VLFS Based on Multi-Floating-Module Model Connected by Elastic Hinges

China Ocean Engineering - Based on the elastic foundation beam theory and the multi-floating-module hydrodynamic theory, a novel method is proposed to estimate the dynamic responses of VLFS (Very...     

匹配层高频宽带水声换能器研究

为了获取更多的水下信息,提高声呐的探测和识别能力,设计高频宽带换能器是极为重要的。 匹配层技术是拓宽换能器带宽的有效方式。从理论上对匹配层拓宽换能器带宽的机理进行了分析,并利用数值计算和有限元仿真分析了匹配层对换能器性能的影响。结果表明：随着匹配层层数增加,换能器的谐振峰数目增加,峰与峰之间通过耦合能够实现拓宽带宽的效果。通过有限元仿真指导制成中心频率为 187.5 kHz 的双匹配层宽带换能器,其最大发送电压响应为 150.3 dB,–3 dB 带宽为 145 kHz。     

The cumulative characteristics of PAEs in PM2.5 in Changji,Northwest China

ABSTRACT

This paper discusses characteristics of the seasonal variation in phthalate acid esters (PAEs) in the PM_2.5 in the city of Changji, which is located an arid area of Xinjiang Province, northwest China. Samples were collected using a Laoying 2030 median discharge intelligent total suspended particulate (TSP) sampler and analyzed by a Shimadzu GC-2010 gas chromatograph. The results showed that PAEs in PM_2.5 were mainly composed of phthalic acid dibutyl phthalate (DBP) and phthalic acid (2-)ethyl hexyl ester (DEHP). DBP and DEHP are the most commonly used plasticizers, accounting for the majority of plasticizers used, and have large environmental emissions. Compared with the proportions of TSPs, proportions of DBP and DEHP in the PM_2.5 were lower, while the proportions of DMP and DEP were higher. A correlation exists between the distribution of PAEs and the particle size and concentration of atmospheric particulates. Seasonal variations in DBP and DEHP were the same, with lowest concentrations in the summer. Although seasonal variation in DMP was not the same as those of DBP and DEHP, the general trend was similar. Seasonal variation in DEP was different from those of other PAEs. This pattern is related to PAE characteristics and seasonal variations in their sources.     

How soil texture,channel shape and cross-sectional area affect moisture dynamics and water loss in irrigation channels

To enhance the utilization efficiency of farmland irrigation water and reduce the leakage of water conveyance channels, the leakage process of channels was simulated dynamically. The simulated results were compared with data measured in laboratory experiments, and the performance of the model was evaluated. The results indicated that the simulated values of the model were consistent with the observation values, and the R² values varied between 0.91 and 0.99. In addition, based on the laboratory experiments, a water supply system (Mariotte bottles) and soil box were built using plexiglass. Three influencing factors, namely, the channel form, soil texture and channel cross-sectional area, were varied to observe and calculate the resulting cumulative infiltration amount, infiltration rate and wetting front migration distance. HYDRUS-3D software was used to solve the three-dimensional soil water movement equation under different initial conditions. The results demonstrated that the U-shaped channel was more effective than the trapezoidal channel in increasing the utilization efficiency of the water resources. A U-shaped channel with a small channel cross-sectional area should be adopted and the soil particle size should be prioritized in the construction of water conveyance channels for farmlands. The simulation results were in agreement with the observed results, which indicates that HYDRUS-3D is a reliable tool that can accurately simulate the soil moisture movement in water conveyance channels. The research results can provide a reference for the design and operation of farmland irrigation systems.     

Multivariate adaptive regression splines for estimating riverine constituent concentrations

Regression-based methods are commonly used for riverine constituent concentration/flux estimation, which is essential for guiding water quality protection practices and environmental decision making. This paper developed a multivariate adaptive regression splines model for estimating riverine constituent concentrations (MARS-EC). The process, interpretability and flexibility of the MARS-EC modelling approach, was demonstrated for total nitrogen in the Patuxent River, a major river input to Chesapeake Bay. Model accuracy and uncertainty of the MARS-EC approach was further analysed using nitrate plus nitrite datasets from eight tributary rivers to Chesapeake Bay. Results showed that the MARS-EC approach integrated the advantages of both parametric and nonparametric regression methods, and model accuracy was demonstrated to be superior to the traditionally used ESTIMATOR model. MARS-EC is flexible and allows consideration of auxiliary variables; the variables and interactions can be selected automatically. MARS-EC does not constrain concentration-predictor curves to be constant but rather is able to identify shifts in these curves from mathematical expressions and visual graphics. The MARS-EC approach provides an effective and complementary tool along with existing approaches for estimating riverine constituent concentrations.     

都市水源区村域社会−生态系统脆弱性空间分异的地理影响模式——以上海市青浦区为例

以上海市青浦区为例,采用数据包络模型、空间自相关模型、多元Logistic回归模型、地理探测器和层次聚类模型分析该区184个行政村社会?生态系统脆弱性的空间差异及地理影响机制。研究表明：① 基于熵权集结交叉的“投入?产出”效率模型对村域社会?生态系统脆弱性评价结果更具可信度和精确性,2018年行政村社会?生态系统脆弱性空间上呈由东向西逐渐降低的变化趋势,脆弱性均值为0.583;② 地理因素对经济发达村域社会?生态系统脆弱性空间分异仍旧具有重要影响。距上海市中心距离、距淀山湖距离、距青浦区中心距离和水域面积成为影响该区社会?生态系统脆弱性的4种主导地理因素,其地理影响力呈现系统结构空间差异和种类属性替代及程度转化;③ 依据地理因素影响力聚类分析将该区社会?生态系统脆弱性地理因素空间耦合模式分为10种,多地理因素耦合模式是主要决定类型,呈现中部多因素主导和两侧单因素主导并存的多元环状地域决定格局;针对不同类型提出调控区域社会?生态系统脆弱性的可行方式。     

中蒙俄经济走廊生态经济区划研究

区划是地理学认识地理环境地域分异规律和优化人地关系地域系统结构与功能的有效手段。本文首先借鉴已有研究,对区域生态经济学这门新兴交叉学科及生态经济区划等相关概念进行了界定,明确了生态经济区划原则。其次,通过设计两级生态经济区划方案,首次对中蒙俄三国重要的经济增长轴带“中蒙俄经济走廊”这一国际区域进行了生态经济区划探索研究。基于研究区地貌、气候等自然地理要素以及经济开发强度等人文经济要素,首先将研究区划分为6类生态经济区。通过引入人均环境污染物产生量、土地利用类型、产业结构、人均GDP、城镇化率等具体生态环境和经济社会指标,进一步将研究区细化为19类生态经济亚区。最后,综合对比分析各类生态经济亚区的生态环境与经济社会特征及地域分异规律,贯彻绿色可持续发展理念,将其确定为优化发展区、重点发展区和保育发展区3类,并提出了针对不同类型区的绿色发展建议。本研究将为中蒙俄经济走廊的绿色发展提供科学支撑。